对映的

SAA ligand Lh could induce asymmetric addition of terminal alkyne to aldehydes without using air-sensitive Ti4and expensive Zn2.with good result of high yield (up to 99%) and good enantioselectivities (up to 84%ee).

将SAA配体Lh应用于在无Ti_4和Zn_2的条件下促进端基炔对醛的不对称加成反应中，反应的收率普遍较高，最高达99%，对映体选择性高达84%ee。

Omeprazole racemate was resolved respectively by simulated moving bed chromatography and batch chromatography with the coated cellulose triphenylcarbamate as chiral stationary phase and ethanol containing 0.1% diethylamine as mobile phase.

用纤维素三苯基氨基甲酸酯涂敷型手性固定相和含0.1%二乙胺的乙醇溶液，研究了模拟移动床色谱和间歇色谱对奥美拉唑对映体的拆分。

Theoretical studies on various geometrical structures of Hypophosphorous acid were carried out using DFT theoretical methods,at the B3LYP/6—311++G** level.Intramolecular proton transfer isomerization has also been studied using the intrinsic reaction coordinate.

采用量子化学密度泛函B3LYP方法，在6—311++G**基组水平上全优化得到了硫代次磷酸的硫酮式和硫醇式两种构型异构体以及相应的对映异构体，同时对分子内质子转移异构化反应微观机理进行了理论分析。

Theoretical studies on various geometrical structures of Hypophosphorous acid were carried out using DFT theoretical methods, at the B3LYP/6-311 ++ G(superscript **) level. Intramolecular proton transfer isomerization has also been studied using the intrinsic reaction coordinate.

采用量子化学密度泛函B3LYP方法，在6-311++G基组水平上全优化得到了硫代次磷酸的硫酮式和硫醇式两种构型异构体以及相应的对映异构体，同时对分子内质子转移异构化反应微观机理进行了理论分析。

Chiral centers of C5 and C8 are directly constructed in the key step of the diastereoselective propargylation from D--tartrate. The methylation and subsequent methoxycarbonylation result in desymmetrization of the terminal dialkynes. The α,β-unsaturated δ-lactone is synthesized after partial hydrogenation and lactonization.

由非天然酒石酸出发，利用双向非对映选择性的炔丙基化反应，在一步反应中同时构建C5和C8手性中心；然后通过末端炔基的甲基化、甲酯基化，延长碳链并对分子去对称化；内酯化得到关键中间体α，β-不饱和六元内酯，再经多步反应转化得到8-epi--Boronolide。

Some studies showed that SPs display toxicity to wildlife and human nervous systems. It may cause acute and chronic neurotoxicity to mammal, and the stereoisomeric structure of SPs affects mammals neurotixicity. There was some enantioselectivity of SPs in acute and chronic neurotoxicity to mammal.

已有研究结果显示拟除虫菊酯类农药对非靶标野生动物和人类的神经系统有一定的毒性作用，其对哺乳动物的神经毒性主要表现为急性和慢性神经毒性，而且其毒性作用与拟除虫菊酯类农药的立体结构相关，有一定的对映体选择性差异。

SAA ligand Lg could catalyze asymmetric addition of phenylacetylene to unactivated aromatic ketones in high yields (up to 83%) and high enantioslectivities (up to 83%ee).

SAA配体Lg用于催化炔基锌对未活化酮的不对称加成反应，对于芳香酮的催化反应，收率可达83%，对映体选择性可达83%ee。

E. . The epoxidation of cis-allylic alcohols is difficult, and with 20％mol Ti 〓 and 30％mol tartrates, up to 80％e.

的对映选择性被得到；对难于环氧化的顺式烯丙基醇，使用20％mol四异丙氧基钛和30％mol酒石酸酯得到最高80％e.e。

Firstly, synthetic racemates of β- amino acids were resolved into their enantiomers by ehiral ligand - exchange flash chromatography with L - hydroxyproline chemically bonded to irregular silica as the stationary phase and aqueous solution containing cupric ions as the mo

首先合成L-羟脯氨酸硅胶键合手性固定相，用于快速色谱中3-羟基-4-甲氧基-β-苯丙氨酸对映体的制备分离，考察了流动相中Cu^2＋浓度、样品体积等因素对分离的影响。

Furthermore, the effects of ligands, metal and reaction time on the reaction were also researched, and the process of new ligand-metal catalysis for Diels-Alder reaction was also analyzed according to Evans" square planar mode and Corey"s tetrahedral manner.

我们对影响配体对映选择性能的各种因素，如配体结构、金属离子、反应时间等进行了研究，而且根据Evans的平面四方形模式与Corey的四面体过渡态理论为新配体—金属配合物催化的该反应提出了可能的反应机理，并对产物的优势构型作了理论分析。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！