富集的

The preventive measures for the harmful defects of alkali metals are as follows: 1, reducing the alkali metals content in the raw materials; 2, increasing the MgO content of the sinter , decreasing the basicity of slag , decreasing the Si content of the pig iron, increasing relative slag volume; 3 , introducing prereduced ore pellets or partly reducted sinter; 4increasing the ability of coke resisting alkali metals; 5, using refractories that have the ability of resisting corrasion of alkali metals; 6 , cleaning the blast furnace periodically. The above recommendations are necessary for decreasing the circulation and accumulation of alkali metals effectively in blast furnace, reducing the harmful influence of alkali metals on blast furnace, increasing the smelting intensity, decreasing the coke rate, improving the gas permeability.

基于碱金属对高炉冶炼的上述危害，本文结合湘钢高炉的实际生产情况，通过理论分析、计算以及其他钢厂防治碱害的经验，提出防治高炉碱害的措施：1、减少入炉原、燃料的碱金属含量；2、提高烧结矿中的MgO含量、降低炉渣碱度、降低生铁含硅量、适当增加渣量；3、采用预还原的金属化球团或部分还原的烧结矿；4、提高焦炭的抗碱能力；5采用抗碱侵蚀的耐火材料；6、周期性性洗炉，以有效地减少碱金属在高炉内的循环富集，降低碱金属对高炉的危害，提高高炉的冶炼强度，降低焦比，改善高炉透气性。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

According to the life form of species and their roles in communities, 6 species groups are used to do ordination analysis and environmental interpretation. The result suggests that:①Despite the strong man-made disturbance at lower altitude sites, the number and character of evergreen species show an change along the altitude gradient.②The rare and endangered species concentrated at two sectors along altitude gradient, corresponding to the upper and lower borders of the mountain mixed forest belt of evergreen and deciduous broad-leaved species.③The pioneer tree species concentrated on the middle and upper positions at lower elevation.④The deciduous accompany tree species show a great diversity on middle and lower position at middle and higher elevation.⑤Coniferous species differentiate along elevation and local topographical gradient.⑥Deciduous species in Quercus, Castanea, Fagus, Carpinus genus as well as coniferous species play primary community-constructing roles at different topographical position at Dalaoling region.

根据物种生活型及其在植物群落中的地位，分6个种组进行排序和环境解释，表明：①尽管低海拔地段受到强烈人为干扰，常绿种类仍显示了数量和性质沿海拔梯度的变化；②珍稀物种在海拔梯度上形成两个相对集中的区段，大致对应于山地常绿落叶阔叶混交林带的上下边缘；③先锋树种在中低海拔的中上坡位富集；④在中、高海拔的中低坡位，落叶的乔木伴生种显示了极大的多样性；⑤为数不多的针叶树种在海拔和局部地形梯度上也有明确分异；⑥它们和落叶的栎、栗、水青冈、鹅耳枥属物种在大老岭地区不同地形部位的植被中起着主要的建群作用。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80～100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100～300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能，且合金内的V元素会向表面富集，因此，钛合金真空热处理和表面涂层的烧结温度不能过高，即应低于其相转变点；通过对生物活性梯度涂层的组成和结构的设计，分析和计算了梯度涂层内的应力大小和分布，结果表明：对于本研究，当成分分布系数n=1.5时，可以获得较合理的涂层力学性能，即在沉积开始时，采用富含BG颗粒的悬浮液，以便在钛合金侧获得同底层BG有良好过渡的富BG涂层；梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定，改变成分分布系数，只能改变涂层内应力变化的趋势；涂层的厚薄不影响涂层内的应力分布规律，但涂层越薄，涂层内的应力变化越快，但这并不意味着涂层越厚越好，因为涂层越厚，涂层允许的变形越小，对于应用于弯曲受力部位的涂层而言，涂层应薄一点为好(50μm)；而对于仅纯受剪切应力的部位，如牙根种植体，涂层可适当加厚(80～100μm)；通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现，它们在水溶液体系中很难发生电沉积；在无水乙醇溶液中，HA颗粒带正电，可在阴极钛合金片上发生均匀的电泳沉积，而BG颗粒则带负电荷；利用复分解反应法，可以制得100～300nm的HA，通过诱导HA在BG颗粒表面结晶，可对BG颗粒进行表面包覆，获得了被HA包覆的BG颗粒，改变了BG颗粒表面的带电特性，使BG和HA颗粒在无水乙醇中均带上正电荷，从而实现了HA和BG颗粒在阴极上的共沉积。

According to the above study result, the diversity of microorganisms population in the SUFR system is complex and the bio-community formed in the SUFR system is stable. The close relations between abundance of bacteria and nutrients were found. The correlation between heterotrophic bacteria and COD was 0.949. The correlation between organic phosphate bacteria and TP was 0.815. The correlation between nitrosobacteria and NH3-N was 0.909. The correlation between disnitrifier bacteria and TN was 0.653. These inneglectable great factors effecting on phosphorus-uptake and phosphorus-release of phosphorus accumulating organisms are the influent COD、the concentration of DO、the sludge retention time、the temperature. The diversity of organic phosphate bacteria population in the SUFR reactor was complex and there is no phosphate bacteria taking the absolute superiority in quantity. The near-native pure culture method powerfully complement the traditional pure culture technique and enrich culture technique. The sludgy bioactivity is very good in whole SUFR reactor. By the quality of being biochemistry, the anaerobic phase is higher than anoxic phase and the anoxic phase is higher than aerobic phase of SUFR.

通过以上试验内容研究发现，SUFR 系统中的微型动物种群较多，微生物生态系统稳定；系统中微生物的数量与营养盐的含量密切相关，其中总异养菌与COD的相关系数r 为0.949，有机磷细菌与TP 的相关系数r 为0.815，亚硝化菌与NH4+-N的相关系数r 为0.909，反硝化菌的数量和TN 的相关系数r 为0.653；污水生物除磷工艺中进水COD 的浓度、DO 浓度、泥龄的长短、温度都是影响聚磷菌释磷及吸磷效果的不可忽视的因素；SUFR 系统中的磷细菌呈现种群多样化的趋势，没有占绝对优势数量的磷细菌；微孔滤膜近自然培养法是对传统纯培养技术和富集培养技术的有力补充；整个SUFR 反应器系统中污泥的生物活性很好，就可生化性来讲，厌氧反应器大于缺氧反应器大于好氧反应器；按照动力学方程式求出的细胞生长动力学特征值和SUFR 脱氮除磷系统工艺的实测值结果基本吻合。

Lithologies are mostly sand and carbonate rocks, caps are mud rock, shale and magmatite. Entrap types are anticline, fault block rebuilt by breaking and the screened entrap diapered rock mass. The composition is CO_2, N_2, CH_4, C_2H_6 and He etc. It is magma air source body and its geologic fashions are intrusion and buried volcanic conduit. The relations between gas reservoirs and gas source bodies have three types: magma intrusion-breaking-communicated gas reservoir, magma intrusion-contacted CO_2 reservoir and buried volcanic conduit-contacted gas reservoir. The CO_2 migration in magma intrusion is consisted of fusing and crystallizing phases;it in volcanic conduit is consisted of near-surface effusion and crystallizing phases.The buoyancy of CO_2 in water far more than migration resistance in breaking or chink, CO_2 is easy float upward, the floating can results in differentiation of different density gases and concentration of sealed gas. The gas in sand reservoir firstly migrate into the higher porosity and coefficient of permeability sand, and along with the pressure going up it migrate into the lower. In magma intrusion-breaking-reservoir migration, CO_2 firstly migrate into watered breaking, began gravity differentiation and concentrate, the gas pressure time and again go up, CO_2 migrate into reservoir and concentrate under expansibility as the pressure reach upward a given extend. The CO_2 in reservoir experience four breaking modes: chemistry deposition, dissolution, diffusion and mechanic breaking, the pressure balance can be broken by faulting and the CO_2 will further migrate and form new reservoir.

济阳坳陷已发现的八里泊、阳25、平方王、平南、高青、花17 CO_2气藏主要储集层位有奥陶系、中生界、沙四段、沙三段、沙一段、馆陶组和明化镇组，储集层岩性以砂岩和碳酸盐岩为主，盖层以泥质岩、页岩和岩浆岩为主。；圈闭类型主要为受断裂改造的背斜、断块及刺穿岩体遮挡圈闭。；气体成分主要有CO_2、N_2、CH_4、C_2H_6、He等。；主要气源体为岩浆气源体，气源体的主要地质形式为侵入体和埋藏的火山通道。；气藏和气源体的空间关系有岩浆侵入体一断裂一气藏沟通型、岩浆侵入体-CO_2气储集层接触型和埋藏火山通道-气储集层接触型三种类型。；岩浆侵入体CO_2气运移分为熔融运移阶段和结晶运移阶段，火山通道中CO_2气运移分成近地表喷发阶段和结晶运移阶段。；断裂中，CO_2在水中的浮力远大于运移阻力，CO_2气容易上浮，CO_2在断裂中的易浮性导致不同密度气体的分异和走向上封闭的断裂气体相对富集。；气体在砂岩储集层运移聚集具有选择性，会优先进入孔隙度和渗透率较高的砂岩，随着压力增加，才会进入孔隙度和渗透率较低的砂岩；在岩浆气源体-断裂-储集层空间输导格架下，CO_2气在膨胀力的驱动下，首先进入含水的断裂并重力分异而聚集，气体压力会不断增高，当压力增至一定程度，CO_2气会向高孔隙度、渗透率的储集层运移并聚集。；在岩浆气源体-储集层接触空间输导格架下，CO_2气受膨胀力的驱动直接向储集层运移并聚集。；成藏的CO_2气会经历化学沉淀、溶解、扩散和机械破坏四种破坏方式，会受断裂切割而打破压力平衡，沿断裂进一步运移和聚集成藏。

Most of water-soluble cyanine dyes have -SO3H and –COOH in their molecules, which will influence the biomolecules' functional characters. A new kind of water-soluble cyanine dyes with several cations in molecules were designed and synthesized, preparation conditions of intermediate and dyes were researched and optimized, the yield of dye is 25%. The novel kind of cyanine dye are water-soluble , spectrum characters was researched , all the dyes were charactered by 1H NMR and TOF-MS, spectrum in different solvent of novel dyes were focused on, one of the kind dyes show higher fluorescence quantum yield than the result reported. Because of several cations in the structure, it is promising when used in DNA assay and other bio-assay field.

大多数水溶性的菁类荧光染料分子结构中都带有-SO3H和-COOH等基团，过多的阴离子的引入容易造成对生物分子的功能属性的影响，本论文设计并合成了分子结构中带有多个正电荷的水溶性的一类新型菁染料，考察并且研究了中间体和染料的合成条件，最终的目标产物产率达到25％，染料通过了质谱和核磁的表征，新型的染料具有良好的水溶性，研究了新染料在多种溶剂的的光谱性质，其中一种染料的在水中的荧光量子产率比文献报道得到了提高，由于富集了正电荷，这类菁染料在DNA标记等生物中有一定应用前景。

In order to disclosure the reason why the electrocatalysis activeness and selectivity droped after being used several hundred hours continuously, the x-ray diffraction, scanning electron microscopy and energy dispersive spectroscope have been used to characterize the surface condition variations of Monel metal. The results indicated: Monel metal belongs to the Cu-Ni alloy around the electrolysis experiment.And after being used for 600hr, the surface layer element composition and geometry distribution of the alloy changed, namely in the alloy the Cu element /which superficial free enthalpy was smaller,"concentrated" to the alloy surface,and formed one kind of marble structure microcrystallite.Thus the electrode surface becamed rough a

为了揭示蒙乃尔合金阴极在连续使用数百个小时后电催化活性剂选择性下降的原因，采用X射线衍射仪、电子扫描电镜和电子能谱分析仪对电解实验所用的蒙乃尔阴极材料在电解实验前后的表面状态进行了表征，结果表明：所使用的蒙乃尔合金阴极材料在电解实验前后均属于Cu-Ni合金，使用600hr后，由于表面层元素组成和几何排布发生了变化，即合金中表面自由焓较小的Cu元素向合金表面&富集&，形成一种大理石结构的微晶，表面粗糙、不均一，这是造成其对硝基苯电还原的催化活性及选择性随着使用时间延长而逐渐下降的主要原因，同时也为此类电极的修饰改进提供了方向。

Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势，并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。