官能团

Between the calculated and experimental Ip~1~ values for 61 monosubstitued paraffins.

对10类单官能团取代烷烃的61个化合物计算结果表明，计算值和实验值之间的平均相对误差仅为0.20%。

He thermal oxidation process of saturates and aromatics with different addition agents were studied by means of In-situ FTIR.

FOT通常利用试验后的沥青粘度变化来评价沥青的老化性能，红外光谱法可研究沥青老化前后官能团的变化。

The interaction between MT and AA was expressed by infrared spectra, the functional groups of -SH in MT had lone pair electrons, which could formπ-πwith -C=O in AA. The equilibrium binding experiment and Scatchard analysis showed, at least three kinds of binding sites would exist when MT-imprinted polymer formed, the most adsorption capacities were 3.3896mg/g, 0.9362mg/g, 1.6583mg/g respectively; most terminal thiolate sulfurs in MT were polymerized as binding sites in the process of polymerization, which could observed from TEM, binding capability of other thiolate sulfurs was weak since spatial hindrance existed.

采用红外光谱研究了加入金属硫蛋白后功能单体丙烯酸官能团谱峰的变化，结果表明金属硫蛋白分子中的-SH与丙烯酸中的C=O在氯仿溶液中能形成π-π键，由聚合物的吸附特性和Scatchard分析可以得出，金属硫蛋白印迹聚合物至少存在三种结合位点，其高、中、低的最大吸附量分别为3.3896mg/g、0.9362mg/g、1.6583mg/g；通过透射电镜可以观察到，金属硫蛋白在聚合过程中主要以分子两端的巯基作为结合位点，不同位置的巯基受到的空间位阻不同，导致产生了三种不同的结合位点。

The results showed that Kaidimycin was chemically neutral, macrocylic polylactones, stable and liable to dissolve into water and pyridine, slight to dissolve into methanol, ethanol and N-butanol, difficult to dissolve into ethyl acetate, acetone, benzene and chloroform. Chemical reaction of functional group of Kaidimycin showed that it had glycoside, amino acid and aldehyde, no reducing sugar, polypeptide and phenol.

凯地菌素属中等极性的、中性抗生素，极性纸层析结果与多烯类抗生素的纸层析结果相似：易溶于水、吡啶，微溶于甲醇、乙醇、正丁醇，不溶于乙酸乙酯、丙酮、苯、三氯化碳；对高温、光照和紫外处理有很好的稳定性；官能团反应试验结果发现，凯地菌素可能含有糖苷键、氨基酸伯氨基和醛基，不含有还原糖、多肽和酚基，高锰酸钾、浓硫酸反应与多烯大环内酯类抗生素的特性相似；并且依据纯品，采用生物法和分光光度法对摇床发酵液进行了效价的测定。

The substrate functionality is usually grafted acid anhydride at up to 25 wt%.

基体官能团通常是接枝酸酐，酸酐比率高达25%。

In the second part, the cross-coupling reaction of organoboronic acid witharyl halide catalyzed by Pd has been studied, and the 〓 catalyzedcross-coupling reaction in organic phase and the 〓-TPPTS catalyzed reac-tion in water phase have been investigated also.

结果表明，无论是有机相催化反应还是水相催化反应，都得到了很高的转化率和产率。该反应条件温和，并且硼试剂和亲电底物上可以带各种官能团，适用范围极宽，是一个极有应用价值的反应。

Wereport the synthesis of an alkyl imidazolium salt supported pyrrolidine amide organocatalyst L-1 and its use and recycling in Aldol condensation reaction.

在这里，我们小组报道了用脯氨酸为原料合成了一种双官能团的离子液体接枝的新型有机催化剂并应用于Aldol缩合反应，它和脯氨酸具有相似的催化作用，可以有效地促进反应的进行。

Five typical coals of low-to-medium rank (Huolinhe brown coal, Majiata non-caking coal, Datong weakly caking coal, Huozhou gas coal, Lingshi fat coal) and their macerals are prepared. The molecular structure and the oxygen functional groups of the selected coals and their macerals are studied by means of the conventional coal properties analysis, chemical analysis and the advanced instrumental methods such as FTIR,XRIK 13C-NMR.N XPS. The molecular structure characteristics, regularities and the results are discussed. Additionally, the total oxygen content and distribution characteristics of different oxygen functional groups in the raw coals and their macerals are studied.

本文中选取了中低变质程度煤中的五种典型煤种——霍林河褐煤、马家塔不粘煤、大同弱粘煤、霍州气煤、灵石肥煤以及它们的不同显微组分作为研究对象，采用了常规的煤质分析、化学分析法以及先进的仪器分析法如傅立叶变换红外光谱、X射线衍射、高分辨固体~(13)C核磁共振谱~(13C-NMR及X光电子能谱等方法，全面地研究分析了所选煤样的惰质组、镜质组的分子结构及煤中氧的赋存形态，得到所选煤样惰质组分的分子结构特征及结构参数，分析比较了惰质组与镜质组在分子结构上的差异性，并讨论了惰质组分的分子结构特征及结构参数随煤变质程度的变化规律；同时，通过研究得到了所选原煤样及其显微组分中总氧含量及各种不同类型含氧官能团的含量分布特征。

The cell organic substance and pigment composition was no much change after magnetic treatment. 4. Response of the antioxidant system of C.

磁处理对藻细胞的分子官能团结构没有产生明显影响，色素组成也不变。

The Pd-catalyzed Suzuki-Miyaura cross-coupling reaction is one of the most efficient methods for the construction of C-C bond.

Suzuki偶联反应是一种形成C—C键的有效方法，在有机合成中发挥着重要的作用。该反应具有反应条件温和、可适用多种活性官能团、受空间位阻影响不大、产率高以及芳基硼酸经济易得且对潮气不敏感等优点，因而得剑广泛应用。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。