对苯二胺

According to Griess reaction, diazonium-salts formed from aromatic amines such as sulfonamides etc., react with NaNO_2 in acid medium and may be coupled with α-naphthylamine or diphenylamine to produce red colored compounds.

一按Griess反应芳香族胺类的重氮化鹽，如对氨基苯磺醯胺类药物等，在酸性溶液中皆能与α-萘胺或二苯胺分别偶合成偶氮色素而显紅色，过多之亞硝酸可与氮色素再作用使紅色消失而呈棕黄色。

Some research and analysis on the reaction of 2,4-difluoronitrobenzene and nucleophilic reagent alcohol sodium (methyl alcohol ,ethyl alcohol, propyl alcohol, n-butyl alcohol, t-butyl alcohol, et hl) and the reaction choice of opposite -F in different solvent and conditions have done in this paper.

论文以2，4-二氟硝基苯为主要原料，研究了其与亲核试剂醇钠(甲醇、乙醇、丙醇、正丁醇、叔丁醇等)在不同溶剂中的反应情况，讨论了在几种代表性的溶剂——醇、四氢呋喃、苯、N，N-二甲基甲酰胺中亲核取代反应的情况，研究了温度、反应时间、亲核试剂、溶剂等条件对亲核取代反应的影响。

P-π conjugated polyamic acid was synthesized by the poly-condensation of benzoguanamine and pyromellitic dianhydride under microwave irradiation. Then PAA was grafted with different side-chain containing azobenzol groups through azo coupling reaction.

选取苯代三聚氰胺和均苯四酸二酐为单体进行微波辐射溶液聚合反应，所得的聚酰胺酸与对位取代基不同的苯胺重氮盐偶合接枝，从而合成了一系列新的具有三阶非线性光学活性的侧链型聚合物。

At first, Polyaniline was synthesized by the improved chemical oxidation technique, then, PANI/HCl, PANI/TSA and PANI/DBSA were obtained by doping emeraldine with HCl, 4-methyl benzene sulfonic acid and dodecylbenzene sulfonate acid, separately. Leucoemeraldine was obtained in the N-dimethylformamide by using phenylhydrazine deoxidizing emeraldine in N_2 atmosphere.

本文首先通过改进合成条件的化学氧化法合成了聚苯胺，经氨水脱掺杂获得本征态聚苯胺，再经盐酸、对甲苯磺酸、和十二烷基苯磺酸掺杂，分别获得到质子酸掺杂的聚苯胺样品，然后在N，N-二甲基甲酰胺中，利用苯肼，在N_2氛围下还原本征态聚苯胺得到还原态的聚苯胺。

Investigation of major metabolic pathways of SFZ-47 in animals The metabolites of SFZ-47 in rabbit urine following oral administration were separated and detected with HPLC and LC-MS methods. On the basis of the chromatographic behavior and mass spectra of the metabolites as well as biotransformation pathways of drugs with the partial structure of SFZ-47, the hydroxylic derivative 4-(3H-1, 2- dihydro-1-pyrrolizinone-2-methylamino benzyl alcohol and the carboxylic derivative 4-(3H-1, 2-dihydro-1-pyrrolizinone-2-methylamino benzoic acid of SFZ-47 were proposed as two potential metabolites and were synthesized.

在动物体内主要代谢途径的确定用HPLC和LC-MS对家兔口服SFZ-47后尿中的代谢物进行了分离、检测，根据代谢产物的色谱和质谱行为以及与SFZ-47有类似结构部分的其它药物的代谢途径，推测其羟基衍生物[4-（3H-1，2-二氢-1-吡咯里嗪酮-2-甲基胺基）苯甲醇]与羧基衍生物[4-（3H-1，2-二氢-1-吡咯里嗪酮-2-甲基胺基）苯甲酸]是两种可能的代谢产物，遂用化学方法合成了这两种衍生物。

N,N '- ditertbutyl nitroxyl radical, 2, 2,6,6- tetramethyl-4 - hydroxyl piperdinehy droxylamine and its nitroxyl radical, as inhibitors of the BPO- initiated copolymerization of styrene (M 1 ) with acrylonitrile (M2 ), at 60℃,has been studied.

研究了二叔丁基羟胺，二叔丁基氮氧自由基，2，2，6，6－四甲基－4－羟基哌啶羟胺和2，2，6，6－四甲基－4－羟基哌啶－1－氧自由基对过氧化苯甲酰60℃引发的苯乙烯（M1）－丙烯腈（M2）共聚合的阻聚行为。

A new imidazolinyl intermediate is prepared from phenylacetic acid and diethylenetriamine firstly, and then they react with the solution of sodium chloroacetate into the imidazolinyl quaternary ammonium salt.

以二甲苯为溶剂，苯乙酸和二乙烯三胺为原料，经酰胺化和环化脱水合成了新型咪唑啉化合物，并用氯乙酸钠溶液对其进行改性得到了苯乙酸咪唑啉季铵盐。

The polycondensation of the benzoguanamine and pyromellitic Dianhydride was carried out under microwave irradiation, and the resulted polyamic acid was grafted with TDI-para position substitution aniline derivatives. Thus graft polymers with different electronic effect of the end group in side chain were obtained.

将微波辐射合成的苯代三聚氰胺-均苯四酸二酐体系的PAA与TDI-对位取代苯胺衍生物反应，通过改变TDI－对位取代苯胺衍生物的对位取代基来合成具有不同电子效应的侧链端基的接枝聚合物。

Results Eleven compounds were obtained and identified as sarcodonin A, scabronine B, 3β-hydroxy-5α, 8a-epidioxyergosta-6, 22-dien,(22E, 24R)-ergosta-7, 22-diene-3β, 5α, 6β-triol,(22E, 24R)-ergosta-7, 22-diene-3β-ol, benzoic acid, 4-hydroxylben-zaldehyde, 4-monopropanoylbenzenediol, ethy1-β-D-glucopyranoside, thioacetic anhydride,(2S, 2'R, 3S, 4R)-2-(2-hydroxyoctadecanoylamino) docosane-1, 3, 4-triol.

结果共分离鉴定了11个化合物，分别是：sarcodonin A、scabronine B、3β羟－5α，5α-过氧麦角甾－6，22-二烯－3β-醇、(22E，24R)-麦角甾－7，22-二烯－3β，5α，6β三醇、(22E，24R)-麦角甾－7，22-二烯－3β-醇、苯甲酸、对羟基苯甲醛、对羟基苯甲酸乙酯、乙基－β-D-吡喃葡萄糖苷、硫代乙酸酐、（25，2'R，3S，4R）-2-（2-羟基－十八碳酰胺）二十二碳烷－l，3，4-三醇。

Latest researches in the catalysts for synthesis of carbamate by ammonolysis of dimethyl carbonate;2. Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate;3.4,4′-Methylene diphenyl carbamatewas synthesized by ammonolysis of dimethyl carbonate, a substitute of phosgene, and 4,4′-diaminodiphenyl methane with anhydrous zinc acetate as catalyst.

用碳酸二甲酯代替光气，以4，4′-二氨基二苯基甲烷为原料，在无水醋酸锌催化剂的作用下，经胺解反应合成了4，4′-二苯甲烷二氨基甲酸甲酯；测定了MDC的熔点；采用傅里叶变换红外光谱和氢核磁共振对产品结构进行了表征；考察了反应温度、DMC用量、反应压力、反应时间、催化剂用量对MDC收率的影响。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。