富勒烯

A compound 2-(3-hydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of the fullerene(C60) and azomethine ylide (prepared from glycine and 3-hydroxybenzaldehyde). The product was characterized by UV-Vis,1H-NMR ,FT-IR and MS. The reaction conditions affecting the yields of product were investigated and the optimum reaction conditions with product yield 75%(based on consumed C60) were:molar ratio of C60∶3-hydroxybenzaldehyde:glycine 1∶3∶6,reaction temperature 95℃,reaction time 18h.

利用甘氨酸和3-羟基苯甲醛与C60发生1， 3-偶极环加成反应，合成分离得到了2-(3-羟基苯基)[60]富勒烯吡咯烷，用UV-Vis、1H-NMR、FT-IR、MS等测试手段表征了产物的结构，并通过单因素方法，探讨了反应条件对产物产率的影响，得到最佳工艺条件：反应物摩尔比1∶3∶6，温度95 ℃，反应时间18 h，产物的产率可达75%（以消耗的C60计）。

Geometric and electronic properties of fullerene—barbituric acid and its dimer have been studied by density functional theory at BLYP level with dnp basis sets.

本文通过密度泛函理论，采用在BLYP/DNP水平上的理论计算，研究了(60)富勒烯—巴比妥酸及其二聚体的几何构型、分子轨道和电子结构。

The second part of this dissertation describes some molecular dynamic simulation results on the collisional reaction dynamics of fullerenes and carbon nanotubes.

在本论文的第二部分，介绍了利用分子动力学模拟方法研究富勒烯和碳纳米管的碰撞反应动力学得到的一些结果。

Exceptionally large nonlinear optical response in C60 had been reported, and diacetylene complexes have the large NLO suspceptibilities, so the novel idea of introducing diacetylene to C60 to improve the NLO suspceptibilities was supposed.

富勒烯具有优良的非线性光学性能，共轭双炔类有机分子有较大非线性光学系数，将C60与双炔类化合物结合在一起设计非线性光学材料是一个有意义的设想。

Results In Vero cell system,under lucifugal and illumination conditions,fullerene C60 has direct virucidal activity and infection block effect,but it does not has any multiplication inhibition action to HSV-1F strain.

以逆相蒸馏法合成了富勒烯脂质体，用药物对病毒所致细胞病变的抑制实验以及病毒的空斑减数实验，观察C60脂质体对HSV-1F株的直接杀灭、感染阻断及增殖抑制作用。

Results In Vero cell system,under lucifugal and illumination conditions,fullerene C60 has direct virucidal activity and infection block effect,but it does not has any multiplication inhibition action to HSV-1F strain.

结果［摘要］目的观察富勒烯抗HSV-1的药效。

The uptake of CNTs by Stylonychia mytilus and their distribution during the dividing process of the cells were observed with optical microscope for the first time. The dose-effect relationship between concentration of CNTs and surviving rate of Stylonychia mytilus was measured.

自从1991年11月日本电气公司基础研究实验室的饭岛钝雄发现碳纳米管以来，其作为一种新型的纳米材料，已成为富勒烯领域的一个主要的研究热点，被广泛应用于物理、化学、材料等各个领域。

A new fullerene derivative containing energy-producing groups was prepared, and the reaction conditions affecting the yield were studied by the kroenecker method. The optimal reaction conditions with a 53.5% yield (based on consumed C60) are: 1:3:6 of molar ratio of C60 , o–nitrobenzaldehyde and sarcosine , 55℃ of reaction temperature, 12 h of reaction time, 40mL of toluene solvent.

利用N-甲基甘氨酸、邻-硝基苯甲醛和C60反应，合成分离出了含有硝基的新型富勒烯吡咯烷衍生物，通过正交试验对其工艺条件进行了研究，探讨了反应物剂量比、温度、时间和溶剂体积对产物产率的影响，得到了合成产物的最佳工艺条件：反应物剂量比为1：3：6、温度为55℃、反应时间为12h、溶剂甲苯体积为40mL，此时产物产率可达到53.5%（以消耗的C60计）。

Under illumination condition,the ED50 and ED90 of direct virucidal activity of C60 to HSV-1F strain are 0.05313 μg/ml and 0.1696 μg/ml respectively,and the ED50 and ED90 of infection block action of C60 are 0.9461 μg/ml and 5.643 μg/ml separately.

以逆相蒸馏法合成了富勒烯脂质体，用药物对病毒所致细胞病变的抑制实验以及病毒的空斑减数实验，观察C60脂质体对HSV-1F株的直接杀灭、感染阻断及增殖抑制作用。

Methods We prepare the fullerene C60 liposomes using reversed phase distillation method,examine the direct virucidal activity,infection block and multiplication inhibition of C60 liposomes to HSV-1F strain,using inhibition experiment of cellular pathologic effect of virus and plaque reduction assay.

以逆相蒸馏法合成了富勒烯脂质体，用药物对病毒所致细胞病变的抑制实验以及病毒的空斑减数实验，观察C60脂质体对HSV-1F株的直接杀灭、感染阻断及增殖抑制作用。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。