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富勒烯

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It was found that the reactions of C_(60) with anthranilic acids and isoamyl nitrite in the presence of triethylamine unexpectedly afforded C_(60)-fusedδ-lactones,which would be difficult to be prepared by other known methods.

通过在三乙胺作用下,富勒烯与邻氨基苯甲酸类化合物和亚硝酸异戊酯的环化反应,首次合成了一系列富勒烯并六元环内酯。

The absorption peaks of cyanine dye part in two compounds were bathochromic shiftsin some content because they were infected by [60]fullerene, this indicated that therewas interaction between [60]fullerene part and cyanine dye part in the compounds.

但染料部分的吸收由于受〓富勒烯的影响,在不同程度上发生了红移,这初步说明了:〓富勒烯和染料之间有分子内的作用。

The palladium-catalyzed heteroannulations of C_(60) with a variety ofο-iodoanilines afforded the first synthesis of C_(60)-fused indoline derivatives.

通过在Pd的催化下,富勒烯和邻碘苯胺类化合物的杂环化反应,首次合成了一系列富勒烯并吲哚啉环衍生物。

The geological distribution and genesis of most natural fullerenes have relations with meteoritic impact, wildfire, lightning strike, et al. and the causes of formation of some natural fullerenes are uncertain.

多数天然富勒烯的地质分布、成因机制与陨石撞击、野火、闪电等有关,但部分天然富勒烯的成因尚不清楚。

Several aminated Fullerene derivatives were synthesized by the reaction of C〓 with phenylamine, diphenylamine and triethylamine etc., the phenomena of fragmentation and aggregation of the aminated Fullerene derivatives in UV laser desorption ionization mass spectrometer was observed, a few nitrogenous poly-Fullerene ions, such as C〓NH, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓, C〓N〓H〓 etc.

对C〓富勒烯与苯胺、二苯胺、三乙胺等形成的加合物在紫外激光解吸电离作用下可以发生不同寻常的裂解和聚合现象进行了研究,认为其形成机理为:上述加合物在紫外激光解吸电离作用下,发生裂解产生C〓NH、C〓N及C〓等离子,然后它们之间发生聚合,形成如:C〓NH、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓、C〓N〓H〓等含氮原子的聚富勒烯离子。

The geometric optimization of C_(59)Sm and C_(60)Sm shows that the replacement of a C atom with a Sm in C_(60) yields a stable substitutionally doped fullerene C_(59)Sm, and among the five possible optimized geometries for C_(60)Sm, the most favorable exohedral sites are above the center of a hexagon and a pentagon ring.

替代掺杂富勒烯C_(59)Sm与外掺杂富勒烯C_(60)Sm几何结构与电子结构分析表明,以Sm原子取代C_(60)分子中的一个碳原子后碳笼仍保持稳定的替代结构,而对五种可能的C_(60)Sm结构,Sm原子倾向于栖息在六碳环与五碳环的空洞上方。

Chemical modification is one of the most important research fields in the fullerene chemistry.

富勒烯化学中,化学修饰一直是富勒烯研究的主要领域之一。

In the second part, the preparation and the properties of self-assembled films of Fullerene and Fullerene derivatives have been studied.

第二部分,主要进行了几例富勒烯富勒烯衍生物的自组装薄膜的研究。

We studied the nonlinear optical properties of fullerene and its arylatedderivative.They both exhibit weak self-defocusing and strong RSA.

研究了芳化富勒烯富勒烯的非线性光学性质,它们都具有弱的非线性自散焦和较强的反饱和吸收。

The catalytic behavior of these complexes in the hydrosilylation ofα-olefins with triethoxysilane has been investigated systematically.

二、富勒烯过渡金属配合物的合成及其催化性能的研究以富勒烯为基的衍生物一般具有独特的催化性能。

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