小纤维

The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles

本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究，实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先，利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维，比较不同的热处理温度与反应时间的改变对产物生成产生影响，进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示，结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现，若热处理温度在100~4750C下可得到Cu23Cl奈米粒，475~4900C 可得Cu奈米粒，450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时，可产生直径比较细的纤维，纤维直径为107 88±21 01nm；且由於奈米金属颗粒镶嵌在二氧化矽纤维中，直径比较细的纤维，可以得到比较小的奈米金属颗粒，这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时，由於表面电浆子共震关系，而使纤维颜色由淡白黄绿色变成黄绿色，再变红褐色。由实验结果得知，利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度，可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。

Over time, these small fibres become thinner and less elastic, and some of them break.

随着时间的推移，这些小纤维变薄和少弹性，他们中的一些突破。

The gel dynamics experiments showed that the gel formation law was similar with the other polymer systems, which wasrelated with dense surface under the soft coagulating condition and the thickening gel; the square of gel thickness was linear with coagulation time. The qualitative analysis of the surface puckers of fibers spun from wet spinning and dry-jet wet spinning was made. The positions where the die swell appeared were not the same and the die swell appeared at the air gap where the fiber would markedly been elongated and vary little in the coagulant, thus the surface of fiber spun from dry-jet wet spinning was more smooth. The radial component concentration gradient was responsible for the radial structure of PAN fiber spun from dry-jet wet spinning. The thicker surface with microvoid structure of

对湿纺和干湿纺进行比较表层沟槽的产生进行定性分析，原因在于孔口胀大区域出现在不同位置，在干湿纺中，溶液的孔口胀大出现在空气层，并在该区完成大部分形变，进入凝固浴后形变很小，纤维表面较为光滑；干湿纺PAN纤维径向结构存在差异，这与丝条内组分由于双扩散进行导致径向上存在浓度差异直接相关；凝固强度较大的体系，可以获得厚度较大且孔结构尺寸较小的皮层；含较少缠结的PAN原液在纤维成形后截面很圆整，但原液缠结浓度增大时成形后圆整度下降；PAN纤维成形是一个远离平衡的过程，凝固作用缓和的体系可以使成形过程靠近平衡，可获得更大尺寸的孔洞结构；原液中少量的非溶剂添加剂显著改变纤维径向结构，可获得孔洞尺寸更小和更为均一的径向结构，这与径向浓度差异的减小、分相时间的集中相关；PAN原液的成形纤维表面依赖于凝固强度；由AFM对相近凝固条件下成形的PAN膜进下

Theurinary IL-6 level positively correlated with density of glomerular matrix membrane, global sclerosis, fiber or fibrocellular crescents and interstitial fibrosis (p. 05). According to the degree of density of glomerular matrix membrane and interstitial fibrosis, urinary Col-IV level had better correlation than urinary TGF-betal and IL-6 levels.In IgAN, Col-IV showed increased expression in diseased renal tissue whereas the site of expression of TGF-betal was mainly localized within the cytoplasm of tubular epithelial cells. Interstial expressionwas also present but glomerular TGF-betal expression was found only in patients with heavy mesangial proliferation. There was a significant correlation between glomerular positivity for Col-IV and severity of histological damage. There was also a significant correlation between positivity for TGF-betal and Col-IV in the tubular epithelial and interstitial lesions. In contrast, there was no ralationship between glomerular positivity for TGF-betal and severity of histological damage.The urinary TGF-betal level paralleled tubular TGF-betal expression.

结果 ①IgAN患者尿TGF-β1、IL-6、Col-Ⅳ水平较健康人明显增高(P＜0.01)，该变化与血中的浓度无关(P＞0.05)；②尿TGF-β1水平与小管间质TGF-β1阳性表达呈正相关(P=0.000)，而与小球TGF-β1阳性表达无关(P＞0.05)，尿Col-Ⅳ水平与小球和小管间质Col-Ⅳ阳性表达均呈良好的相关性(P＜0.01)，还与小管间质TGF-β1阳性表达呈正相关(P＜0.05)：③小球Col-Ⅳ阳性表达与肾组织慢性病变密切相关(P＜0.05)，小管间质Col-Ⅳ和TGF-β1阳性表达均与肾小管间质病变呈良好的相关性(P＜0.01)，而小球TGF-β1阳性表达与肾组织损伤无关(P＞0.05)；④尿TGF-β1、Col-Ⅳ水平与肾小球基质基底膜面密度、小管间质病变呈正相关(P＜0.01)，与小球内细胞数呈负相关(P＜0.05)，该结果与其在组织中的表达一致；尿IL-6水平浙江大学硕士学位论文尿TGF一B一、IL一6和Col一IV在IgA肾病中的应用价值与基质基底膜面密度、球性硬化、纤维或细胞纤维新月体所占肾小球百分数及小管间质病变均有显著的相关性(F.05)；在轻度肾病理损伤时，尿'l'G卜pl、I卜6、Col一IV水平即升高，而尿Col一W在反映细胞外基质积聚和间质纤维化程度上比尿TGF一pl和IL一6有更好的相关性。

The fascia might be microscopic, like the tiny fibers that bind individual muscle cells into bundles and hold the skin onto underlying structures; or large, tough, inflexible sheets, like the iliotibial band.

那些筋膜也许是很细小的，就像小纤维一样把相互独立的细胞捆成一束，或使皮肤连成一体，或结成大块、坚韧、牢固的片层，如髂胫带。

As hollow fiber membranes thickness are different, yet urea clearance rate in simulation solution is relatively high, which can reach more than 64% and little difference among them; the BSA have a relatively high rejection, which can be achieved over 98%. There is a certain difference in the Lysozyme clearance rate, the smaller thickness, the higher the rate of removal, and the removal rate of 10μm thickness of the membrane is 29%. The clearance rates of urea were very high using different fiber diameter dialyzers, at around 80%. Urea clearance ratecan reach to the highest 88.6% using 0.26mm fiber diameter dialyzer. The clearance rates of Lysozyme vary greatly, the smaller the diameter, the higher clearance rate, and the highest removal rate of lysozyme is 62.79% using 0.26mm fiber diameter dialyzer. However, there is little impact on the rejection of BSA, which can reach 98%.

不同壁厚中空纤维膜透析器对模拟液中尿素的清除率均可达到64％以上，且差异不大，对牛血清白蛋白的截留率均可达到98％以上，对溶菌酶的清除率有一定的差异，壁厚越小清除率越高，壁厚为10μm的膜对溶菌酶的清除率为29％；不同纤维内径透析器对尿素的清除率均在80％左右，纤维内径为0.26mm的透析器对尿素的清除率最高，达到88.6％，对溶菌酶的清除率差别很大，内径越小，清除率越高，内径为0.26mm的透析器对溶菌酶的清除率达到62.8％，对牛血清白蛋白的截留影响很小，截留率都能达到98％以上。

Covered with fibrils more or less evenly disposed.

由差不多均匀分布的小纤维覆盖。

Xiuyu is a collection of serpentine minerals, is a small fibrous, and the leaf-shaped serpentine crystals, is a very delicate dense block.

岫玉是蛇纹石矿物集合，是一个小纤维，和叶片状蛇纹石晶体，是一个非常微妙的致密块。

In addition ,the paper studied the theory differences between the medium consistency refining and low consistency refining ,discussed the characteristic of medium consistency refining, expounded self-refining effect of small fiber-net in medium consistency pulp rapids on the grounds of laboratory test and production application, explained the advantage of medium consistency refining in mill's application according to the theory,hope to build the basis of research and production of medium consistency refining equipment and technology.

此外，文中还探讨了中、低浓打浆机理的差异及中浓打浆的特性，在中浓纸浆流体特性及试验室小试、中试和生产使用的基础上提出了纸浆湍流剪切力场小纤维网络体的&自打浆效应&新观点，以期为中浓打浆的研究和应用提供理论基础。

The result shows that smooth sizing with some tiny and uniform protuberances can enlarge the surface area of the glass fiber, and increase the wettability of resin to glass fiber, so as to increase the interface properties of the glass fiber/resin composites.

分析结果表明，纤维的表面比较光滑并存在一些小而规整的小突起时，涂层的分布是均匀的，这些小突起有利于增大纤维的表面积，提高纤维表面的粗糙程度，从而增强纤维与树脂之间的结合性能。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。