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A series of polyurethane anionomers were synthesized from isophorone diisocyanate, polyneopentanediol adipate and dimethanol propionic acid.

用异佛尔酮二异氰酸酯、聚己二酸新戊二醇酯和二羟甲基丙酸合成了负离子型聚氨酯离聚体。

Three alicyclic dianhydrides, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,4,5-cyclopentanetetracarboxylic dianhydride, and 1,2, 4, 5-cydohexane tetracarboxylic dianhydride were polymerized with two aromatic diamines, 1,4-bis (4-amino-2-trifluoromethylphenoxy) benzene (6FAPB, a) and 4, 4'-bis(4-amino-2-trifluoromethyl phenoxy) biphenyl (6FBAB, b) respectively, via a two-step polycondensation procedure to afford two series of fluorinated semi-alicyclic polyimides.

分别将脂环族二酐单体1,2,3,4-环丁烷四酸二酐、1,2,4,5-环戊烷四酸二酐和1,2,4,5-环己烷四酸二酐与芳香族含氟二胺1,4-双(4-胺基-2-三氟甲基苯氧基)苯(6FAPB, a)和4,4'-双(4-胺基-2-三氟甲基苯氧基)联苯(6FBAB, b)反应制备两个系列的含氟半脂环族聚酰亚胺,研究了PI薄膜的热性能和光学性能。

The common chemical constituents were juniper camphor,1,3,3-trimethylcyclohex-1-ene-4-carboxaldehyde,borneol,α-curcumene,α-bisabolol,cis-caryophyllene,benzyl benzoate,methyl β,β-dimethylbenzenepropanoic acid ester,2,4-decadienal and heneicosane in the essential oil of the five cultivars' Hangjuhua.Among them,juniper camphor is most which were composed of 11.96%,10.51%,10.95%,13.28% and 10.77% of the total essential oil,and methyl β,β-dimethylbenzenepropanoic acid ester is second,which were composed of 1.51%,1.86%,2.52%,4.89% and 2.51% of the total essential oil,respectively.

5种栽培类型杭菊花挥发油中共有成分为1,3,3-三甲基环己-1-烯-4-甲醛、冰片、α-姜黄烯、α-甜没药萜醇、顺式石竹烯、桧脑、安息香酸苄酯、β,β-二甲基苯丙酸甲酯、2,4-癸二烯醛和二十一烷;其中桧脑含量最高,分别占挥发油总量的11.96%,10.51%,10.95%,13.28%和10.77%,为5种栽培类型杭菊花挥发油中最具特征的成分;其次是β,β-二甲基苯丙酸甲酯,分别占挥发油总量的1.51%,1.86%,2.52%,4.89%和2.51%。

The influences of different surfactants (sodium dodecyl sulfate, sodium cholate and sodium deoxycholate), different electrolytes (sodium phosphate monobasic, sodium tetraborate and 3-cyclohexylamino-1-propane sulfonic acid), buffer pH and organic modifiers on the determination of sialic acid were studied.

其次建立了一种测定唾液酸的在线富集CZE法,该方法用40 mM磷酸二氢钠为缓冲溶液电解质,通过将样品溶解在乙腈:水=2:1的样品基体中,进样时间增加到100 s来达到样品富集的效果,并考察了样品基体中乙腈浓度和进样时间对富集效果的影响,研究了用硼砂或3-环己胺-1-丙烷磺酸作为电解质、缓冲溶液pH值和有机修饰剂的加入对唾液酸检测的影响。

The effect of progesterone could be potentiated by GABA A receptor agonist muscimol and antagonized by GABA A receptor antagonists bicuculline and picrotoxin as well as GABA B receptor agonist baclofen. The effect of progesterone and the actions of these drugs mainly manifested in the concentration range of progesterone 0 01~0 05 μmol/L.

该作用可被氨基丁酸A受体激动剂蝇蕈醇加强,被氨基丁酸A受体拮抗剂荷包牡丹碱和印防己毒素以及氨基丁酸B受体激动剂巴氯芬阻断,而且孕酮的效应以及各药物对其的影响均集中在0.01~0.05 μmol/L孕酮浓度中较为明显。

Chromatography peaks were obtained by GC-MS and 56 compounds were identified. The main components were linalyl butyrate (30.212%),(1α, 3α, 4β, 6α)-4,7,7-trimethyl-bicycloheptan-3-ol (10.940%),-4-carene (1.826%), 4-methylene-1-(1-methylethyl)-bicyclo [3.1.0] hexane (1.109%),β-myrcene (1.170%), limonene (5.784%), 3, 7-dimethyl-1, 6-octadien-3-ol (5.742%), n-hexadecanoic acid (0.914%) and-9, 12-octadecadienoic acid (2.952%), etc.

用GC-MS分离出69个峰,鉴定出56种物质,主要成分为:芳樟丁酸酯(30.212%)、(1α, 3α, 4β, 6α)-4,7,7-三甲基-双环[4.1.0]庚烷-3-醇(10.940%)、-4-蒈烯(1.826%)、4-亚甲基-1-(1-甲基乙基)-双环[3.1.0]环己烷(1.109%)、β-月桂烯(1.170%)、柠檬烯(5.784%)、3,7-二甲基-1,6-辛二烯-3-醇(5.742%)、n-棕榈酸(0.914%)、-9,12-十八碳烯酸(2.952%)等。

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是,超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解,这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

A bis-imdazoline corrosion inhibitor JUC was synthesized by reacting with divinyl three amine,and its quaternary ammonium JUCI was also synthesized for corrosion inhibition in acids.

以己二酸、二乙烯三胺为原料合成了双环咪唑啉缓蚀剂JUC,并对其季铵化后得到了适于酸化用的双环咪唑啉季铵盐缓蚀剂JUCI;采用静态挂片失重法对合成的缓蚀剂在酸化条件下的缓蚀性能及与非离子表面活性剂SA-1复配后的缓蚀性能进行了评价研究。

At the same time, for the alternatives, another set of devices was also set up according to balanced method. From above two experiments, we got solubility datas of succinic acid, glutaric acid and adipic acid in six solvents of water, ethanol, n-butanol,choloroform, acetone and toluene, of which most were measured for the first time.

由合成法和平衡法实验测定了丁二酸、戊二酸和己二酸三种溶质在水、乙醇、正丁醇、氯仿、丙酮、甲苯六种溶剂中的溶解度数据,其中大部分体系和溶解度数据是首次测定。

The logarithm difference values of partition coefficients of the compounds in butyl ether/water and in cyclohexane/water system were used for the measurement of the Lewis acidity, while the logarithm difference values of partition coefficients in trichloromethane/water and in tetrachloromethane/water system were used for the measurement of the Lewis basicity, and they were used successfully to differentiate the relative strength of Lewis acidity and basicity for 59 benzene and its derivates.

以化合物在正丁醚/水和环己烷/水溶剂体系中分配系数的对数差作为酸性指数,以其在氯仿/水和四氯化碳/水溶剂体系分配系数的对数差作为碱性指数,提出了一种新的度量有机物Lewis酸碱性的方法,按此方法成功地区分了59种苯系物Lewis酸碱性的相对强弱;并成功地将上述酸碱性指数引入定量结构—性质/活性相关研究之中,探讨了苯系物的正辛醇/水分配系数、水溶解度和土壤有机碳吸附系数等常见理化性质与其Lewis酸碱性间的相关性并建立了相应的定量模型,发现它们之间存在良好的相关性。

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