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季铵化合物

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Double son quarter the 铵 salt surface live is a type of new double with live sub- surfaces, it is pass to unite to connect 基 regiment 2 two close body at head 基 or tight depend head the 基 conjunction get up of compound.

双子季铵盐表面活性剂是一类新型的双子表面活性剂,它是通过联接基团将两个两亲体在头基处或紧靠头基处连接起来的化合物。

The molecular charge distribution of the reactivator is affect the reactivating efficacy directly. Moreover its association with hydroximic acid dissociation constant pAa closely, and it will have a great impact on reactivating ability indirectly.(3) There is likely to exist front molecular interaction between Cholinesterase Reactivators and OPC-inhibited AChE, the action sites mainly lie on the aromatic ring, the substitute R and the hydroixic acid group. They act on the aromatic residues of AChE by Π-Π conjugation .(4) The reached results by Comparative Molecular Field Analysis is useful to design new higher efficacy derivatives for 1, 2, 4-oxadiazole class nonquaternary Cholinesterase Reactivators.

2复能剂分子的电荷分布直接影响复活活性,同时对肟酸解离常数pKa具有重要影响,间接影响复活能力;(3)复能剂与磷酰化酶可能存在前线轨道作用,作用部位可能主要在芳香环及其取代基R和肟基上,与AchE的芳香族残基发生л-л电子作用;(4)通过比较分子力场法研究可以指导1,2,4-oxadiazole类非季铵肟胆碱酯酶重活化剂新化合物的合成,可能得到活性更高的复能剂。

The purpose of this paper is to synthesize some phosphonium salts with PPh3 and some chiral quaternary ammonium salts with L-Valine. And we also use L-Valine and L-Phe-OMe to synthesize a new type catalyst —2,5-diketopiperazine , the simplest compound of cyclo-peptide.

本文利用廉价易得的三苯基磷和手性L-缬氨酸作为起始原料,合成了几种普通季鏻盐和手性季铵盐,并且利用L-缬氨酸与L-苯丙氨酸甲酯反应,合成了一种新型的相转移催化剂——2,5-二酮哌嗪环类的化合物。

ABSTRACT Inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles whose inhibition is caused by chemical adsorption and quaternary ammonium salts whose inhibition is caused by physical adsorption are mainly studied from microscope through quantum chemistry calculation, and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by making use of model-constructing thought of grey theory in this paper.

本文主要通过量子化学计算,从微观角度研究了化学吸附型缓蚀剂苯腈类化合物和物理吸附型缓蚀剂季铵盐在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系;并运用灰色理论建模思想,研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。其中,通过量子化学计算,从微观角度研究物理吸附型缓蚀剂在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系,是在尝试着进行;而运用灰色理论建模思想,研究缓蚀剂缓蚀性能与分子结构的关系,是一项具有尝试性和开拓性的工作。

In this thesis, two classes nonquaternary Cholinesterase Reactivators (1,2,4-oxadiazole and a -ketothio Hydroximic Acids derivatives ) and some clinical therapy used reactivators added to almost 40 cases have been caculated by using Comparative Molecular Field Analysis,ab initio and molecular mechanism methods. The characteristics of the molecular orbitals and the quantitative structure-activity relationship have been investigated.

本文利用比较分子力场法,量子化学从头算法,分子力学及计算化学回归分析等方法,对1,2,4-oxadiazole类非季铵肟胆碱酯酶复能剂,α—酮硫代异羟肟酸酯复能剂及部分现临床使用的复能剂,近40个化合物进行了计算,分析和研究了其电子结构和几何结构特征,建立了定量构效关系方程,得到了以下一些有意义的结果。

After coupling diazotized p-chloroaniline with imidazole, the resulting monoazo dye is quaternized with dimethyl sulfate. Upon dimethylamination, the ...

对-氯苯胺重氮化后,与咪唑偶合,生成单偶氮染料,与硫酸二甲酯季铵化,所得季铵化合物再经二甲胺基化即为题示染料。

A new imidazolinyl intermediate is prepared from phenylacetic acid and diethylenetriamine firstly, and then they react with the solution of sodium chloroacetate into the imidazolinyl quaternary ammonium salt.

以二甲苯为溶剂,苯乙酸和二乙烯三胺为原料,经酰胺化和环化脱水合成了新型咪唑啉化合物,并用氯乙酸钠溶液对其进行改性得到了苯乙酸咪唑啉季铵盐。

All these compounds contain hydroxy groups and can be used as hydrophilic chain-extenders in the synthesis of cationic polyurethane ionomers.

这些化合物(或与含三羟基的化合物配合使用),可以作为季铵阳离子型聚氨酯离聚物的扩链剂。

The results also show that this is suitable method to collect quaternary ammonium compounds from seaweeds.

分析结果表明,海藻中季铵化合物的含量很丰富;绿藻特别是浒苔中的季铵化合物含量最高可达到1.31 %。

With the key product of acrylamide,it mainly produces varieties of polyacrylamide and its derivatives,polyacrylic acid and its multipolymer,water soluble polymer products such as polyamine and poly quaternary ammonium compound,super strong suction resin and fortified rubber,etc.

企业以丙烯酰胺系列为龙头,主要生产各种规格型号的聚丙烯酰胺及其衍生物、聚丙烯酸及其共聚物、聚胺和聚季铵化合物等水溶性高分子产品和超强吸水树脂、高苯乙烯橡胶等。

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随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

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