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The etherification reaction of methanol and isoamylene was investigated in an internal recycle gradientless reaction with an ion exchange resin (NKC-9) as catalyst.

采用国产大孔磺酸树脂(NKC-9),在无梯度反应器内对异戊烯与甲醇醚化反应进行了研究。

Synthesis of isobornyl methacrylate by using macroporous sulfonic ion exchange resin as catalyst has been realized.

大孔强酸性高于交换树脂为催化剂合成甲基丙烯酸莰醇酯。

Woodson or apocynum venetum Linn as raw material, it utilizes the method of decoction and alcohol sedimentation to remove impurity. After extract is separated by macroporous adsorptive resins, then use polydextran gel LH-20 to purify, obtain isoquercitrin. Compared with the method of traditional silica gel column chromatography, this method has characteristics such as: experiment period is short, dissipation of organic dissolvent is little, yield of produced product is high, and purity coefficient is fine and so on. Isoquercitrin produced by this invention can be provided for medicine research or used as chemistry control article.

Woodson或罗布麻的叶为原料,采用水提醇沉除杂的方法,提取液经大孔吸附树脂分离后再用葡聚糖凝胶LH-20纯化得罗布麻甲素,此法与传统硅胶柱层析的方法相比,具有实验周期短,有机溶媒消耗少,制得的产品得率高和纯度好的特点,本法制得的罗布麻甲素可供药物研究或化学对照品使用。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene, PDVB)为第一网,具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine, PAEM)为第二网的疏水/亲水大孔聚二乙烯基苯/聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks, IPN),研究这类疏水/亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学;测定了该树脂对香兰素在不同温度下的吸附等温线,吸附等温线符合Freundlich等温吸附方程,利用热力学函数关系计算出了吸附焓、自由能和熵变。

Objective To study the conditions and effects of purification of the extract of Ligusticum chuanxiong Hort. by adopting macroporos resin.

目的 探讨大孔吸附树脂对川芎提取物的纯化条件及纯化效果。

The main research includes: Using ethanol extrat and macroporous resin refining to isolate kaempferitrin from Ligustrum sinecse Lour.

主要研究工作包括:采用乙醇提取-大孔吸附树脂精制的方法提取光叶小腊树花中的山柰苷。

Results:The optimal extraction method was that Curcuma longa L.

渗漉法提取及大孔树脂分离正交试验。

The adsorption and desorption performance of eight macroporus adsorbent resin for separation red pigments from Magnoliaceae×soulangeana flower,and determination of pigments by high pressure liquid chromatographywere studied.

探讨了八种大孔树脂对二乔木兰花红色素组分的分离性能,并进行了色素成分的高效液相色谱法分离。

A new type of large pore PP used to graft MAH was also studied.

还探讨了以新型大孔PP用于MAH固相接枝的可行性。

Objective To explore the optimal techniques in separation of phenols from Melastoma dodecandrum with macroporous resins.

目的 筛选大孔树脂分离纯化地菍中总酚类物质的最佳工艺。

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