对映异构的

The thermodynamic parameters in the separation of enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were calculated and the dissociation constants of cinchonine and cinchonidine on the cinchonine imprinted monolithic disk were determined by frontal analysis.

计算了氨基酸衍生物对映体以及辛可纳非对映异构体分离过程的热力学参数并利用前沿色谱法测定了辛可宁和辛可尼丁在盘状分子印迹整体柱上的离解平衡常数。

Results: Under the experimental conditions adopted, the baseline separation of ephedrin and ephedrine levorotatory was obtained.

结果：麻黄碱及伪麻黄碱对映体得到良好分离，并满足进行左旋麻黄碱中对映异构体杂质检查所需要的条件。

Objecdt ive Synthesis of molecularly imprinted polymer membrane to separate racemate of amino acid hydantoins.

合成了可对氨基酸海因对映异构体选择性分离的分子印迹聚合物膜。

The minimal energy conformations of host-guest complexes were obtained with Tripos force field. Molecular dynamics simulations were carried out to investigate chiral molecular recognition and the distribution of hydrogen bonds. The energies of recognition system were calculated with MM+ force field as well.

首次将分子力学方法引入卟啉的手性分子识别领域的研究；用Tripos力场研究了主客体配合物最低能量构象，比较了同一主体与互为对映异构体的两个氨基酸甲酯形成的配合物的能量差异；用分子动力学模拟方法研究了手性分子识别行为及体系的氢键分布；用MM+力场研究了识别体系的能量。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2，2'-二取代的联萘衍生物在手性构型上高度稳定的特点，分别从光学活性的-和-2，2'-二乙炔基-1，1'-联萘结构模板出发，通过Sonogashira偶连反应导入苄基碸，然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子－对映异构体-3和-3。

Based on the results of this report and the results of literature reports on the preferred conformation of enantiomeric 3-substituted-1, 4-benzodiazepines, a nucleophilically solvated C3 carbonium ion intermediate resulting from either a P or a M conformation is proposed to be an intermediate.

基於本文所报导的结果及文献所记述之对映异构性在C3位有取代基时的1，4-苯并二氮类的倾向构象，设想提出所观察之现象是由正或负构象所致的一个亲核性经溶剂化的C3阳碳离子为中间体。

Treatment of dials with N-tert-butanesulfinamide, all biaryl dials were successfully converted into the corresponding bis-imines which were then treated with samarium diiodide to afford diamine products. The absolute configurations of all the intramolecular coupling products were determined by X-ray crystallography.

轴手性二醛与N-叔丁基亚磺酰胺缩合得到相应的亚胺，其为一对非对映异构体。N-叔丁基亚磺酰亚胺在二碘化钐条件下得到的偶联产物，经X-衍射也确定了其立体构型。

The yields and ees obtained in the AD reaction of eight olefins utilizing 10 in PEG/NMO system were 72～90% and 79～96%(except for trans-5-decene and ally naphthyl ether).

3配体10和配体8是一对假对映异构体，在AD反应中立体选择面相反，可得到相反构型的产物。

It was found that manganese porphyrins linked with stable nitroxyl radials could oxidize sulfides using NaOCl as the oxidant to give the corresponding sulfoxides in good to excellent yields (80-97%) with high chemoselectivity and diasteroselectivity (dr≥7:1 for glycosyl sulfoxides).

发现连有稳定氮氧自由基的卟啉锰络合物对NaOCl选择性氧化各种硫醚底物有较好的催化效果，获得了高的产率(80％～97％)、化学选择性和非对映选择性(糖基亚砜非对映异构体的比例大于7：1)。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体，合成了七{2，6-二-O-[3-(1，3-二羟基丙氨酸)]}-β-环糊精，再用醋酸酐将其乙酰化，得到了一种淡黄色粘稠液体，合成了一种新型的环糊精衍生物；以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物，再将其烷基化和酰基化，合成了β-环糊精聚合物的不同衍生物，用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上，通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究，结果表明所合成的β-环糊精衍生物对各类化合物，特别是对位置异构体和对映异构体具有较好的分离效果，显示了很强的立体选择性。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！