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富勒烯

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Because the olefinic hydroxyl groups are linked with olefinic carbon, so it can ionize H〓 ion and present the properties of weak acid, and so the olefinic hydroxyl groups change into the structure of alcoholate in the presence of alkali , but the structure of alcoholate may change into the structure of olefine alcohol again, after the Na〓 ions is removed, or when the pH value of its solution turn into pH. Because the structure of the olefine alcohol is not stable and is easy to isomerizate to become the structure of olefine ketone, so there appear the ca. 1730cm〓 C=O absorption peak in the IR spectra of the products.

明确指出了在C〓、C〓富勒醇中存在烯碳羟基与叔碳羟基等二类羟基,烯碳羟基由于与一个共轭体系相连,从而其羟基可以离解而呈现出弱酸的性质,因而在碱性条件下易形成烯醇钠盐的结构,当除去钠离子后或在酸性溶液中,烯醇钠盐结构转变为烯醇结构,但由于烯醇结构不如烯酮结构稳定,从而形成烯醇结构后,烯醇结构异构化为烯酮结构,因此在其产物的IR谱图上出现1730cm〓附近的C=0吸收信号。

A quantitative relationship between the separation factor and the bonded-phase molecular topological index for fullerenes is established.

建立了富烯勒的分离因子与键合相分子拓扑指数间的定量关系。

The above view of isomerization between the structure of olefine alcohol and olefine ketone can succeed to explain that the structure and properties of C〓 Fullerols change with the pH value of its solution.

作者提出的上述富勒醇的结构以及烯醇与烯酮的互变异构的观点能成功地解释C〓、C〓富勒醇的结构随其溶液pH值的变化而发生变化的现象。

Therefore, a physical model to correct the PL quenching efficiency was developed, which was affected by the fullerene absorption.

给出了富勒烯吸收作用对荧光猝灭效率影响的校正方法、物理模型和数学推导过程。

Gas discharges of barium,cluster,hydroxyl and fullerene were introduced,and the probability of these four emitters'application in gas discharge lamp s was discussed.

简要介绍了钡、团簇、羟基和富勒烯等的放电,探讨了这四种物质在气体放电灯中应用的可能性。

The results available now indicate that glass-like carbon synthesized from phenolic resin is a non-graphitizing carbon, and consists of both sp 2-hybridized carbon atoms that form imperfect graphite structure and sp 3-hybridized carbon atoms that are due to the presence of disordered carbon; and in the fullerene-related structure of glass-like carbon, there exist some pentagons and heptagons carbon rings.

玻璃炭作为一种特殊炭材料已广泛应用于许多领域,其制备、性质、应用以及基本结构的研究已经取得了很大的进展,已有的研究结果表明酚醛树脂基玻璃炭是一种典型的非石墨化炭材料,由 sp2杂化态碳原子和 sp3杂态碳原子组成,且在其类富勒烯结构中存在五元环和七元环。

The topological resonance energy method was applied to all the open structure isomers of C36X to investigate their aromaticity.

采用拓扑共振能方法对富勒烯C36X开环结构中的所有可能的异构体及阳离子和阴离子芳香性进行了理论研究。

As is well-known,the buckminsterfullerene〓was discovered by means ofmass spectrum with laser-evaporation pr...

富勒烯是三连接的笼形分子,其多面体的表面由五元环和六元环构成。

In this paper we address the question of the transition between autoionization that prevails in small molecules, and delayed ionization occurring in larger molecules or clusters. This transition is illustrated by autoionization of Na2 Rydberg states on one hand, delayed ionization in fullerene C60, and delayed detachment in small cluster anions on the other hand.

本文通过Na2的里德堡态的自电离,富勒烯C60的延迟电离,阴离子小团簇的延迟解离研究了在小分子中起主导作用的自电离和在大分子以及团簇中出现的延迟电离之间的转变过程。

The nonlinear optics performance of fullerenes in femtosecond time-scope was studied by using femtosecond time-resolved optical Kerr effect.

3利用飞秒时间分辨光克尔实验证明了富勒烯分子体系在飞秒时域内的三阶非线性响应并不大。

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