嵌段共聚物

But due to the commonstructure characteristic of the segmented copolymers, the ratio of 〓 is still aneffective parameter to predict the crystallizability of the two segments in limitedenvironment.

虽然这个确切的比值对聚醚酯多嵌段共聚物不具有普遍意义，但是由于聚醚酯多嵌段共聚物共同的结构特征，软硬链段之间的相对长度仍是一个反映两种链段结晶能力的一个很有用的参数。

By employing such a method, 5 series of elastomers, including natural rubbers, elastomeric polyester fibers and ethylene-octene, ethylene-methyl acrylate as well as SIS triblock copolymers, were investigated with the purpose of studying elongation induced phase structure and mobility changes of the samples. For NR samples, it was demonstrated that there exists a small amount of crystals at RT even for unelongated samples. For both NR and the soft segment of PEE, with the increase of elongation ratio, the elongation-induced crystallinity increases almost linearly in a certain region of R, in accord with the increase of the lamellar thickness of the crystals; The behavior of ethylene copolymers, in terms of elongation induced morphorpholgy changes, are quite different from NR and PEE. The crystals are found to be gradually destroyed with the increase of R, with accord with the decrease of the lamellar thickness; The motional behavior of the soft segment of SIS, changes from "liquid" to "solid", in terms of 13C NMR spin-lattice relaxation.For many of the aformented samples, the dependence of 13C spin-lattice relaxtion time T1 on R are different for different groups, indicating that the changes of mobility at MHz frequency region with elongation are different for different groups.

通过对天然橡胶、聚醚酯嵌段共聚物、乙烯-辛烯共聚物、乙烯-丙烯酸甲酯共聚物、SIS等高分子弹性体样品聚集态结构和分子运动的研究，获得了一些新的实验结果，如：给出了确切的实验证据，证明了室温下未拉伸的天然橡胶样品中存在着微量的结晶；发现随着拉伸比增加，天然橡胶及聚醚酯样品的软段部分会出现拉伸诱导的结晶，且结晶度在一定范围内呈现近似线性的增加，所形成晶片的厚度也随之逐渐增加；而乙烯共聚物随着拉伸比的增加，原有的结晶会被逐渐破坏，晶片厚度逐渐变薄，结晶中的缺陷逐渐增加；随着拉伸比的增加，SIS中PI软段部分的核磁共振弛豫行为会出现从液态到固态的转变等；在对上述多个体系的研究中，还发现不同基团的自旋-晶格弛豫时间随着拉伸比呈现不同的变化趋势，表明不同基团的高频运动随拉伸比增加有不同的变化规律。

In the thin films of semicrystalline block copolymers there exist three driving forces: the interaction between substrate and block copolymer, crystallization of crystallizable component and microphase segregation between unlike blocks. The relative strength of these three driving forces can be regulated by various methods.

在这两类结晶性嵌段共聚物薄膜中存在三种作用力：基体和嵌段共聚物之间相互作用力、可结晶链段的结晶以及不同链段之间的排斥作用力。

Attributed to the lubricant-effect of flexible LCPB,cold crystallization was observed in stereoblock PB.Bd-Ip block copolymersHTPB-b-PI,C-(PI-b-HTPBn,C-n,and PI-b-HTPB -b-PI and Bd-St block copolymersHTPB-b-PS,C-(PS-b-HTPBn,C-n, and PS-b-HTPB-b-PS containing crystallizable HTPB were well synthesized,the microstructures and properties of the copolymers were investigated in detail.

通过与异戊二烯或者苯乙烯共聚，合成了含高反式聚丁二烯的丁二烯-异戊二烯嵌段共聚物包括HTPB-b-PI，C-(PI-b-HTPBn，C-n和PI-b-HTPB-b-PI和丁二烯-苯乙烯嵌段共聚物包括HTPB-b-PS，C-(PS-b-HTPBn，C-n和PS-b-HTPB-b-PS，对嵌段共聚物的结构和性能进行了系统的研究。

Attributed to the lubricant-effect of flexible LCPB,cold crystallization was observed in stereoblock PB.Bd-Ip block copolymersHTPB-b-PI,C-(PI-b-HTPBn,C-n,and PI-b-HTPB -b-PI and Bd-St block copolymersHTPB-b-PS,C-(PS-b-HTPBn,C-n, and PS-b-HTPB-b-PS containing crystallizable HTPB were well synthesized,the microstructures and properties of the copolymers were investigated in detail.

加热器通过与异戊二烯或者苯乙烯共聚，合成了含高反式聚丁二烯的丁二烯-异戊二烯嵌段共聚物包括HTPB-b-PI，C-(PI-b-HTPBn，C-n和PI-b-HTPB-b-PI和丁二烯-苯乙烯嵌段共聚物包括HTPB-b-PS，C-(PS-b-HTPBn，C-n和PS-b-HTPB-b-PS，对嵌段共聚物的结构和性能进行了系统的研究。

Their thermotropic phase behavior was investigated by differential scanning calorimetry and POM. It was found that T(subscript S-N) w and T(subscript N-I), of PMMAZO was slightly increased with the increased of the mass ratio of liquid crystal block segments. PEO and PMMA block affected the liquid cystal behavior of PMMAZO. Meanwhile, PMMA and PMMAZO obviously influenced the crystals property of PEO segments3 which was decreased as the increase of molecular weight of PMMA and PMMAZO segments.

以差示扫描量热仪和偏光显徽镜研究了ABC三嵌段共聚物PEO-b-PMMA-b-PMMAZO的热力学相转变行为，发现随着PMMAZO链段的质量百分比的增加，三嵌段共聚物中PMMAZO链段的T和T逐渐提高；同时，PMMA和PMMAZO链段的长短影响PEO链段的结晶性，随着液晶段PMMAZO和PMMA链段分子量的增加，PEO链段的结晶性减弱。

We prepared a serious of functional polymers with RAFT method.First we synthesize a tri-block polymer.One end is hydrophobic PMMA and the other end is hydrophilic PtAA,the middle is the functional epoxy group,which can be fluorinate by CF_3COOH.

本文运用RAFT方法合成了一系列不同链长比例的三嵌段共聚物：聚—聚—聚(PMMA-b-PGMA-b-PtBMA)，然后利用GMA中含有的环氧官能团，合成含氟的一段，最后将PtBMA一段酸解为亲水段PtAA，即形成了双亲双憎的嵌段共聚物。

DSC and WAXD studies showed that the block copolymers were meltable, and due mainly to the flexible nylon6 segments.

采用DSC热分析的方法，结合WAXD，研究发现，所合成的嵌段共聚物具有可熔融的性质，主要的转变来自柔性的尼龙链段；通过对聚合物空间立体结构的改造，分子链中间位结构的引入以及两嵌段组分分子间和分子内的相互作用强烈影响嵌段共聚物的结晶行为，使结晶更不完善，晶体结构更为疏松，自聚集倾向在很大程度上得到抑制。

The sizes of the self-assembly micelles of the amphiphilic block copolymers and the effects werestudied by dynamic light scattering and UV-visible spectrophotometer. The micelle sizes werelargely influenced bythe hydrophobic chain content in the copolymer, the properties of the solvent and the copolymer concentration in the organic phase. The morphology of the micelles was investigated by transmission electron microscopy. Theresults showed that the micelles appeared spheres with inner core and outer shell. The critical association concentrations were determined by pyrene monomer fluorescence probe technology. The degradability of copolymer was studied by the loss of the intrinsic viscosity in the degradation process. The results indicated that the degradation rate of PECL was slower thanthat of PELLA and PEDLLA. The stability of the copolymer micelle dispersion was examined by measuring the critical flocculation concentration, which gradually decreased with increasing the content of thehydrophobic chain in the copolymer. The rheological results showed thatthe viscosity ofthe micelle dispersion with higher content of PEG segments was firstly decreased and then increased with the increasingthe temperature. Otherwise, the variation of viscosity was irregular. The viscosity of the micelle dispersion increased with the increase of the electrolyte (Na 2SO 4) concentrations. Polymer micelles paclitaxel was prepared by self-emulsification/solvent evaporation method and solid dispersion technique with amphiphilic block polymers as the carrier material.

运用动态光散射和紫外分光光度计研究了两亲性嵌段共聚物自组装胶束的粒径及其影响因素，结果表明，自组装胶束的形成机理受制备方式的控制，胶束的粒径随着共聚物相对分子质量或疏水嵌段相对分子质量和有机相中共聚物浓度的增大而增大，随着有机溶剂的水溶性的增强而减小；采用透射电镜观察胶束的形态结构，发现胶束呈具有核壳结构的均匀球形；采用芘荧光探针法测两亲性嵌段共聚物的临界聚集浓度；通过降解过程中共聚物特性粘度的变化研究两亲性共聚物的降解性能，发现与PELLA和PEDLLA的相比，PECL 降解速率较慢；随着共聚物中疏水嵌段含量的增大，纳米分散液的稳定性逐渐下降；PEG含量高的PEDLLA纳米分散液随着温度的升高，纳米分散液的粘度先下降然后增大，反之，没有规律性，且随着电解质Na 2SO 4浓度的增大，体系粘度增大。

The DPD simulation results show that blending of copolymers is an effective way to control the morphology and inner structure of multicompartment micelles, and block sequence, block ratio, chain architecture and block length all have large effects.

混合体系中，嵌段共聚物的嵌段序列、嵌段比例、嵌段长度和共聚物分子构造都对最终的胶束形貌和结构有着很大的影响。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。