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The one carbon unit transfer reaction involving in the tetrahydrofolate coenzymes has caused great interest which is very important in the living system and has played an important role in the designing and syntheses compounds (especially the anti-cancer and LCD materials). In our study it was found that benzimidazolium salt has the ability to transfer one or two one-carbon unit and is a kind of new tetrahydrofolate coenzymes model. This research provides new method for biomimetic synthesis.

在非酶催化条件下,不仅实现了与生物体内相类似的一碳单元转移反应,而且可以转移具有不同官能团的取代&一碳单元&,使这种一碳单元转移反应传递的功能化一碳单元更加多样化,这方面强劲的研究工作进展,将为异常活跃的合成化学提供更多常规合成方法难以实现或实现不理想的仿生合成新方法。

Because substituted anilines have Lewis acid or Lewis base group, extractions with complexing agent was conducted.

由于取代苯胺都具有Lewis酸性或Lewis碱性官能团,采用相应的络合剂进行了络合萃取的研究。

Boehm titration, FT-IR, BET method and micro coulometry were involved in the analysis and characterization of surface functional groups, pore structure and chlorine content.

采用Boehm滴定和FT-IR方法对改性活性炭表面官能团进行表征并用BET方法分析其物理结构,使用微库仑仪分析产物有机氯含量。

The results show that:(1) Light-calcined MgO powders prepared with nature magnesite or Mg2 both are of face-centered cubic structure.

结果发现:水化前后得到的都是面心立方晶体结构的MgO,但水化前得到的轻烧MgO中仍存在官能团CO32-的残留物,而水化后得到的轻烧MgO中不存在CO32-,而且颗粒变得较易破碎,大大减少了细磨时间;再者,水化后的轻烧MgO活性较高,加上Mg2在分解过程中残留的水分对MgO 的烧结起催化作用,因此,使其经高温锻烧制得的烧结镁砂的开口气孔率由水化前的2.0%下降到0.6%,闭口气孔率由水化前的6.1%下降到2.8%,体积密度由水化前的3.29g/cm3提高到3.46g/cm3。

Fullerene oxides played an important role in studying functionalization of carbon clusters, which stimulated the interest of scientists.

碳笼氧化物对碳笼的官能团化研究具有重要意义,因而激起了人们广泛的研究兴趣。

Once the prodrug is in the blood supply, esterases hydrolyse the ester to unmask the carboxylate group and the drug can interact with its target.

药物的醚作为前体药物,口服作用时,由于醚把羰基官能团的极性遮掩了,前体药可以穿越肠内壁的细胞膜,一旦前体物进入血液循环,就会发生水解暴露出羰基使药物与目标相互作用。

In the fifth part, asymmetric synthesis of β,γ-trans-alkenyl α-amino esters was achieved by chiral phosphoric acid catalyzed transfer hydrogenation of β,γ-alkynyl α-imino esters. Utilizing Hantzsch ester as the hydrogen donor, both the alkyne and imine moieties of β,γ-alkynyl α-imino esters were reduced to yield β,γ-trans-alkenyl α-amino esters with up to 96% ee.

第五部分工作中,使用手性磷酸作为催化剂,Hantzsch酯作为氢源,β,γ-炔烃取代的α-酮酸酯亚胺中的炔键和亚胺官能团均被还原,以中等的收率和优秀的对映选择性(up to 96% ee)得到β,γ-反式烯烃取代的α-氨基酸衍生物。

Our group first reported a novel dialkylation reaction of alkyl zinc iodides with aromatic aldehydes and an olefination reaction of benzyl zinc bromides with aromatic aldehydes respectively.

我们实验室分别首次报道了在过渡金属络合物催化下带官能团有机卤化锌试剂与芳香醛的双烷化反应和烯基化反应。

We provide a brief survey of recent results on the electronic transport characteristics of single molecules as well as self-assembled monolayers.

摘要介绍了测量单个有机分子导电性质的一些进展,包括分子的尺寸效应、官能团效应、分子与电极的接触效应等,以及分子逻辑器件的初步研究。

The weak base anion exchange resin with covalent bond side chains which contain donator atom N offering unshared electron pairs, is able to form a coordinative covalent bond to heavy metal in which unsaturated vacant orbits exist in its electron shells.

在天然淡水水体的环境下,重金属被树脂吸附源于树脂胺基官能团上的N原子有孤对电子,水中所含重金属的价电子层有空轨道。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

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A single payment file can be uploaded from an ERP system to effect all pan-China RMB payments and overseas payments in all currencies.

付款指令文件可从您的 ERP 系统上传到我们的电子银行系统来只是国内及对海外各种币种付款。