己酰基

A novel monomer the 1-methyl-4,5-bis(4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methyl-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4′-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与4-(4-羟基苯基)-2，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

A novel monomer the 1-methyl-4,5-bis (4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methy l-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4'-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体 1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与 4-(4-羟基苯基)-2 ，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

Additionally, the quantum chemical study on the isomeriaation mechanism of the enol ester of 2-acyl-l,3-cyclohexanedione was performed, which was discovered by Yang when he synthesized the derivate of 2-acyl-l,3-cyclohexanedione.

第三部分工作是对杨定亚在合成2-酰基-1，3-环己二酮类化合物的衍生物时意外发现的烯酯异构化反应机理进行了研究。

Using benzophenone as a probe, the energytransfer mechanism was studied by pulse radiolysis experiments on TOP-BP-CH andTBPO-BP-CH system. The results showed that organo phosphoryl compounds canaccept energy from excited CH and capture a proton from geminate pair .

结果表明含磷酰基有机化合物在能量转移过程中有双重作用：一方面从环己烷激发态接受激发能，另一方面从环己烷偕离子对〓夺取质子，发生质子转移过程。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

In this thesis, we want to describe the new one-carbon and three-carbon chain extension and ring expansion of 2-aroyl-3,4-dihydro-2H-naphalen-l-one, which is the first report based on our knowledge.

本文在前人的研究基础上，首次开展了α—芳酰基苯并环己酮增加一个碳原子和三个碳原子的自由基扩环和链增长反应，以及自由基加成成环反应。

The transesterification reaction were studied under organic solvents systemThe dosage of diatomite immobilized lipase of Enterobacter aerogenes is 1000 U, ethanol as acyl receptors(alcohol:oil molar ratio is 4:1,2 times add),5 mL n-hexane, 180 r/min,35℃,48 h,and the conversion rate of 92.91%.

有机溶剂体下催化生产生物柴油硅藻土固定化产气肠杆菌脂肪酶用量为1000 U，乙醇为酰基受体(醇：油摩尔比为4：1，2次等量加入)，5 mL正己烷，180 r/min，35℃，反应48 h，转化率达92.91%。

Series of FAnC(n=1~4) were synthesized by acylation reaction of FAn (scheme 1) with cinnamyl choride.

通过肉桂酰氯与ε-己内酯改性丙烯酸酯间的酰基化反应，合成了一系列光敏性大单体。

The synthesis,characterization and mesomorphic properties of new dimerliquid crystalline compounds D-mn and their derivatives D2F-mn based on4-(trans-4-alkyl cyclohexyl)benzoic acid and cholesterol are described in this thesis.

本文描述了一系列新型双介晶结构液晶化合物ω-[4-(反-4-正烷基环己基)苯甲酰基]脂肪酸胆固醇酯及衍生物(D2F-mn)的合成及其结构表征和介晶性质。

In this paper, 4-4-(trifluoromethoxy benzoyl cyclohexyl-3, 5-diaminobenzoate with a large branch chain, pyromellitic dianhydride and 4-(4-aminobenzyl) benzenamine were used to synthesize polyimides. The effect of monomer charge order on pretilt angle was investigated for the first time when PIs were used as LC alignment layer, and the effect of diamine mole ratio on pretilt angle was studied. The thermal stability of the pretilt angle was discussed.

文章用均苯四酸二酐、4，4'-二胺基二苯甲烷和具有较大支链的4-（4-苯甲酰基）环己基－3，5-二胺基苯甲酸酯等单体制备聚酰亚胺，首次研究了单体加料顺序对液晶预倾角的影响，同时也研究了二胺配比对液晶预倾角的影响问题，并探讨了预倾角的热稳定性等问题。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。