己酸

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

Using mordern physical chemistry techniques (such as XRD、 TG-DTA、 IR、 XPS and 〓Xe-NMR)、 chemical adsorption techniques (NH〓-TPD、 H〓-TPD、 TPO、 TPR etc.) and pulse flow microreaction of n-hexane、 methylcyclopentene and n-hexane containing 0.2ppm thiophene, we studied mainly the following three points:(1). the changes occured during the calcination pretreatment of Pt ammine complex supported on β and L zeolites;(2). the effect of structure and acidity-basicity of zeolite on the dispersion and electron state of Pt particles; and (3). the influence of second metal component on the reactivity of nhexane aromatization and sulphur-resistance of Pt/L zeolite catalyst. Several interesting and valuable results are obtained and summerized as follows

本论文运用各种近代物理表征方法(XRD、BET、TG-DTA、IR、XPS和〓Xe-NMR)、化学吸附技术(NH〓-TPD、H〓-TPD、TPO、TPR等)和正己烷、甲基环戊烷及含噻吩正己烷的脉冲微反等方法，着重研究了(1)载Pt的β和L沸石在分解预处理过程中发生的变化；(2)沸石载体结构及酸碱性对Pt粒子分散及电子状态的影响；(3)第二金属组份对载Pt沸石催化剂上正己烷芳构化及抗硫性能的影响等，得到了某些有意义的结果。

Effects of various parameters such as potential scan rate and cyclohexanol concentration on the eletro-oxidation of cyclohexanol were also studied.

初步认为，NiO首先被氧化为NiOOH，NiOOH再与环己醇发生还原反应生成己二酸和NiO，因此，NiOOH可作为较好的催化环己醇氧化反应的催化剂。

A series of long chain alkyl methylnaphthalene sulfonates, including hexyl methylnaphthalene sulfonate, octyl methylnaphthalene sulfonate, decyl methylnaphthalene sulfonate, dodecyl methylnaphthalene sulfonate, and tetradecyl methylnaphthalene sulfonate, was characterized by high performance liquid chromatography and electrospray ionization mass spectrometry. Through a great deal of testing, the analytical conditions were optimized.

采用反相离子对高效液相色谱和电喷雾离子化质谱对系列长链烷基甲基萘磺酸盐，包括己基甲基萘磺酸盐、辛基甲基萘磺酸盐、癸基甲基萘磺酸盐、十二烷基甲基萘磺酸盐、十四烷基甲基萘磺酸盐进行分析，通过液相色谱分离条件的优化，找到了最佳分析条件。

Professional sales companies operating bromide products: sodium bromide, sodium bromide, potassium bromide, potassium bromate, Tetrabromobisphenol A, Deca-BDE, ten PBDEs, DBDPE, hexabromodiphenyl Central dodecane, dibromo neopentyl glycol, neopentyl bromide three alcohols, three bromine phenol, octabromodiphenyl ether, brominated polystyrene, bromide, calcium bromide, dibromo succinic acid, dibromo-D ene glycol, bromide surfactants series: Dodecyl trimethyl ammonium bromide, tetradecyl trimethyl ammonium bromide, cetyltrimethyl ammonium bromide, octadecyl trimethyl ammonium bromide dodecyl trimethyl ammonium chloride, tetradecyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, tetrabutyl ammonium bromide wholesale sales: dimethylolpropionic acid, DL-malic acid, isophthalic acid PIA, glycolic acid, adipic acid.

公司专业经营销售溴化物系列产品：溴化钠、溴酸钠、溴化钾、溴酸钾、四溴双酚A、十溴二苯醚、十溴联苯醚、十溴二苯乙烷、六溴环十二烷、二溴新戊二醇、三溴新戊醇、三溴苯酚、八溴醚、溴化聚苯乙烯、溴化铵、溴化钙、二溴丁二酸、二溴丁烯二醇、溴化表面活性剂系列：十二烷基三甲基溴化铵、十四烷基三甲基溴化铵、十六烷基三甲基溴化铵、十八烷基三甲基溴化铵、十二烷基三甲基氯化铵、十四烷基三甲基氯化铵、十六烷基三甲基氯化铵、十八烷基三甲基氯化铵、四丁基溴化铵批发销售：二羟甲基丙酸、DL-苹果酸、间苯二甲酸 PIA、羟基乙酸、己二酸。

At present, 70,000 tons / year of adipic acid project completed the overall progress of the project 98%, adipic acid and related projects have been the end, assistive devices and production equipment also has entered the pre-production stage; and 50,000 tons / year project alcohol ketone the overall progress of the project completed 99%, nitric acid and hydrogen projects overall progress of the project 98 percent completed, with test conditions; In addition, 704 pumping stations - natural gas pipeline project Dushanzi overall progress of the project 98 percent completed.

目前，7万吨/年己二酸项目总体工程进度完成了98%，己二酸及配套项目施工已经收尾，辅助装置和生产装置也已经进入试生产阶段；且5万吨/年醇酮项目总体工程进度完成了99%，硝酸及制氢项目总体工程进度完成了98%，具备试车条件；另外，704泵站-独山子天然气管道项目总体工程进度完成了98%。

Sodium tungstate ; cyclohexene ; catalytic oxidation ; adipic acid ; acidic ligand ; reaction kinetics

钨酸钠；环己烯；催化氧化；己二酸；酸性配体；反应动力学

The catalyzed oxidation of cyclohexanol with 30% aqueous hydrogen peroxide by mass fraction to produce adipic acid can be achieved using tungstic acid -acidic additive catalyst system in the absence of organic solvents and phase-transfer reagent.

以钨酸-酸性添加剂为催化体系，在无有机溶剂和相转移剂的情况下，催化30%过氧化氢氧化环己醇合成己二酸。

Cyclohexene ; catalytic oxidation ; tungstic acid ; hydrogen peroxide ; adipic acid

环己烯；催化氧化；钨酸；过氧化氢；己二酸

When the molar ratio of tungstic acid∶acidic organic additive∶cyclohexene∶hydrogen peroxide was 1∶1∶40∶176 (tungstic acid, 2.5 mmol) and the tungstic acid/resorcinol used as catalyst, the isolated yield of adipic acid was up to 90.9% for 8 h.

以钨酸/有机酸性添加剂为催化体系，在无有机溶剂、相转移剂的情况下，催化30%过氧化氢氧化环己烯合成己二酸。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。