富勒烯

This paper includes three parts:preparation of fullerene,the theoretical design and synthesis of novel pyrrolidine nitro-derivatives,the investigation of the application of fullerene and its derivatives in high energetic explosives and nitramine modified double base propellant.

本论文主要包括三部分：富勒烯原材料制备研究，新型硝基富勒烯吡咯烷衍生物的理论设计与合成研究，富勒烯及其衍生物在高能炸药和硝胺改性双基推进剂中的应用研究。

The structure of all kinds of [60]fullerene derivatives and their characterization via (13)~C NMR spectros-copy are reviewed and the (13)~C NMR spectroscopic properties of various symmetry [60]fullerene derivatives are mainly dis-cussed .

本文全面综述了多种[60]富勒烯衍生物的结构，阐述了(13)~C NMR谱在[60]富勒烯衍生物结构表征中的应用，重点讨论了不同对称性[60]富勒烯衍生物的(13)~C NMR谱图特征。

The C_(60)-fused tetrahydrofuran derivatives are excellent synthons for further functionalization.While treated with different equiv,of BF_3·OEt_2 at various temperature,several novel functionized fullerene derivatives have been successfully synthesized.2.1,4-Fullerenols C_(60)ArOH were synthesized via the reaction of[60]fullerene with 4-substituted phenylhydrazine hydrochlorides and sodium nitrite under moisture and aerobic conditions.

这种四氢呋喃环合富勒烯衍生物作为一个合成中间体又可发生进一步的衍生化反应，其与不同当量BF_3·OEt_2在不同温度条件下可以得到二氢呋喃环合富勒烯衍生物、三元环合富勒烯衍生物等。2。

In addition, two water-solublephosphonic acid derivatives of C〓 and two diadducts of phosphonate derivative of C〓were also prepared. All the four compounds can be dissolved in DMSO, which is asolvent easy to be soluble in water. Their DMSO aqueous solution could haveprospective applications in the field of biomedicine.

研究了富勒烯膦酸酯衍生物的水解反应，首次合成了两个水溶性富勒烯膦酸衍生物，另外还合成了两个二加成的富勒烯膦酸酯衍生物，这四个衍生物均能很好地溶解在和水互溶的DMSO中，它们的DMSO水溶液可能在生物医学研究中可能会有很好的应用价值。

Three fullerene derivatives including a bisadduct of tetraethyl methano[60] fullerenediphosphona- te、a dimalonic acid[60]fullerene (DMA C60and fullerol were used to study the relationship between their photo-induced GSH depletion and structures.

采用二加成亚甲基富勒烯[60]二膦酸四乙酯、二加成富勒烯[60]丙二酸(DMA C60)和富勒醇 3种富勒烯衍生物研究富勒烯衍生物的结构与光诱导细胞内GSH耗竭的关系。

It was discovered that trimalonic acid C60、fullerol、dimalonic[60]fullerene hydrolysate、tetraethyl methano[60]fullerenediphosphonate、methano[60]fullerenediphosphonic acid and dimalonic acid C60 exhibited different inhibitory effects on Taq DNA polymerase.

实验发现，6种富勒烯衍生物三丙二酸富勒烯、富勒醇、富勒烯丙二酸水解物、亚甲基富勒烯二膦酸四乙酯、亚甲基富勒烯二膦酸四乙酯的完全水解物和二丙二酸富勒烯对Taq DNA聚合酶存在不同程度的抑制作用。

B、 In the laserablation study of composite materials composed of 〓 and ozonized〓 precipitate as well as metal fullerides 〓, endohedralmetallofullerenes of the type 〓 were formed in the positive ion channel. c、 Inthe laser ablation study of rhodium containing metal fulleride 〓, two sequencesof metallofullerenes were formed in both the positive and negative ion channels, with〓 and 〓.respectively.

在激光烧蚀金属富勒烯盐的实验中发现形成的金属富勒烯类型依赖于金属元素的性质、含量及金属富勒烯的制备方法：a、在〓的实验中观察到取代型金属富勒烯〓和〓正负离子的产生。b、在对含La和Y的富勒烯复合样品〓以及金属富勒烯盐〓的激光烧蚀过程中观察到金属内嵌富勒烯正离子团簇〓的产生。c、在〓的激光烧蚀实验中观察到两个系列金属富勒烯〓和〓的形成，在负离子通道中〓在正离子通道2n=48-56。

Many kinds of organofullerenes are not stable under reductive, oxidative or thermal conditions, where the functional addends are removed from the fullerene sphere and lead to the formation of pristine fullerenes.

在还原、氧化或加热条件下，许多富勒烯衍生物的加成基团会从富勒烯骨架上断开，得到富勒烯母体，是富勒烯环加成反应的逆反应。

The study of natural fullerenes is a new area of across fullerene science and geological science. So far natural fullerenes have been found in shungite, fulgurite, carbonaceous conglomerates in impact crater, E/K boundary carbonrich clay rock layer, T/P boundary layer, dinosaur eggshell, coal, heavy crude oil, solid bitumen and socalled seminatural fullerenes in common soots, Chinese ink sticks, commercial char, et al., only with low concentrations.

天然富勒烯研究是富勒烯科学和地质科学相交叉的一个新兴研究领域，迄今为止已在桑加岩、闪电熔岩、陨石撞击坑中的含碳质角砾岩、古近系/白垩系地层界线的含碳粘土岩、三叠系/二叠系界线岩石、恐龙蛋壳、煤、重质油、固体沥青以及半天然的烟灰、木炭、书墨等物质中检测到富勒烯的存在，但含量很低。

For its special conditions of production, fullerene is hardly yielded through the process of the common earth environment and dynamic geology. The first presence of fullerene in Shungite, Russia in 1992 aroused the interest of studying natural fullerene.

富勒烯的形成条件特殊，普通的地球环境和地质过程不利于富勒烯的生成。1992年天然富勒烯在俄罗斯前寒武纪地层桑加岩中被发现，引起了人们对天然富勒烯研究的兴趣。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。