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The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应,用茚〓和1,1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物,发现可控制反应条件,使1,1'-联茚与〓反应,并高产率地得到具有新颖结构的单加成物,用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征,测得它的两个〓杂化的桥头碳的化学位移为〓ppm,证明生成的衍生物为6∶6闭式环加成,〓NMR谱中共给出38个信号,表明〓联茚衍生物分子具有〓对称性;在波长532nm,脉冲宽度8ns的激光下,〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近,由于〓联茚单加成衍生物熱稳定性好,在四氢呋喃,丙酮等极性溶剂中溶解性好,能分别均匀地掺入溶胶-凝胶中,已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能;使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究,通过等温压缩曲线测试,证明浓度为〓〓时,〓联茚衍生物能够形成单层膜。

Then research them, find out how long they've been around, check out the Better Business Bureau information on them.

然后研究,从而找出了多久,他们一直在周围,检查出更好的营商局关于这方面的资料。

The experimental results showed that the wire beam electrode could be used to study inhomogeneity of localized corrosion of metals.

结果表明,采用丝束电极技术能较好地研究金属局部腐蚀的不均匀性。

This paper will take emphasis on the study of Kerberos and GSI authentication mechanism, inosculate the two kinds of mechanism in order to reach the point of better security effect.

本文着重研究Kerberos认证机制和GSI认证机制,实现这两种机制相整合,以达到更好的安全效果。

What's more, we also study some key techniques and realization difficulties of image authentication in-depth, including referent block to help tamper localizing, sign bit adjustment for binary encoding, mean quantization improvement, diagonally extension to help tamper localizing, and discard isolated error point to tolerate incidental distortion. These techniques can be used for good reference to the development of image authentication technique.

此外,我们还对数字图像鉴别的一些关键技术和实现难点进行了深入研究,主要包括有:参考点辅助定位技术、二值编码中的符号处理技术、均值量化方法的改进技术、对角扩展和去除孤立点技术等,这些技术的研究都对数字图像鉴别技术的发展具有很好的借鉴意义。

An Isothermal two-phase model has been proposed on the basis of theoretical and experimental study.

六、在理论和实验研究基础上,提出了等温两相数学模型,较好地描述了超临界苯烃化反应中催化剂结焦失活的过程。

K. Kinkle,"Comparison of extraction methods for quantifying extracellular polymersin biofilms", Water Science and Technology, vol.

罗曦,雷中方,张振亚,杉浦则夫,「好氧与厌氧污泥胞外聚合物的提取方法研究」,环境科学学报,第二十五卷,第十二期,2005。

This thesis is a good attempt for pushing forward the engineering application of semi-aerobic landfill in our country.

本研究是对推动准好氧填埋技术在我国尽早应用的一次有益尝试。

We found that porphyran is a kind of good material for optical limiter.

研究发现,卟啉类反饱和吸收材料有很好的光限幅作用。

It was found that theintrduction of polar phosphatidylcholine to LLA chains had largely changed thehydrophilicity of the synthesized polymers. And from the research ofendothelioid cell (ECV304) compatibility and adhesion of blood platelet, wefound that the cells adhesion of ECV304 on the films of PLLA-PC-PLLA lagedcomparing to PLLA, but then could proliferate and cover the films in total,PLLA-PC-PLLA, the same as PLLA are not cytotoxicity and ECV304 canattach and proliferate on them, and PLLA-PC-PLLA can reduce the adhesion ofblood platelet.

结果表明:由于聚乳酸中磷脂酰胆碱结构的引入,使得该材料的亲水性得到很大的改善,并且随着聚合物中磷脂结构单元比例的增高其亲水性能就越好;通过对该材料进行细胞亲和性的实验研究,发现这种材料能够使细胞锚着并支持细胞的增殖;而血小板黏附的实验结果初步显示了该材料具有较好的抗血小板黏附的性质。

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推荐网络例句

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。