对映的

Under the optimized conditions, in-situ-generated N,N -dioxide from the corresponding amide (10 mol%) and m-CPBA (20 mol%) retained the same asymmetric catalytic activity and enantioselectivity, and most of the aromatic,α,β-unsaturated, heterocyclic, aliphatic and steric hindrance ketones could be converted into the corresponding cyanohydrin trimethylsilyl ethers in up to 99% yield and 93% ee.

底物扩展证明，该有机小分子催化体系对芳香酮、杂芳香酮、脂肪酮、位阻酮以及α，β-不饱和酮都具有优良的手性诱导能力，收率高达99％，对映选择性达93％ee。

The influences of the composition of mobile phase, the flow rate, the temperature and the injected quantity on the enantiomer rententivity and selectivity were examined and discussed.

考察了流动相组成、流速、进样量和温度等因素对对映体分离的影响。

The total synthese three natural compounds to explore enantioselective synthesis of flavanol: We use phloroglucin and 2, 4, 6-trihydroxyacetophone as starting materials to synthesis distenin in two ways; Resorcin was used to synthsis 2, 5-dimethoxymethoxyacetophone though 3 steps.

对黄烷醇化合物的立体选择性全合成进行了探索：以间苯三酚和2，4，6-三羟基苯乙酮为原料，尝试用两条路线对Distenin化合物进行了全合成研究；以对苯二酚为原料，经三步制得2，5-二甲氧甲氧基苯乙酮，与2，4，6-三甲氧甲氧基苯甲醛反应，经四步反应得到天然产物3，5，7，2′，5′-二五羟基黄烷关键中间体1-（2′，6′-二甲氧甲氧基苯）-3-（2"，4"，6-三甲氧甲氧基苯）丙烷-1R，2R-二醇83及其对映体84；简要介绍了EGCg类化合物的生物活性和研究概况。

Based on the common symbolic dynamic method, a novel time-varying symbolic dynamic method is proposed. The Logistic map is used to test the properties of the method.

本文在符号动力学方法的基础上，对映像系数进行修正，针对耦合单峰Logistic映射，提出一种基于时变映像系数恢复信号初值的新方法。

The total synthese three natural compounds to explore enantioselective synthesis of flavanol: We use phloroglucin and 2, 4, 6-trihydroxyacetophone as starting materials to synthesis distenin in two ways; Resorcin was used to synthsis 2, 5-dimethoxymethoxyacetophone though 3 steps.

对黄烷醇化合物的立体选择性全合成进行了探索：以间苯三酚和2，4，6-三羟基苯乙酮为原料，尝试用两条路线对Distenin化合物进行了全合成研究；以对苯二酚为原料，经三步制得2，5-二甲氧甲氧基苯乙酮，与2，4，6-三甲氧甲氧基苯甲醛反应，经四步反应得到天然产物3，5，7，2′，5′-二五羟基黄烷关键中间体1-（2′，6′-二甲氧甲氧基苯）-3-（2&，4&，6-三甲氧甲氧基苯）丙烷-1R，2R-二醇83及其对映体84；简要介绍了EGCg类化合物的生物活性和研究概况。

Expanding pinacol reductive coupling reaction into asymmetric one with both diastereoselectivity and enantioselectivity may lead to its application in synthesising medicaments and biologic active compounds with structure of vicinal diol. Asymmetric pinacol coupling reaction is also the most compact and effecient method in synthesizing chiral ligands or chiral auxiliary with C〓 symmetry.

将这一反应发展成为既有高度的非对映选择性，又有高度对映选择性的不对称偶联反应在合成许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用，同时不对称Piancol偶联反应也是合成C〓对称性的邻二醇多用途手性配体或手性助剂的最为简捷有效的方法。

The invention includes all sterioisomeric forms, including individual diastereoisomers and enantiomers of the compound of formula as well as racemic and non-racemic mixtures thereof.

本发明包括式化合物所有的立体异构形式，包括单个的非对映异构体和对映异构体，及其外消旋的和非外消旋的混合物。

Resolution and preparation of ethofumesate enantiomers were achieved under the optimal semi-preparation conditions. The chemical structure of two elutes were identified by GC-MS, the optical property and the eluting order were determined by using the Circular Dichroism detector and polarimeter.

在优化的半制备色谱条件下，完成了乙氧呋草黄对映体的拆分、收集和制备，两个组分的化学结构经GC-MS确证，光学性质和流出顺序用圆二色检测器和旋光仪进行测定，获得了光学纯度超过97%的左旋和右旋对映体。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应，高度非对映选择性地一步控制了含有季碳的三个相邻立体中心，有效地构建了&2-季碳1，3-二醇&结构单元，首次实现了此类重排—还原过程的催化循环，其中对于两个C1位的差向异构体底物，此反应具有明显的非对映选择性放大特点。

Though enantioslectivity in the epoxidation of some substrates with soluble polymer-supported tartrates is a little lower than that with solution-phase tartrates, it is higher than enantioslectivity with insoluble polystyrene resin-supported tartrates, linear poly s and corrosslinked poly s. It is obvious that soluble polymer-supported tartrates have good catalytic activity and enantioselectivity.

尽管可溶性聚合物支载的酒石酸酯在某些底物环氧化中的对映选择性比小分子酒石酸酯低一些，但明显优于文献报道的不溶性聚苯乙烯树脂支载的酒石酸酯、线形聚酒石酸酯和交联聚酒石酸酯配体，显示了良好的催化活性和对映选择性。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！