实验

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

We present theoretical analysis and experimental results of coherent population trapping within Zeeman sublevels of rubidium under Hanle configuration, and bichromatic dark states are firstly observed in the experiment.

本论文从理论和实验角度阐述了铷原子Hanle构型下塞曼子能级相干布居数囚禁实验，首次在实验过程中发现了双暗态结构。

The first experiment is called 'syllable-flip-flop' test, in which the experimenter asked the subjects to reverse the order of two syllables in bisyllabic words and observed how they syllabify it.

第一个实验为音节颠倒实验，在这个实验中要求受试者将双音节字的顺序颠倒过来念再观察他们如何切分音节。

The results revealed that screwdrivers with triangle shaped handle could help subjects produce the maximum torque. Besides, using screwdrivers with hexagon shaped handle spent the least time, generated the minimum biceps muscle activity, and bad the least subjective fatigue rating. Moreover, wearing an anti-static glove or being barehanded can produced the maximum torque and spent the least time as well. Experiment 2 evaluates the handle diameter of screwdriver (30 mm, 34 mm or 38 mm) and operation plan. The results showed that the torque increased with the increase of the radius, the operation time and the brachioradialis muscle activity also increased with the increase of the radius.

本 研究共分为三次实验，实验一分析握把造型(八角形、锐角六角形、圆角六角形、枪型、圆角三角形)与手套(棉质手套、防静电手套、赤手)的影响，结果显示三角形造型握把可产生最大扭力，六角形造型握把的锁附螺丝时间最短、二头肌肌肉活动度最低、主观整体疲劳评比最低，防静电手套与赤手状态的扭力最大并且锁附螺丝时间最短；实验二比较握把直径(30 mm、34 mm、38 mm)与作业面的影响，结果显示直径越大扭力越大，但直径越小锁附螺丝时间则越短，且肱桡肌肌肉活动度越低。

This paper designs four simulation experiments to verify the CSAPFBA algorithm, and the results of the four simulation experiments are given. This paper lengthways compares the CSAPFBA algorithm with the CSFQ algorithm and breadthwise compares the CSAPFBA algorithm with the CSPAFA algorithm so as to analyze the performance of the CSAPFBA algorithm from the theoretical and experimental aspects.

本文设计了4组模拟实验验证CSAPFBA算法并且给出了模拟实验结果，将CSAPFBA算法分别和CSFQ算法、CSPAFA算法进行了纵向比较、横向比较以便从理论和实验两个方面分析CSAPFBA算法的性能。

objective the effects of anthocyanin pigment from maize purple plant on resisting lipid peroxidation were investigated.methods the inhibition of anthocanin pigment from maize purple plant was examined in vitro that autcoxudation of lecithin liposome system induced by fe2+.50 mice were randomly divided into 5 groups.vehicle and different dose anthocyanin pigment from maize purple plant were given respectively,and then experimental injury of mice liver was induced to make use of bromobenzene and the content of mda was determined in liver homogenate.results the inhibition rates of anthocyanin pigment from maize purple plant on linoleic acid oxidation was higher that of ascorbic ascorbic acids.the content of mda in homogenate in middle and high dose of pigment were significantly lower than that in low dose and the injured control group.there were no significat differences in the content of mda in homogenate between low dose group and injury control group.conclusion the anthocyanin pigment from maize purple plant have the capability to resist lipid peroxide.

目的 探讨玉米紫色植株色素抗脂质过氧化的作用。方法体外实验测定玉米紫色植株花色苷色素在fe2+引发的卵磷脂脂质体体系中抗氧化活性。体内实验，取50只小鼠随机分成5组，分别给予溶媒和不同剂量的色素，然后采用溴代苯致实验性肝损伤，测定肝匀浆的丙二醛含量。结果在由fe2+引发的卵磷脂脂质体体系中玉米紫色植株色素对脂质过氧化有明显的抑制作用，抑制率随样品的浓度增高而增大，并且明显优于抗坏血酸。在溴代苯致小鼠实验性肝损伤模型实验中，中、高剂量组的丙二醛含量均低于损伤模型组。低剂量组和损伤模型组比较丙二醛含量差异无统计学意义。

As part of the planning, execution and reporting of a study, the various processes carded out are carefully documented as Standard Operating Procedures.

作为实验的计划、实施和实验报告的一部分，不同的实验过程被当作标准操作程序记载。

(1) In the sorption kinetics experiment, Cu2+ sorptions by Ceratophyllum demersum, Myriophyllum triphyllum and Hydrilla verticillata respectively, all reached balance within 35mins, all of the test results of sorption kinetics recommended the pseudo second-order equation and indicated that this kind of sorption was a complicated process of simultaneous actions of many reactions. The test results of thermodynamic sorption fitted with Langmuir model better than Freundlich model, and the maximum sorption quantites were 13.12, 20.12, 7.79mg/g, respectively,In the desorption test, the desorption rates of each plants were all below 1%, indicating strong sorption-holding action of these submersed mcrophytes on Cu2+.

通过上述研究，得到以下结论： 1、狐尾藻、金鱼藻、黑藻在对铜离子的吸附动力学实验中，均在35min内达到吸附平衡，分别用一级动力学方程和伪二级动力学方程拟合，结果均为用伪二级动力学方程拟合效果较好，表明该吸附为多种反应同时作用的复杂过程；在热力学实验中，三种植物的吸附曲线都能较好的用Langmuir曲线拟合，其拟合最大吸附量分别为13.12、20.12、7.79 mg/g；在解吸实验中，三种植物的解吸率都较低，说明对铜离子都有较好的吸持能力。

Preparation of the cathode includes:shaping under the press of 40Mpa, sintering at 550℃for 1 hour and at 900℃for 8 hours and threading with molybdenum bar; Considering the literatures we choose CaCl2 as salt for preparation titanium. Pretreatment of salt is for 1 hour at 100℃and for 2 hours at 300℃. Partial pressure of oxygen which need lower than 5.11×10-7Pa to reduct titanium oxides and hygroscopic property of salt need a sealed equipment to electrolyse. And finally successfully designed a satisfied one and the results show that the equipment can be satisfied the requirment of the experiment. Flow of the inert gas is 1.5L/min, the voltage is 2.8 V, temperature is 850℃and time is 2 hours during pre-electrolysis. Flow of the inert gas is 0.2L/min, the voltage is 3.1 V, temperature is 900℃and time changes with the mass of TiO2 during electrolysis, namely the greater need the longer time; To eliminate influence of salt and other impurities, the products need to wash with distilled water and dilute chlorhydric acid , then wash with dilute hydrochloric acid under supersonic wave assistant. Finally, electrometical properties of the electrolysis of TiO2 is researched by cyclic voltammetry and chronoamperometry, and results show that there are two main reodox steps, namely from TiO2 to TiO and from TiO to Ti.

阴极制备主要包括40MPa压力下模压成型、两段式烧结(1小时内升至550℃保温1小时，再1小时升温至900℃保温8小时)及烧结后TiO2块打孔用钼棒串接三个主要环节；实验中选用CaCl2作为电解熔盐，并对其进行预处理(100℃，保温1小时； 300℃，保温2小时)；经热力学计算，还原钛氧化物的氧分压至少要低于5.11×10-7Pa，结合电解过程中所用熔盐CaCl2有极强的吸水性的特点，电解装置应有较高的密封性，自行设计了一套密封性可靠的电解装置，便于实验过程中熔盐预处理和氧分压的控制；通过干燥处理预电解过程中Ar流量大约为1.5L/min、电压为2.8 V、温度为850℃、时间为2小时，电解过程中Ar流量大约为0.2L/min、电压为3.1V、温度为900℃，实验结果表明电解时间与TiO2质量密切相关，质量越大需要电解的时间越长；通过自来水冲洗—稀盐酸浸泡、洗涤—在超声波辅助作用下稀盐酸洗涤，可减少熔盐及其它杂质对电解产物检测结果的影响；最后，通过循环伏安法、计时电流法对电解机理的研究，确定电解还原TiO2制备金属钛主要经历了TiO2-TiO-Ti的过程。

On the basis of previously research, this paper re-probe into the mechanism of electro-chemist mechanical manufacturing process, making the rational technological parameter, and developing the manufacturing equipment. Through a lot of technology tests, get a lot of labratory data, accordingly, researched the surface feature of the electro-chemist manufacturing process, and deeply discussed its influence on the work piece feature. The last result is that: the electro-chemist mechanical manufacturing process can reduce the low-frequency component significantly, but on high-frequency component, it has little influence, having obviously positive pole flat effect. After manufacture, the tip parts on the surface of the work piece is cut off, there is micro "high land" shape, the parameter for surface roughness is reduced a lot, the surface outline of the work piece is negative, the bearing length rate is cliffy. Also the surface quality of the work piece is improved. This can help to avoid changing the shape, improve the feature of rub, gear and reduce the time to suit. This would also ensure the precision and result in a longer work piece life.

在以前研究的基础上，本论文重新探讨了电化学机械复合光整加工工艺的机理，确定了较合理的工艺参数，对电化学机械复合光整加工设备进行了改进，通过工艺实验广泛地搜集了大量实验数据，依据实验数据，多角度地研究了电化学机械复合光整加工的表面形貌特点，并且从理论上深入讨论了电化学机械复合光整加工表面形貌对工件工作性能的影响，最后得出的结论为：电化学机械复合光整加工对工件原始表面的低频成分有较大程度的降低，而对高频成分影响较小，有明显的阳极整平作用，被加工工件表面的尖峰状凸起被去除，工件表面呈现出微观&高原型&，表面轮廓不平度高度特性参数大幅度降低，工件表面轮廓分布集中，且呈负偏态，轮廓偏斜度为负值，轮廓支承长度率曲线陡峭，工件的表面质量得到综合改善，这对提高零件的抗接触变形能力、改善摩擦、磨损性能、降低工件的磨合时间、提高工件的精度保持性、延长工件的寿命均有利。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。