季盐

Studies on biquaternary ammonium salt algaecide for removing red tide;2. Its main composition is biquaternary ammonium salt .

为了解决循环冷却水中的微生物问题，克服目前常规使用的季铵盐杀菌剂的不足，研究开发了一种新型非氧化性杀菌剂TS-838，其主要成分为双季铵盐。

In this paper, through a series of experiments, two series of quaternary-ammounium Gemini surfactants were synthesized, namely the pair alkylene double quaternary ammonium salt surfactant m-s-m·2Br and the pair the alkylene double quaternary ammonium salt surfactant -s-·2Br. We has carried on the attribute with the infrared spectrum to its structure, and to affected the factor which the synthesis pair the alkylene double quaternary ammonium salt surfactant responded to carry on the discussion. We has discovered the synthesis pair the ethylene double quaternary ammonium salt surfactant m-2-m·2Br optimum condition: The bromo alkane and a tetramethyl ethylene diamine mole of ratio is 3.0: 1.0, makes the solvent by the ethyl alcohol, 80℃ under responds for 48 hours in the backflow temperature; Synthesis pair alkylene double quaternary ammonium salt surfactant 12-S-12 ·2Br optimum condition: 12 tertiary amine and 1, 3- propylene dibromide (1, 4- two bromines butane) a mole of ratio is 2.2: 1.0, makes the solvent by the ethyl alcohol, responds for 48 hours in the constant temperature 80 ℃ under backflow.

本文通过一系列的实验，合成了两个系列的Gemini型表面活性剂，即双烷撑双季铵盐表面活性剂m-s-m·2Br和双烷撑双季铵盐表面活性剂-s-·2Br，用红外光谱对其结构进行了表征，并且对影响合成双烷撑双季铵盐表面活性剂反应的因素进行了讨论，找出了合成双乙撑双季铵盐表面活性剂m-2-m·2Br的最佳条件：溴代烷与四甲基乙二胺的摩尔比为3.0：1.0，以乙醇作溶剂，在回流温度80℃下反应48小时；合成双烷撑双季铵盐表面活性剂12-s-12·2Br的最佳条件：十二叔胺与1，3-二溴丙烷(1，4-二溴丁烷)摩尔比为2.2：1.0，以乙醇作溶剂，在恒温80℃下回流反应48小时。

On the basis of analyzing data about stearic acid triethanolamine ester quaternary's preparation process and methods of analysis and identification, this article summarized synthetic conditions for this quaternary ammonium salt, this synthetic condition composed by synthesis of esters and quaternary ammoniation.

在对有关硬脂酸三乙醇胺酯季铵盐的制备工艺、分析鉴定方法的资料分析的基础上，综述了由硬脂酸制备该季铵盐的工艺条件，该工艺条件由酯胺的合成和季铵化2步构成。

In this paper, a quaternary ammonium salt of chitosan was synthesized and the factors affect on the solubility or degree of substitution of product, such as the concentration of alkali, the time of basification, the content of water in system, the time of dispersing and the method of adding epoxyproryltrimethylammonium chloride, were discussed in detail. The product was characterized by IR, DSC, TG and X-RAY diffraction. The effects of time, humidity and temperature on the gases permeability of the quaternary ammonium salt of chitosan film were researched.

本论文研究了壳聚糖季铵盐的合成反应，对碱化浓度、碱化时间、水的含量、分散时间和醚化剂的加入方式等因素对制备反应的影响进行了考察；应用红外光谱、DSC、TG以及X-射线衍射对产物进行了表征；探讨了时间、湿度和温度对壳聚糖季铵盐膜透气性的影响。

Qualitative and quantitative mensurations were done to the cationic surfactants with the methods of basic bromophenol blue and potassium ferricyanide.

通过对1227、1231、1631和FC-911四种季铵盐阳离子表面活性剂的定量分析，确定阳离子表面活性剂最佳的定量分析方法为铁氰化钾法，运用此法测得合成季铵盐的产率。

The factors affect on the degree of substitution of product, yield and apparent viscosity, such as the mol rates of EPTAC with -NH2, reaction temperature, reaction time and the content of water in system have been discussed in detail. FTIR spectrometer and UV spectrometer are used to characterize the structure of the derivative and it is proved that substitution reaction mainly occurs on the -N element .The particle size and morphology of chitosan and quantemary ammonium salt of chitosan are analysised by comparing photos of their scanning electron microscope. The degree of substitution of HACC is determined by acid -base conductometric titration. An error in current formula of DS has pointed out and a correct formula has presented.On the base of experience of above experiment, the reaction conditions of HACC were systematically investigated through orthogonal design, and then the best conditions are found. Water-solubility and dependence of pH are studied.

壳聚糖和环氧丙基三甲基氯化铵在异相条件下发生反应，通过单因素实验，制备了一系列不同性能的壳聚糖季铵盐，本文首次详细讨论了反应条件(反应摩尔比、反应时间、反应温度、水含量)对产率及产物性能的影响；用红外光谱和核磁共振对结构进行表征分析时，发现季铵盐阳离子基以N位上取代为主；通过电镜图片对壳聚糖和季铵盐衍生物外观形貌进行对比，采用酸碱电导滴定法测定产物的取代度，并对常用取代度公式做了修正。

Water, Sodium Laureth Sulfate, Cocamidopropyl Betaine, Cocamide MEA, Disodium Cocamphodiacetate, Sodium Lauryl Sulfate, PEG 40 Hydrogenated Castor Oil, Perfume, Sodium Chloride, Propylene Glycol, Quaternium 80, Methylparaben, Polyquaternium 10, Hydroxypropyl Guar Hydroxpropyltrimonium Chloride, Citric Acid, Diazolidinyl Urea, Tetrasodium EDTA, Polyquaternium 7, Propylparaben, Sodium Hydroxide, Panthenol, Persea Gratissima Oil, Penta Sodium Pentetate, Hedera Helix Extract, Bambusa Vulgaris Extract

水，月桂醇聚醚硫酸酯钠，椰油酰胺丙基甜菜碱，椰油酰胺MEA，椰油酰两性基二乙酸二钠，月桂醇硫酸酯钠，PEG 40 氢化篦麻油，香料，氯化钠，丙二醇，季铵盐-80，苯甲酸甲脂，聚季铵盐-10，羟丙基瓜尔胶羟丙基三甲基氯化铵，柠檬酸，重氮烷基咪唑脲，乙二氨四醋酸四钠，聚季铵盐-7，对羟基苯甲酸丙酯，氢氧化钠，泛酰醇，酪梨油，喷替酸五钠，常春藤萃取物，银竹萃取物。

One route was that the amino-groups on the silica gel were transformed to tertiary amines by Eschweiler-clarke reaction that amine-groups react with formaldehyde and methanoic acid to prepare tertiary amines; the silica gel intermediates with tertiary amine groups reacted with chorohydrocarbons to prepare insoluble silica gel quaternary ammonium salt bactericides. Another route was that the amino-groups on the silica gel reacted with excessive chlorohexadecane; the preparing intermediates were quaternized with iodomethane to obtain insoluble silica gel quaternary ammonium salt bactericides.

一条路线是根据埃施韦勒-克拉克(Eschweiler-clarke)胺甲基化反应，进行胺基叔胺化反应，制成带有叔胺官能团的硅胶中间体，此中间体上的叔胺与卤代烷反应生成杀菌活性官能团季铵盐，制成硅胶类水不溶性季铵盐杀菌剂；另一条路线是带有胺反应活性中心的硅胶与过量正氯代十六烷反应，得到的中间体再用碘甲烷季铵化，得到最终产品——水不溶性季铵盐杀菌剂。

Dialkyldimethyl quats,and imidoamine quats are still quite popular in the United States,South America,and Asia.

在织物柔软剂的原料中，双烷基二甲基季铵盐，酰胺基二甲基硫酸甲酯季铵盐，以及含咪唑啉的季铵盐在美国、南美和亚洲等地仍然很流行。

The adsorptive properties of gas-liquid interface and liquid-solid interface of bisquaternary ammonium salt surfactant are used as object to study the surface tension of BQAS changing with its concentration,adsorptive isothermal line,saturated adsorption and minimum balance time.

以研究双季铵盐型表面活性剂BQAS吸附特性为目的，从溶液表面张力随浓度的变化、饱和吸附量等方面研究了双季铵盐BQAS的气液界面吸附特性；用双季铵盐BQAS和砂岩体系，在液固比一定时，从时间、浓度对静态吸附量的影响方面研究了双季铵盐BQAS的液固界面吸附特性。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。