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The effects of some factors, such as reaction temperature, reaction time, substrate concentration and yeast concentration, on the acetophenone conversion and- 1-phenylethanol enantioselectivity were investigated by orthogonal experiments.

研究了酵母细胞催化芳香酮的不对称还原反应,采用正交试验综合考察了反应温度、反应时间、底物浓度和酵母浓度等因素对底物苯乙酮转化率和产物1苯基乙醇对映选择性的影响。

The ability of the chiral bis-imidazolium salt for asymmetric catalytic benzoin condensation has been probed. It has shown good catalytic activity for benzoin condensation, but no enantioselectivity has been detected.

探讨了手性双咪唑鎓盐不对称催化苯偶姻缩合反应的性能,结果表明其对苯偶姻缩合反应具有高的催化活性,但未能显示对映选择性。

Discussion of what the identity of the carvone enantiomer tells you about the identity of the limonene in your sample.

讨论一下香芹酮对映体的鉴定对你样品中柠檬烯的鉴定有什么启示。如果有的话

In the asymmetric hydrogenation of ethyl pyruvate catalyzed by 0 5% Rh/PVP TiO 2, the chiral modifier cinchonidine not only induces the enantioselectivity, but also accelerates the reaction rate greatly.

研究了辛可尼定作手性修饰剂修饰的负载型纳米铑簇合物催化剂(0 5 %Rh/PVP TiO2 )催化丙酮酸乙酯不对称氢化反应,在该反应中手性修饰剂辛可尼定不仅具有对产物生成的手性诱导作用,而且对反应具有明显加速作用;在优化反应条件后,反应的TOF和对映选择性分别可以达到 5 8 0min-1和

Effect of kieselguhr on enantioselectivity of enzymatic hydrolysis of chiral dichlorprop methyl ester (2,4-DP) has been specifically studied by chiral gas chromatography.

利用手性气相色谱技术研究了硅藻土吸附作用对-2,4-二氯苯氧丙酸甲酯(2,4-DP)酶促水解对映体选择性的影响。

Objecdt ive Synthesis of molecularly imprinted polymer membrane to separate racemate of amino acid hydantoins.

合成了可对氨基酸海因对映异构体选择性分离的分子印迹聚合物膜。

The preparation of a novel chiral sulfonamide alcohol derived from natural camphor and its application in the titanium tetraisopropoxide-promoted enantioselective addition of diethylzinc to benzaldehyde is described.

由天然樟脑合成了一个新手性磺酰胺醇,并对其在二乙基锌对苯甲醛的对映选择性加成中的催化性能进行了研究,获得了73%化学产率和

A HPLC method for chiral separation of citalopram hydrobromide enantiomers and optical puritydetection of escitalopram oxalate was established.

利用Chiralpak AD-H手性柱建立了氢溴酸西酞普兰对映体HPLC手性拆分的方法,同时对草酸依地普仑进行了ee值检查。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体,合成了七{2,6-二-O-[3-(1,3-二羟基丙氨酸)]}-β-环糊精,再用醋酸酐将其乙酰化,得到了一种淡黄色粘稠液体,合成了一种新型的环糊精衍生物;以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物,再将其烷基化和酰基化,合成了β-环糊精聚合物的不同衍生物,用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上,通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究,结果表明所合成的β-环糊精衍生物对各类化合物,特别是对位置异构体和对映异构体具有较好的分离效果,显示了很强的立体选择性。

Separation of racemic mixtures of benzyl glycidyl ether was achieved with HPLC by using Chiralcel OD as chiral stationary phase and hexane/2-propanol mixture of different ratios as eluents.

在 Chiralcel OD多糖类手性固定相上,以各种不同配比的正己烷-异丙醇为洗脱剂,对苄基缩水甘油醚的外消旋体进行对映体拆分,考察了不同洗脱剂配比、柱温和流速对分离度和出峰时间的影响。

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She gently rebuff ed him, but agreed that they could be friends

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If in the penal farm, you were sure to be criticized.

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