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己二烯

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CySeCD exhibits better GPX activity than 6-AnSeCD in the reduction of H2O2 and cumenyl hydroperoxide by glutathione, respectively.

采用双酶偶联法测定GPX的活力结果显示,6A,6A'-二环己胺-6B,6B'-二硒桥联-β-环糊精(6-CySeCD)催化谷胱甘肽还原H2O2和枯烯H2O2的活力均比6-AnSeCD的高。

Thus, in order to attain acetal can be used as precursor of its matrix olefine aldehyde, 2-undecental glycol acetal was synthesized, and the corresponding optimum reaction conditions as: 2-undecental 0.2mol, glycol 0.3mol, cyclohexane as solvent, catalysed by vitamin C, the optium reaction time was 6h, its reaction yield could reach over 77.25%.

为了进一步探求效果更理想的前体化合物,本文继续合成了2-十一烯醛乙二醇缩醛,通过单因素优化实验得到最佳反应条件为:环己烷作溶剂,VC作催化剂,用量0.42%,醛醇物质的量之比0.2:0.3,反应时间6h,此条件下产品收率达77.25%。

Could keep above 95% in the fixed beds. In order to achieve high stereo-selectivity with yeast, ethyl acetoacetate was used as the model substrate,and a novel approach was proposed to selectively inhibit R-enzymes in yeast before reaction.

以乙酰乙酸乙酯为模型底物,以丙烯酸、乙醚、二甲基亚砜、丙烯酰胺、正己烷等有机溶剂选择性地抑制酵母中R型酶,提高反应立体选择性。

We studied the number of ordinated water of polyoxometalate catalysts how to affect the catalytic activity.

2,研究了1 , 2-二氯乙烷做溶剂,催化氧化环己烯的体系中杂多酸所含配位水的数量对催化剂活性的影响。

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