对映体

Discussion of what the identity of the carvone enantiomer tells you about the identity of the limonene in your sample.

讨论一下香芹酮对映体的鉴定对你样品中柠檬烯的鉴定有什么启示。如果有的话

The results of the reaction show that better regioselectivity is obtained when Cd2+ is used as additive and give stereoselective product when cinchonine is used as chiral additive.Keywords: NaBH4, Regioselective,Stereoselective,Benzoyl acetone,Metal ion

结果发现，不同的金属离子添加剂使反应出现不同的化学选择性，而Cd2+离子对苯甲酰丙酮的还原具有较好的化学选择性，同时在辛可宁存在条件下得到了对映体过量的产物。

A nonaquous capi l l ary e l ecbophoretic chira l separation of l , l '-bi-2-naphtho l with a new chira l se l ector N-benzy l cinchonine ch l oride is described in this paper.

利用新的手性选择剂苄基氯化辛可宁，在非水相中成功地分离了联萘酚对映体，并对分离的机理作了初步地探讨。

AIM: To compare the separation ability of different neutral cyclodextrins and their derivatives on ofloxacin enantiomer by capillary electrophoresis and to explore the possible mechanisms of chiral separation.

目的：比较在毛细管电泳中不同中性环糊精及其衍生物对氧氟沙星对映体的手性拆分能力，并提出可能的手性识别机制。

The influences of the composition of mobile phase, the flow rate, the temperature and the injected quantity on the enantiomer rententivity and selectivity were examined and discussed.

考察了流动相组成、流速、进样量和温度等因素对对映体分离的影响。

In addition, adsorption of the pesticide on kieselguhr decreased "free pesticides", which also enhanced the enantioselectivity of hydrolysis of 2,4-DP.

此外，硅藻土吸附作用对农药底物的束缚引起处于"自由状态"的底物减少，也使酶促反应的对映体选择性略有增强。

Effect of kieselguhr on enantioselectivity of enzymatic hydrolysis of chiral dichlorprop methyl ester (2,4-DP) has been specifically studied by chiral gas chromatography.

利用手性气相色谱技术研究了硅藻土吸附作用对-2，4-二氯苯氧丙酸甲酯(2，4-DP)酶促水解对映体选择性的影响。

Methods: The cyclodextrin, concentration, pH, organic solvent were studied, and the results indicated that the enantiomer of ephedrin and ephedrine levorotatory were baseline separated under the following experimental conditions: uncoated fused silica capillary (75 μm× 68 cm), 25 mmol/L Tris, 2% HP-β-CD and 1% SBE-β-CD, pH was adjusted at 3.0 by phosphoric acid, and 15 kV separation voltage.

以SBE-β-CD和HP-β-CD二元环糊精为手性添加剂，探讨了环糊精种类及浓度、pH、有机溶剂种类等因素对麻黄碱及伪麻黄碱对映体拆分的影响，结果表明：毛细管：未涂渍熔融石英毛细管75μm×68 cm（有效长度60 cm）。分离用缓冲液为25 mmol/L的Tris缓冲液，含2.0% HP-β-CD和1.0% SBE-β-CD，用磷酸调节pH至3.0。

About the identity of the limonene in your sample.

讨论一下香芹酮对映体的鉴定对你样品中柠檬烯的鉴定有什么启示。

Chiral separation of D -, L -phenylglycine by RP-HPLC was accomplished by adding a complex of optically active L -Phe-Cu2+ to the mobile phase. Chiral separation mechanism was further elucidated in light of unambiguously assigning the structure of the elutents from RP-HPLC by taking advantage of tandem mass spectrometry due to its unique capability of structural identification of the unknows.

以含 L -苯丙氨酸铜配位络合物的溶液作为手性流动相，采用反相高效液相色谱法拆分了非衍生苯甘氨酸对映体，使用质谱对拆分组分进行了结构鉴定，得到了拆分组分的化学结构，用量子化学计算预测了该结构的最稳定构象。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。