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己烯

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This invention discloses an intermolecular charge transfer chromogen with triphenylamine group, with a formula indicated by (1), wherein: R1 is hydrogen atom or methyl group or methoxyl group, R2 is hydrogen atom or 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group.

本发明公开的含三苯胺基团的分子内电荷转移生色团,具有式1所示的结构式,其中R 1 为氢原子或甲基或甲氧基,R 2 为氢原子或2-(5,5-二甲基-3-乙烯环己烯基-2-烯亚基)丙二腈基。

This invention applies mild condition uses substituent group triphenylamine aldehyde or triphenylamine dialdehyde as raw material to react by heating with 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group to produce the intermolecular charge transfer chromogen with high decomposition temperature, non-coplanar structure, and triphenylamine group.

本发明采用温和的手段,将取代基三苯胺单醛或取代基三苯胺双醛为原料与2-(3,5,5-三甲基环己烯-2-烯亚基)丙二腈共热生成具有高的热分解温度、非共平面空间结构的含三苯胺基团的分子内电荷转移生色团。

The qualitative analysis of the volatiles emitted from tea plants infested by Ectropis obliqua Prout with GC-MS or zNoseTM showed the similar results, however the relative contents of-3-hexen-1-ol,benzyl nitrile,indole,-caryophyllene obtained from both showed a certain difference.

结果表明:GC-MS与zNoseTM对茶尺蠖取食诱导的茶树挥发物的定性分析结果差别不大;但两者测定茶尺蠖取食诱导的茶树挥发物中顺-3-己烯醇、苯乙腈、吲哚、反-石竹烯等4种组分的相对含量有一定差异。

These results were veryreasonable considering the fact that cyclohexene and 1-octene can not bepolymerized with Ziegler-Natta catalyst.

产物的FD-MS分析结果表明:〓和辛烯-l的加成物为加成数从1到16的混合物;〓和环己烯主要生成加成数为9的加成物。

P-Isopropylphenol was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using 4-isopropylcyclohexenone as the material and the hydrogen offer, industrial dipentene as the hydrogen acceptor and the solvent.

采用5%Pd/C作为转移氢催化剂,4-异丙基环己烯酮为氢给予剂,工业双戊烯为氢接受剂和溶剂进行反应,合成了对异丙基苯酚。

The bubble point, dew point and critical point were determined for binary mixtures of 1 pentene and 1 hexene, and thus the problem that critical parameters are evaluated without accurate and reliable theory is solved.

测定了1-戊烯-1-己烯二元混合物在不同组成下的泡点、露点及临界点,解决了没有准确可靠的理论估算临界数据的问题。

Research on the Over critical and Overflow at Variable Conditions of Marine Steam Turbine;2. Strongly total domination edge critical graphs;3. This paper measures the critical energy of detonation of hydrocarbon fuel(butane,naphtha,pentene,hexene,JC5) and air mixtures using Bruceton method in the rectangular shock tube.

该文在矩形激波管内采用布鲁塞顿法测定了丁烷、石脑油、戊烯、己烯、JC5等碳氢燃料与空气混合物形成爆轰时所需的临界起爆能,并根据所测定的临界起爆能的大小,分析比较了这几种碳氢燃料的相对爆轰敏感度及相应的安全性能,最后讨论了分子量,分子中键的饱和度和分子结构等因素对碳氢燃料临界起爆能及相应的安全性能的影响。

This paper measures the critical energy of detonation of hydrocarbon fuel(butane,naphtha,pentene,hexene,JC5) and air mixtures using Bruceton method in the rectangular shock tube.

该文在矩形激波管内采用布鲁塞顿法测定了丁烷、石脑油、戊烯、己烯、JC5等碳氢燃料与空气混合物形成爆轰时所需的临界起爆能,并根据所测定的临界起爆能的大小,分析比较了这几种碳氢燃料的相对爆轰敏感度及相应的安全性能,最后讨论了分子量,分子中键的饱和度和分子结构等因素对碳氢燃料临界起爆能及相应的安全性能的影响。

Cyclohexene ; catalytic oxidation ; tungstic acid ; hydrogen peroxide ; adipic acid

己烯;催化氧化;钨酸;过氧化氢;己二酸

When the molar ratio of tungstic acid∶acidic organic additive∶cyclohexene∶hydrogen peroxide was 1∶1∶40∶176 (tungstic acid, 2.5 mmol) and the tungstic acid/resorcinol used as catalyst, the isolated yield of adipic acid was up to 90.9% for 8 h.

以钨酸/有机酸性添加剂为催化体系,在无有机溶剂、相转移剂的情况下,催化30%过氧化氢氧化环己烯合成己二酸。

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