己基乙炔

A gas chromatographic-mass spectrometric method for the simultaneous determination of environmental estrogens (including 4-nonylphenol, bisphenol A,diethylstilbestrol and 17α-ethinylestradiol) and endogenous estrogens (including 17α-estradiol, 17β-estradiol, estriol and estrone) in urine and bed mud is reported.

报道了尿及河底泥中环境雌激素(壬基酚、双酚A、己烯雌酚、17α-乙炔基雌二醇)和内源性雌激素(17α-雌二醇、17β-雌二醇、雌三醇、雌酮)的气相色谱-质谱测定法。

To investigate the pollution levels, occurrence and distribution of estrogens, six estrogens in the surface sediments of Wenyuhe River were analyzed quantitatively by GC/MS following ultrasonicated extraction including diethylstilbestrol, estrone(E1),β-estradiol(E2), 17α-ethynylestradiol(EE2), estriol(E3), and β-estradiol 17-valerate. Six estrogen concentrations ranged from 0.39-36.6ng/g and the mean concentration was 10.2ng/g.

为了调查温榆河沉积物中雌激素物质的污染状况，采用超声萃取、GC/MS法研究了6种常用雌激素（包括己烯雌酚DES、雌酮E1、雌二醇E2、乙炔基雌二醇EE2、雌三醇E3和戊酸雌二醇EV）在北京温榆河上游及干流表层沉积物中的含量水平，并对其分布及来源情况进行了分析。

They have close relationship as the former may provide new ideas and approaches for the later, while the later may be the simulation for the former and gives it helps in degradation products identification and mechanism explanation. It is necessary to choose a suitable system, which has high potential of treating EDs and close relationship to the natural environment, to combine the researches in the two aspects. Our group has been engaged in researches on the photochemical properties and application to water pollution control of different ferric species including Fe -OH complexes, Fe -polycarboxylate complexes, Ferric oxides and Fe -humic acid complexes. Fe -oxalate complexes system has higher efficiency than the other ferric species systems in photooxidation and degradation of organic compounds. This thesis is focused on the photodegradation of nine EDs estradiol (E2), estrone (E1), 17α-ethynyl estradiol (EE2), diethylstilbestrol , bisphenol-A , 4-Nonylphenol , 4-Octylphenol , di-n-butyl phthalate , and di (2-ethylhexyl) phthalate .

因此从处理效率和环境化学意义两方面考虑，结合本课题组在不同铁形态（包括Fe-OH配合物、Fe-多羧酸配合物、Fe氧化物、Fe-腐殖酸配合物等）的光化学特性及其在水污染控制中的应用方面较系统的研究工作基础，本论文选择了四类共9种典型的内分泌干扰物（雌二醇（E2）、雌酮（E1）、17α-乙炔基雌二醇（EE2）己雌酚、双酚A、壬基酚、辛基酚、酞酸二丁酯和酞酸二乙基己基酯），研究了它们在Fe-草酸盐配合物体系中的光降解效果，推测其降解机理，探索环境内分泌干扰物光氧化处理的新体系，同时为预测其在环境中的光降解行为提供了依据。

In order to lower the Δn value and obtain broad mesophase range, new negative dielectrics anisotropy liquid crystal compounds 4a and 4b were designed by replacement a phenyl ring with a cyclohexyl ring in the common tolane liquid crystals.

为降低液晶分子的双折射率并获得宽液晶相区，用环己基替代传统二苯乙炔液晶分子中的一个苯环，得到一类结构新颖的含乙炔桥键的负介电各向异性液晶分子4a， 4b。

Four soluble poly(p-phenylene vinylene) derivatives with asymmetric alkoxyl substituents, poly (2-methoxy-5-butoxy)-p-phenylene vinylene, poly [2-methoxy-5-(3'-methyl)butoxy]-p-phenylene vinylene, poly (2-methoxy-5-hexyloxy)-p-phenylene vinylene and poly (2-methoxy-5-octoxy)-p-phenylene vinylene, were prepared by dehydrochlorination reaction with using p-hydroxyanisole and alkyl bromide as raw materials.

以对羟基苯甲醚和溴代烷烃为原料，采用强碱诱导的脱氯化氢缩合聚合法合成了四种可溶性不对称烷氧基取代聚对苯乙炔衍生物，分别为聚（2-甲氧基－5-丁氧基）对苯乙炔、聚［2-甲氧基－5-（3'-甲基）丁氧基］对苯乙炔、聚（2-甲氧基－5-己氧基）对苯乙炔和聚（2-甲氧基－5-辛氧基）对苯乙炔。

The target molecules were synthesized through a Sonogashira coupling reaction of 1-trans-4-(trans-4-n-pentylcyclohexyl)cyclohexylacetylene and 4-iodo-2,3-difluoro- phenyl ether with total yields of 27%～28%.

目标化合物采用1-trans-4-(trans-4-正戊基环己基)环己基乙炔与4-碘-2，3-二氟苯基醚进行Sonogashira偶联反应制备，反应总产率27%～28%。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。