官能团

Pymetrazine is chosed as the lead compound, and 21 compounds were firstly designed and synthesized. These compounds were characterized by introducing phenyl derivatives with different functional groups to replace pyridine ring with the isosteric principle and the method of homogeneous synthesis and reasonable biologically designing in order to find new compounds with potential biological activity. These compounds were confirmed by IR, H NMR and MS spectra.

本文选取吡蚜酮为先导化合物，运用电子等排理念，综合类同合成、生物合理设计的方法，引入含有不同官能团的苯基衍生物替代吡蚜酮的结构中心吡啶环，设计合成了21个未见文献报道的化合物，寻找具有潜在生物活性的新三嗪酮类化合物，通过核磁共振氢谱、红外光谱、质谱等手段进行了结构表征，并验证正确。

The result showed all the characteristic absorption peaks of hydroxyl-naphthaoquinone in the FT-IR spectrum of the product. The constituents of the product were determined by GC-MS to be: 1, 4-naphthaoquinone, 5-hydroxy-1,4-naphthaoquinone and 7-methoxy-1-tetralone, and the content of juglone in the product was 96.42%. The structure of juglone in the product was confirmed by 1H NMR. This study offered a simple and effective method to get high purity juglone from bark of J. mandshurica.

分别用FT-IR表征了产品的有机官能团、用GC-MS分析了产品的化学组成和产品中胡桃醌的相对含量（GC含量达96.42%）、通过1H NMR确认了产品的胡桃醌结构本研究提供了一种从核桃揪树皮中简便快捷地提取制得高纯度的胡桃醌产品的方法。

It is shown that the of the porous carbon towards (I_2) depends on the pore volume of the porous carbon; the adsorption of the porous carbon towards phenolic compounds depends on the density of carboxylic and lactonic groups on the surface of the porous carbon; the adsorption of the porous carbon towards Cr d...

发现多孔炭对酚类化合物及Cr的吸附以化学吸附为主，其中对酚类化合物的吸附由羧基与内酯基的表面密度合量决定，对Cr的吸附由表面官能团中羧基和内脂基含量的合量决定；多孔炭对I2的吸附以物理吸附为主，由孔容决定。

Silver nanoparticles with average particle size ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using 10 kinds of different functional group-containing organic modifiers, such as polyvinylpyrrolidone, tween-80, sodium dodecyl sulfate, sodium polyacrylate, polyethylene glycol, D-sorbitol, sodium dodecyl sulfonate, sodium dodecylbenzene sulfonate, polyvinyl alcohol, cetyltrimethylammonium bromide, at room temperature.

摘 要：选择10种含有不同官能团的有机物为表面修饰剂，如聚乙烯吡咯烷酮、吐温-80、十二烷基硫酸钠、聚丙烯酸钠、聚乙二醇、山梨醇、十二烷基磺酸钠、聚乙烯醇、十二烷基苯磺酸钠和十六烷基三甲基溴化铵等，在室温下进行了平均粒径在2～131nm范围内纳米银颗粒的控制合成研究。

As mercapto -function group has strong sorption on methyl mercury, an experiment was conducted to reveal the effect of the substances containing mercapto -groups on transfer and transform of mercury in soil by adding wool whose decomposed products consisting of abundant mercapto -composition.

巯基对汞特别是甲基汞有强烈的吸附作用，本试验通过对土壤添加富含巯基官能团的羊毛，初步研究含巯基物质在土壤环境中对土壤汞迁移转化作用的影响。

Moreover, Oxygen-containing groups such as methoxyl, carbohydrates, carboxylic/carbonyl, were also very different among four HAs

另外不同腐殖酸之间，含氧结构单元如甲氧基、碳水化合物结构、羧酸/羰基官能团等的含量也明显不同。

Monofilm of silane on the surface of the glass substrates is prepared via the method of self-assembled monolayers, Hf (SO4)24H2O and HCI are used as raw materials, HfO2 thin films are prepared on the active groups of the alkyl silane by the liquid phase deposition.

利用自组装单层膜技术，在玻璃基板上生长有机硅烷单分子膜层，以Hf(SO4)24H2O和HCI配制HfO2前驱液，通过液相沉积在硅烷的功能性官能团上诱导生成二氧化铪薄膜。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

In this article, star-high vinyl content polybutadiene was prepared using a multi-functional organolithium anionic initiator by " one-step " process. On the basis of 250ml glassware experiment ,we improved the experiment in 2L metal kettle. The polymerization condition was got as follows: polymerization temperature : 50-60 ℃, monomer content : 8-llg/100ml, polymerization time : 3~4 hours.Chracterizations were carried out by 'H-NMR, IR and GPC.

本文首次采用多官能团有机锂引发剂一步法合成出了星型高乙烯基聚丁二烯，在250ml玻璃瓶的基础上，进行2L金属斧的扩大实验，确定了以下聚合工艺参数：聚合反应温度：50～60℃，单体浓度：8～11g／100ml，聚合反应时间：3～4小时。

Because there are many articles about organozinc reagents react with aldehyde, we investigated the preparation of bisorganozinc reagents and its reactions.

第一章：有机卤化锌试剂在有机合成中研究进展本章主要对有机锌试剂，特别是带官能团的有机卤化锌试剂的产生、发展、制备及其在有机合成中的应用作了详细的综述。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。