官能团

ABSTRACT Power electronics devices are developed rapidly. There are some factors which influence the protective properties of the devices, including such as electrical characteristics of protection materials, the interface conditions of protective materials-pn junction, the surface effective charge density, the polarizable or unpolarizable properties of organic protective materials, etc.

电力半导体器件是近期发展起来的一类功率电子器件，其表面保护与其它电气元件不同，一方面要考虑器件表面绝缘保护材料的电性能和含杂等因素；另一方面，器件的表面钝化保护材料与器件接触后，器件的界面情况、材料与器件接触带电情况、以及材料所含官能团的极性等情况，也是影响器件性能的主要因素。

Using classical diazotisation of anilines, 5-(4-aminophenyl)-10,15,20-triphenyl-porphyrin was converted to a series of meso-tetraarylporphyrins with different substituents, including 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin (80%), 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin (74%), 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin (76%), 5-(4-hydrazinephenyl)-10,15,20-triphenylporphyrin (67%) and 5-(4-bisphenyl)-10,15,20-triphenylporphyrin (32%). Therefore an efficient way of synthesizing unsymmetrically substituted TAPs was developed.

利用芳胺的重氮化及重氮盐反应，研究了5-(4-氨基苯基)-10，15，20-三苯基卟啉上氨基官能团的转化反应，以较高产率合成了5-(4-羟基苯基)-10，15，20-三苯基卟啉(80%)、5-(4-氯苯基)-10，15，20-三苯基卟啉(74%)、5-(4-碘基苯基)-10，15，20-三苯基卟啉(76%)、5-(4-肼基苯基)-10，15，20-三苯基卟啉(67%)和5-(4-联苯基)-10，15，20-三苯基卟啉(32%)等一系列含单个para-取代基的meso-四芳基卟啉，为合成不对称取代的芳基卟啉提供一条有效途径。

Particularly, the neutral anion fluorescence chemical sensor uses cholic acid molecules as the molecule frame, and introduces a neutral thiourea or ureido to the positions of a 3 bit carbon atom and a 24 bit carbon atom to be used as a bonding unit; a fluorescence chemical functional group is introduced to the positions of the 3 bit carbon atom and the 24 bit carbon atom or to other positions and used as a signal unit, and then a neutral anion fluorescence chemical sensor is synthesized.

具体而言是以胆酸分子为分子骨架，在其3位碳原子和24位碳原子上引入中性硫脲或脲基，作为键合单元；在3位碳原子和24位碳原子上或其他位置引入具有荧光化学官能团，作为信号单元，合成中性阴离子荧光化学传感器。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-bPCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过RAFT活自由基聚合方法制备聚（苯乙烯-b-对氯亚甲基苯乙烯）二嵌段共聚物，其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应，最终获得了含有1，2，3-三氮唑官能团的聚苯乙烯二嵌段共聚物，核磁共振谱表征结果证明，PS-b-PCVB中的氯亚甲基完全转变成了1，2，3-三氮唑基团。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-b-PCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过可逆加成－断裂链转移聚合活性自由基聚合方法制备了聚（苯乙烯－b-对氯亚甲基苯乙烯）二嵌段共聚物，其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应，最终得到了含有1，2，3-三氮唑官能团的聚苯乙烯二嵌段共聚物，核磁共振谱表征结果证明，PS-b-PCVB中的氯亚甲基完全转变成了1，2，3-三氮唑基团。

In addition to complex anion crowd carried by organic functional group, there were many kinds of mass point like aluminum, silicon, zinc and rare earth elements et al in composite elastic material, and there were replaceable cation as well as anion; besides, all cation kept rather distant each other. It was not easy to crystalize in composite elastomer because of the block of organic molecule.

在复合弹性体材料中，除了存在有机官能团所带有的络阴离子群之外，还同时存在铝、硅、锌和稀土元素等多种质点；存在可以置换的阳离子和阴离子，并且各种阳离子都保持相当远距离；由于有机分子的阻挡，复合弹性体内不易析晶。

The salt effect of biosorption process might be related with the radii of cations and the stability of chelates, maybe also related to the interaction between anions and functional groups which had positive charge.

生物吸附过程的盐效应可能与阳离子的半径以及与配位体所形成的配合物的稳定性有关，也可能与菌体表面带正电荷的官能团与阴离子之间的静电作用有关。

At the same time, the fouling mechanism of membranes given in this thesis can give a reasonable explanation on the change of membrane performance. Our results show that the magnetization of membranes can effectively improve the anti-fouling ability of the PAN- Fe_3O_4 membrane. The obtained result may give insight to the development of new membranes with a good anti-fouling performance in the filtration of blood solution. No chemical bond was found between PAN and Fe_3O_4 in the membrane at room temperature. The addition of Fe_3O_4 can improve the temperatures of dehydrogenated reaction and decomposition of PAN but dot change the glassy transition temperature. The resistance against acid is stronger than the resistance to base for a PAN- Fe_3O_4 membrane.

结果表明在PAN- Fe_3O_4超滤膜制备过程中使用外加磁场作用能有效提高膜的耐污染能力，这一结果为开发适用于血液处理的耐污染超滤膜提供了一种新途径；在PAN- Fe_3O_4超滤膜中，四氧化三铁与PAN在室温下没有形成化学键，也不存在官能团之间的相互作用；添加Fe_3O_4对膜的玻璃化温度没有影响，但能提高PAN环化脱氢反应的温度和分解温度；PAN- Fe_3O_4超滤膜的耐酸性强于耐碱性，在pH值为10以上的溶液中由于水解作用而溶解，使得膜失去使用价值，膜的耐酸性与酸的种类、浓度和氧化性有关。

In this project, we have prepared conveniently Si-Mg 1,1-difunctional group reagents-α-silylvinyl Grignard reagents by hydromagnesiation of alkynylsilanes; Se-Br 1,1-difunctional group reagents-α-bromovinylselenides by hydrobromination of alkynylselenides; Sn-Br and Sn-I 1,1-difunctional group reagents by hydrozirconation of alkynylstannanes followed by halogenating reaction.

本项目通过炔基硅烷的镁氢化反应，方便地制得了Si-Mg 1，1-双官能团试剂-α-硅基烯基镁化物；通过炔基硒醚的溴氢化反应，方便地制得了Se-Br 1，1-双官能试剂-α-溴代烯基硒醚；通过炔基锡烷的锆氢化反应，继而卤代方便地制得了Sn-Br和Sn-I 1，1-双官能试剂。

The structure of the organosilane moieties and ultrasonic treatment time were all significant for the quantities of grafted amino groups .

有机官能团的结构和超声波处理的时间对于嫁接有机基团的量很重要。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。