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富勒烯

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In order to solve the problem of the clustering of the zeros of permanental polynomials of the fullerenes, a multi-dimensional stable marriage model is proposed, relevant algorithms are given, and the clustering problem is solved.

本文提出了多维稳定婚姻问题的模型,同时相应地给出了算法,并成功地应用于富勒烯积和多项式零点的聚类问题。

HPLC was coupled with both mass spectroscopy and ultraviolet absorption spectroscopy for simultaneous separation and characterization of the products from glow plasma reaction of chloroform.(3) Phosphorus pentachloride has been used to perchlorinate acenaphthene under moderate pressure and temperature in sealed reaction vessels.

在此基础上,以反相C〓柱为固定相,甲醇/乙醇/环己烷为流动相,采用梯度洗脱的方法,对氯仿辉光放电合成产物进行高效液相色谱-紫外光谱-质谱联用分离分析,成功的分离得到包括富勒烯C〓和全氯代碳簇在内的数十种产物,并得到了相应的质谱和光谱数据。

Historically, the discovery of the buckminsterfullerene molecule by Kroto et. al in 1985 when they investigated the nature of carbon present in interstellar space is unique since it is one and only new allotrope discovered in the 20th century.

从历史角度来看,1985年Kroto等人发现富勒烯C〓的这件事可以说是独一无二的,因为C〓是整个二十世纪发现的唯一一种新的同素异形体。

According to the literatures and our experiments, appropriate conditions for the reaction of C60 with alkyl azide and the separation of adducts were obtained. The relationship between the structure and the chromatographic polarity of the products was also summarized.

根据文献报道和实验总结出了富勒烯与烷基叠氮化合物的反应条件和产物的分离条件,并对化合物结构与色谱极性的关系作了归纳总结。

Topological resonance energy and bond resonance energy methods were applied to all the open structure isomers of C36CH2 to investigate their aromaticity.

用键共振能和拓扑共振能方法对富勒烯C36CH2开环结构中的所有可能异构体及其阳离子和阴离子芳香性进行了研究。

In the chapter four,the main study was focused on [60,70]fullerene reaction with 4,4,5,5-tetramethylidazoline- 2- thione and DL- valine and other α-aminoacids. The results ofcharacterization showed that it was a carbene reaction. The possible mechanism wasput forward based on the results of characterization.

第四章,主要研究了[60,70]富勒烯,4,4,5,5-四甲基咪唑啉-2-硫酮与DL-缬氨酸和其它氨基酸的反应,通过对反应产物的详细的表征,发现该类反应是一个产生卡宾的新反应。

Using DFT combined with the orbital localized approach and Xu's covalence new concepts on a molecular fragment, it is concluded that the covalence of copper atom is 7 in 〓-type clusters and in inorganic fullerene-like molecule 〓, and there are Cu-Cu single bonds in 〓-type clusters.

应用DFT结合轨道定域化的方法和分子片共价的新概念,提出了在〓类簇合物和无机类富勒烯分子〓〓中Cu原子的共价为7,以及化合物中Cu-Cu单键的存在;解释了通常认为这类化合物中Cu-Cu之间没有成键作用而又不能回答较短的Cu-Cu键长的问题。

The second part of the dissertation is about the investigations on structure and applications of fullerene doped optical glasses.

本论文的第二部分是对掺富勒烯激光玻璃的结构与应用探讨。

The absorption spectra together with the vibration Raman and reflection spectra of C〓 and C〓 mixture doped phosphate and fluophosphate laser glasses has been studied, and their structure characters are analyzed.

对掺C〓/C〓混合物的磷酸盐和氟磷酸盐激光玻璃进行了吸收光谱,Raman光谱和红外反射光谱的测试与分析,根据实验结果,初步推断了富勒烯在激光玻璃中可能的结合与结构特性。

You are the basis of life on Earth, you let our pencils write, and you form the most fortuitous fullerenes.

你是地球上生命的基础上,你让我们的铅笔写,你是最幸运的形式富勒烯

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