对映体

Under appropriate conditions, the conversion of acetophenone could be as high as 100% and the enantiomeric excess of-1-phenylethanol exceeded 99.0%.

在合适的条件下底物苯乙酮的转化率高达100%，产物-1-苯基乙醇的对映体过量值大于99.0%。

Chiral N,P ligand 5 was examined for the asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with up to 89% yield and up to 81.6% ee.

化合物5用于钯催化的1，3-二苯基-2-烯丙基乙酸酯的不对称烯丙基烷基化反应，产率为89%，对映体过量最高为81.6% ee。

With the development of life science and biological engineering, chiral separation and recognition have been payed close attention universally ,which have important significance in organic chemis- try, life science and medicinal chemistry.

随着生命科学和生物工程的发展，手性拆分和手性识别引起了人们的普遍关注，研究对映体拆分与识别对有机化学、生命科学和医药工业均具有十分重要的意义。

Omeprazole racemate was resolved respectively by simulated moving bed chromatography and batch chromatography with the coated cellulose triphenylcarbamate as chiral stationary phase and ethanol containing 0.1% diethylamine as mobile phase.

用纤维素三苯基氨基甲酸酯涂敷型手性固定相和含0.1%二乙胺的乙醇溶液，研究了模拟移动床色谱和间歇色谱对奥美拉唑对映体的拆分。

A HPLC method for chiral separation of citalopram hydrobromide enantiomers and optical puritydetection of escitalopram oxalate was established.

利用Chiralpak AD-H手性柱建立了氢溴酸西酞普兰对映体HPLC手性拆分的方法，同时对草酸依地普仑进行了ee值检查。

In this paper, the enantioseparation of naringenin was firstly studied by using CDMPC chiral stationary phase.

首次在纤维素三(3，5二甲苯基氨基甲酸酯)手性固定相上，对柚皮素进行了对映体分离研究。

Using THz absorption spectra can distinguish different kinds of amino acids, enantiomers and racemic compounds and structure isomers.

这一研究对建立氨基酸THz谱数据库，及其在氨基酸的手性对映体、结构和成分的区别方面有很重要的理论与实践意义。

The facts indicate that apart from the asymmetric induction of chiral diamine backbone,sterically hindered substitute groups on the aromatic rings,and the presence of sp~3-hydridized amino donors and its N,N\'-disubstituted groups in chiral SalanCrX complexes all play important roles in controlling polymer stereochemistry and enantioselectivity.

研究发现除了手性二胺骨架的不对称诱导作用，苯环上的大位阻取代基、N，N\'-二取代基的位阻作用以及N原子上sp~3杂化的供电子效应都对调控聚合物的区域和对映体选择性有很大作用。

In our study, the synthesis of spice and the resolution of racemates menthol,(R, 5-4-hydroxy-3-methyl-2-(2-propenyl)-2-cyclopenten-1-one (R, S-HMPC were achieved in ionic liquids by three lipase that are usually used in biocatalysis. Meanwhile, some problems associated with enzyme catalysis in ionic liquids were also addressed.

本论文以三种常用于生物催化的脂肪酶作催化用酶，在&绿色&反应介质—离子液体中实现了香料的合成和手性对映体的拆分，同时也对酶在离子液体中催化所存在的问题进行了一些探讨。

Firstly, synthetic racemates of β- amino acids were resolved into their enantiomers by ehiral ligand - exchange flash chromatography with L - hydroxyproline chemically bonded to irregular silica as the stationary phase and aqueous solution containing cupric ions as the mo

首先合成L-羟脯氨酸硅胶键合手性固定相，用于快速色谱中3-羟基-4-甲氧基-β-苯丙氨酸对映体的制备分离，考察了流动相中Cu^2＋浓度、样品体积等因素对分离的影响。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。