大分子单体

The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法，包括单体合成和聚合物的合成，聚合物的合成是在严格无氧无水条件下，在金属钴配合物三-三苯基磷氯化钴，加入环戊二烯钠单体，随后加入双内炔或双外炔共轭单体，反应后沉淀，过滤，洗涤，真空干燥，得到含环戊二烯茂钴有机金属钴的大分子聚合物。

When the concentration of MAH is higher than that of St, some MAH monomer reacts with St to form SMA, others can directly grafts onto PP macroradicals. When the amount of St added is higher than that of MAH, part of St monomer may preferentially react with PP macroradicals to form more stable styryl macroradicals, while others copolymerize with MAH, yielding SMA. MFR of the grafted PP is lower in this case. It is considered that MFR of the grafted PP is decided by concentration of free monomers, or, number of grafting reactive species. FTIR analysis confirmed the above mechanism.

当MAH单体用量多于St单体时，一部分MAH单体与St反应生成SMA，另一部分可直接与PP大分子自由基进行接枝反应；当St单体用量多于MAH单体时，除与MAH反应生成SMA之外的St单体可先与PP大分子自由基反应，并起到稳定PP自由基的作用，这时接枝物的MFR较小，亦即接枝物的MFR与体系中可进行接枝反应的活性种数目有关。

This dissertation successfully fabricated cross-linked polysiloxanes under base catalysts such as potassium hydroxide siloxanolate or tetramethylammonium hydroxide (Me_4NOH) siloxanolate by anionic ring-opening copolymerization of cyclosiloxanes and Polyhedral Oligomeric Silsesquioxanes as multifunctional monomers.

本论文首次通过阴离子开环共聚，成功地将POSS大分子作为多官能团单体，与环硅氧烷在KOH硅醇盐或Me_4NOH硅醇盐等碱性催化剂的作用下，直接合成交联聚硅氧烷：通过调节POSS大分子和环硅氧烷单体的种类以及化学计量比，可合成出一系列不同种类和不同交联密度的交联聚硅氧烷；并对其阴离子开环共聚机理以及极性调节剂DMAc对凝胶时间的影响进行了详细讨论；同时借以凝胶含量和溶胀比、GPC、FT-IR、固体~(13)C和~(29)Si NMR、WAXD、DSC以及TG等手段对所得聚合物的微观结构以及热性能进行了详细考察。

A series of polymers containing 1,8-naphthalimide moieties in the side chains have been prepared via RAFT technique. Firstly, five styrene and two methyl acrylate based 1,8-naphthalimide monomers were synthesized and characterized. Then, carbazyl group terminated polystyrene was used as macromolecular RAFT agent.

我们合成了5种苯乙烯类和2种甲基丙烯酸酯类萘酰亚胺单体，以一种含末端带咔唑结构的聚苯乙烯为大分子RAFT试剂，考察了所得单体的RAFT聚合，发现苯乙烯类1，8-萘酰亚胺单体可以聚合，但是聚合度不高，甲基丙烯酸酯类1，8-萘酰亚胺单体RAFT聚合不可控。

In this paper, different methods to prepare T 8 and related functional compounds are introduced, then the applications of inorganic/organic polymer nanocomposites basing on T 8 and related macromer to the fields such as: photocurable resins, thermal-resistant an...

在叙述了从不同的前驱体制备功能性的 T8方法基础上，介绍了从 T8大分子单体出发制备的无机/有机聚合物纳米复合材料在光固化树脂、耐热阻燃材料、多孔材料、改性高分子材料等领域的应用。

The PMMA macromer was obtained by radical polymerization in the presence of 2-mercaptoethanol as a chain transfer agent, followed by termination with acryloyl chloride.

甲基丙烯酸甲酯进行自由基溶液聚合，巯基乙醇为链转移剂，然后用丙烯酰氯封端制备了聚甲基丙烯酸甲酯大分子单体。

n thes paper, the oligomers with different molecular weight of monohydroxylpolyethersulfones were synthesized in solution and the optimum condition ofpolymerization was obtained; With phase transfer catalyst method,the oligomerswas obtained and transformed to monovinylpolyethersulfones macromer. Its structure was characterized with IR and 1H-NMR.

本文采用溶液法以单酚（4－氯－4'－羟基二苯砜）为原料合成了不同聚合度的单酚低聚体，得到了控制聚合度的最佳聚合条件；用相转移催化剂法成功地将单酚转化为单烯大分子单体，并用IR、1H—NMR对其结构进行了表征；测定了双键官能度均在1.90以上。

Polyurethane-acrylate Macromer was synthesized by IPDI, HEMA and PEG, and a new kind of transparent polymer was preparaed by the Macromer crosslinked.

利用异佛尔酮－二异氟酸酯、甲基丙烯酸－β羟乙酯、聚乙二醇合成了一种聚氨酯丙烯酸酯类大分子单体，并将其固化交联得到一种新型透明材料。

The macromer cationically copolymerized with tetrahydrofuran to give a copolyether grafted with PEG chain. Using copolyether with about 1.3grafts per molecule, the S-PEU with PEG grafted onto soft segments was synthesized.

以四氢呋喃与少量大分子单体进行正离子开环共聚合制得每个链接有约1.3个PEG枝的聚丁二醇，用以合成了在软链段上接有PEG枝的聚醚氨酯。

Soluble comb-shaped polyether phosphate type polymer LPEP was obtained by polymerizing the phosphate macromolecular monomers with long side chain, which was prepared by reacting polyethylene glycol mono methyl ether and other compound with phosphoryl oxychloride.

来源：ABCd7论文网www.abclunwen.com对分子结构和合成工艺进一步改进，采用聚乙二醇单甲醚等与三氯氧磷反应合成了长链型磷酸酯大分子单体，聚合得到可溶性的梳状聚醚磷酸酯型聚合物LPEP。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新