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Effects of various parameters such as potential scan rate and cyclohexanol concentration on the eletro-oxidation of cyclohexanol were also studied.

初步认为,NiO首先被氧化为NiOOH,NiOOH再与环醇发生还原反应生成二酸和NiO,因此,NiOOH可作为较好的催化环醇氧化反应的催化剂。

It was found that manganese porphyrin had the highest activity, and a maximum 15.4% of cyclohexane conversion and 93.9% selectivity of cyclohexanone and cyclohexanol could be obtained under the suitable conditions.

结果发现,锰卟啉催化活性最好,在适宜反应条件下,环烷转化率高达15.4%,环酮和环醇的总选择性约为93.9%。

Under the conditions of n∶n = 1∶100,95 ℃ and 6 h,the conversion of nitrocyclohexane reached to 100% and the selectivity for cyclohexanone oxime was 84.2%.

在催化剂与硝基环烷摩尔比为1∶100、反应温度95 ℃的条件下,反应6 h后的硝基环烷转化率可达100%,环酮肟选择性可达84.2%。

The dominant techniques of cyclohexanone synthesis from cyclohexane by catalytic oxidation were introduced.

介绍了以环烷为原料催化氧化合成环酮的主要方法,分析了环烷氧化采用的主要催化剂。

Particularly,ethylenediamine is an optimal choice for improving the selectivity for cyclohexanone oxime.

在催化剂与硝基环烷摩尔比为1∶100、反应温度95℃的条件下,反应6h后的硝基环烷转化率可达100%,环酮肟选择性可达84.2%。

The Di(2-ethyl hexyl) Adipate in Nenjiang river water was extracted by hexane with ultrasonic generator.

采用超声波提取技术,用正烷提取嫩江水中二酸二(2-乙基基)酯增塑剂,以气相色谱/质谱联用选择离子监测法检测,外标法定量。

Through mechanism analyzing on the process of producing HMT , it was known that because the resistance of isobutylene was small ,the yield of outgrowth in such a reaction system was little and the yield of reaction was as high as 86%. 2,3-dimethyI-butene-2 had the biggest resistance and lowest yield of reaction of 18%. 2,3-dimethyl-butene-l had bigger resistance than isobutylene and more outgrowth than isobutyles but its yield of reaction could reach 70%.

通过对上述三种烯烃合成HMT的研究可知,由于新烯位阻小,反应中副反应少,收率高达86%:而2,3—二甲基—丁烯—2的位阻最大,反应中副反应最多,反应收率最高仅为18%;2,3—二甲基—丁烯—1的位阻比新烯大,反应副产物比新烯多,但反应收率仍可达70%。

The result of situ-FTIR study on the process of dehydrogenation of CHL, we concluded the reaction mechanism, and proved that monovalence copper had more activity than zero valence copper and the side reaction mainly took place on zero valence copper.

通过对环醇脱氢反应过程的原位傅立叶变换红外光谱研究,推导出了反应机理,得出Cu〓较Cu〓更具有环醇脱氢活性,环醇脱氢的副反应主要发生在Cu〓上。

The response to single compound: To both females and males, the compounds that elicit larger responses of adults are benzaldehyde, benzene acetaldehyde, hexanol,β-phenyl ethyl alcohol, benzyl alcohol, cyclohexanol and eugenol. Phytol, 2-methyl-cyclohexanone and β-caryophyllene reveal to have weaker activity.

对单一化合物的反应:两种昆虫,不论是雌蛾还是雄蛾,能引起较强EAG反应的化合物均为苯甲醛、苯乙醛、正醇、β-苯乙醇、苯甲醇、环醇和丁香酚,植醇、2-甲基环烷和β-石竹烯仅能引起微弱的EAG反应。

The results show that the identical resonance in 2.09THz is originated from the collective vibrational modes triggered by the torsional vibrations of the pyran ringsin hexoses; and the other characteristic resonances of the hexoses is originated from the intermolecular collective modes mediated by hydrogen bonding network of the crystalline structure.

研究结果表明,糖在2.09THz处的共性吸收峰来源于糖分子中吡喃环扭曲振动引发的集体振动模式;而糖的其它特征吸收峰主要来源于晶体结构中由氢键网络支配的分子间集体振动模式。

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