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In addition, the systematic study on the polymorphisms of XLF-343, which is an innovative and solid drug, indicated that at least 5 polymorphisms were obtained, including 4 crystalloids and 1 amorphism.

此外,还对创新固体药物XLF-343进行了多晶型问题的系统性研究,发现该化合物至少存在5种以上晶型,4种为晶态,1种为非晶态。

The isothermally crystallized films of the low temperature fractions of the two PPEs possess the similar crystalline morphology, i. e., thinner and high content of cross-hatching lamellae. The main reason to create the different crystallization behavior between the two PPEs and their fractions was due to the different distribution of the copoymerized ethylene unit.

对于分级样品,PPE1和PPE2高温级份的结晶行为差别较大:PPE1的高温级份结晶时形成的片晶较厚并且交叉片晶的数量也较低,剪切时产生较多纤维晶;两个样品的低温级份结晶形态类似,即结晶时形成的交叉片晶的含量都较高,剪切产生纤维晶数量差不多。

According to the experimental observations from Fujiwara et al, when the undercooling is low enough, the (111) silicon will be the dominant orientation in the polycrystalline silicon. As the undercooling becomes much higher, the (100) will be the dominant orientation.

根据Fujiwara等人所进行的矽晶粒竞争生长实验,当过冷度很小时,生长出的多晶矽中,(111)晶向的矽晶占了大多数;然而在过冷度较大时,(100)晶向的矽晶则为多数。

The crystal-lization of this amorphous alloy is a multi-stage continuous nucleation up to saturation process. The local crystallization energy decreases gradually indicating that the thermal stability of the residual amorphous matrix becomes weak at the steady crystallization stage, which is ascribed to the diffusion of boron atoms at elevated temperatures.

进一步研究发现,该非晶合金的晶化为多阶段的连续形核直至饱和的过程;当进入稳定晶化阶段时,剩余非晶的局域晶化激活能逐渐下降,非晶基体的热稳定性降低,这是由B原子的高温扩散导致的。

The magnetic transition temperature decreases with grain size for the films and the Curies temperatures of the films is lower than the target with average grain size of 4 urn.

与平均晶粒尺寸为4μm的多晶块体样品相比,多晶薄膜的金属〓半导体转变温度均低于块体样品,并且多晶薄膜的磁化强度转温度的升高衰减的较快。

As we all know, thermochemistry is the direct application of thermodynamic in the field of chemistry.

近年来,纳米结构材料引起人们极大的兴趣,对这些由有限个原子构成的小颗粒,再由这些小颗粒凝聚而成的纳米结构材料在热化学方面有什么新的特点,它与颗粒尺寸的关系和粗晶、多晶材料所遵循的规律是否一致,已成功描述粗晶和多晶热力学行为的经典热力学理论对纳米材料是否还适用,这些问题是纳米材料的深入研究和推广应用所必须解决的关键问题。

In this paper,the forming mechanism and affecting favtor of bulk metallic glasses is systematically discussed from the aspects of thermodynamic, kinetic and microstructure . Thermodynamic factors which favor the amorphization of alloys analyzed, the glass forming range of ternary alloys system was proposed by using Miedema theory, Toop model and considering the influence of free energy of pure metals at different temperature. The approach was applied to predict the composition range of amorphous Mg-Cu-La alloys. Several methods(such as three empirical criterions ,binary alloys phase diagram , Miedema theory and Toop mode) were used to design a series of Mg65Cu25La10 、Mg68Cu17La15 and Mg57Cu23La20 alloys, These bulk amorphous alloys with maximum diameter thickness reaching to 1mm were prepared by means of graphite-molding casting though the raw materials are of a low purity by conventional casting processes at a low cooling rate.

本文从合金的热力学、动力学及结构形成条件方面系统的讨论了Mg 基大块非晶的形成机制及影响因素,并从非晶形成的热力学观点出发,综合应用Miedema理论和Toop 模型,并考虑纯金属在不同温度下的自由能,在此基础上提出了一种定量预测三元非晶合金形成范围的方法,用该方法计算Mg-Cu-La 三元合金系的非晶形成范围,应用多项技术(三经验原则、二元合金相图及Miedema 理论和Toop模型)设计了Mg65Cu25La10 、Mg68Cu17La15 和Mg57Cu23La20非晶合金。

The growth mechanism of silver seed on silicon has been presented: at first, the silver monolayer and multilayer firstly grows onto silicon without fully covering the surface at the expense of silicon etching due to the silver seed attracting the electron from silicon, after that, the monolayer coalesces together, forming continuous grain film with some silver atoms diffusing into the silicon and the multilayer still grows thick simultaneously.

提出了银晶籽在硅表面的生长机理是:首先是在硅表面没有被完全覆盖的情况下,单层银晶籽生长的同时伴随有多层的生长,此后单层逐渐形成连续的薄膜,在单层晶籽层上多层薄膜逐渐增厚,并伴随有部分银原子向硅中的扩散。

SiC polytypes of 6H and 15R and a transition zone between the two were observed under HREM and TEM and discussed from the point view of the crystal structures; the clear evidence of Al〓C〓 nucleated in the SiC particle was provided, indicating the aluminum penetrating the SiC grains is already carbon-saturated and, consequently, Al〓C〓 crystals grow in the particles wherever a temporary local supersaturating is produced; The experimental observation indicated that the types of the interface between SiC and Al are variable and the distribution feature of reaction product, Al〓C〓, were also given in the present work: to be nucleated on SiC, to be aggregated at SiC/Al interface zone or to be aggregated at the crystal boundaries.

通过高分辨透射电镜,本文观察到SiC增强体中6H和15R同质多晶现象及6H-15R SiC转变区,以及另外一种无序的SiC同质多晶,并从其晶体结构的角度解释了6H和15R在晶体内共存的现象。通过高分辨透射电镜,本文给出了Al〓C〓在SiC颗粒内部形核的明证,表明Al〓C〓形核是Al渗透到SiC颗粒内部在C过饱和处在SiC的(0006)面上而形核,而且一种可能的位相关系为A1〓C〓[11〓0]∥SiC[11〓0]。研究结果同时给出了SiC/Al复合材料的界面反应产物A1〓C〓的分布特征:在SiC上形核并生长,聚集于SiC/Al界面去附近,或者聚集于晶界上。

After irradiation of Ti-sapphire femtosecond laser followed by a thermo development which is photo-thermo-refractiveprocess,Li2O · Al2O3 · 3SiO2 micro crystalline phase structure is observed and confirmed in the glass matrix with the help of optical microscope and X-ray diffraction.

经近红外飞秒激光照射和热处理后,通过显微镜观察及X射线衍射分析发现,玻璃内部形成以银原子为晶核的Li2O·Al2O3·3SiO2多晶结构微晶,晶体细小,呈乳白色,为六方晶系,呈现空间取向分布结构。

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