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By employing such a method, 5 series of elastomers, including natural rubbers, elastomeric polyester fibers and ethylene-octene, ethylene-methyl acrylate as well as SIS triblock copolymers, were investigated with the purpose of studying elongation induced phase structure and mobility changes of the samples. For NR samples, it was demonstrated that there exists a small amount of crystals at RT even for unelongated samples. For both NR and the soft segment of PEE, with the increase of elongation ratio, the elongation-induced crystallinity increases almost linearly in a certain region of R, in accord with the increase of the lamellar thickness of the crystals; The behavior of ethylene copolymers, in terms of elongation induced morphorpholgy changes, are quite different from NR and PEE. The crystals are found to be gradually destroyed with the increase of R, with accord with the decrease of the lamellar thickness; The motional behavior of the soft segment of SIS, changes from "liquid" to "solid", in terms of 13C NMR spin-lattice relaxation.For many of the aformented samples, the dependence of 13C spin-lattice relaxtion time T1 on R are different for different groups, indicating that the changes of mobility at MHz frequency region with elongation are different for different groups.

通过对天然橡胶、聚醚酯嵌段共聚物、乙烯-辛烯共聚物、乙烯-丙烯酸甲酯共聚物、SIS等高分子弹性体样品聚集态结构和分子运动的研究,获得了一些新的实验结果,如:给出了确切的实验证据,证明了室温下未拉伸的天然橡胶样品中存在着微量的结晶;发现随着拉伸比增加,天然橡胶及聚醚酯样品的软段部分会出现拉伸诱导的结晶,且结晶度在一定范围内呈现近似线性的增加,所形成晶片的厚度也随之逐渐增加;而乙烯共聚物随着拉伸比的增加,原有的结晶会被逐渐破坏,晶片厚度逐渐变薄,结晶中的缺陷逐渐增加;随着拉伸比的增加,SIS中PI软段部分的核磁共振弛豫行为会出现从液态到固态的转变等;在对上述多个体系的研究中,还发现不同基团的自旋-晶格弛豫时间随着拉伸比呈现不同的变化趋势,表明不同基团的高频运动随拉伸比增加有不同的变化规律。

The results above showed:(1) The cultivars of large-flowered chrysanthemum are widely distributed in Beijing area with plentiful floral types and floral colors;(2) The cultivars with the rare types and colors are urgent for protection;(3) Most of the quantitative characters obeys to the normal distribution,some important traits agreed with skewed distribution.The probability grading can assist quantitative character in establishing new grading standards;(4) Most of qualitative characters is asymmetrical in cultivars,which might be caused by unbalanced differentiation of characters or linkages coming from emphasis characters selection;(5) The floral characters are relatively stable and have comparably large influence on classification,the characters of stipule also have a certain degree of stability and can act as an reasonable supplement for cultivars classification,but the foliar characters have worse stability and can only be recognized as lower level criterion.(6) The genetic relationship among the Flat-petaled group,the Quilled-petal group and the Spoon-petaled group are closest,which followed by the Filiform-petal group because of long-term selection pressure for the specialization of the petal tip loved by most people.The Anemone-petal group has further genetic relationship with these four groups.(7) ISSR molecular marker detection indicates that the proportion of polymorphic loci of lardge-flowered chrysanthemum is higher,in which the Flat-petaled group has the highest genetic diversity level.

综合以上的研究结果表明:(1)北京地区现有大量大菊品种,且花型与花色较为丰富;(2)珍稀花型、花色品种亟需保护;(3)大部分数量性状是符合正态分布的,少数重点观赏性状迫于选择压力呈现偏态分布,概率分级法能够辅助大菊的数量性状建立新的分级标准;(4)大部分质量性状在品种群内的分布是不均匀的,可能是由菊花性状遗传分化的不均衡性或受到选育重点性状的连锁作用而造成的;(5)大菊花部性状相对稳定,对品种分类影响较大,其托叶部分也具有一定程度的稳定性,可以作为品种分类的合理补充,而叶部性状稳定性较差,在品种分类中应作为更次一级的分类依据;(6)平瓣类、管瓣类和匙瓣类的亲缘关系最近,畸瓣类品种花瓣先端特化受到人们的喜爱,长期的选择压力使其区别于3种基本瓣型,而这四种瓣型与桂瓣类在亲缘关系上较远;(7)ISSR分子标记检测表明:大菊品种多态性位点百分率较高,平瓣类品种的遗传分化最为丰富。

From the phylogenetic tree constructed for IGF-I, the homology was as high as 95%, which revealed the relative relation between them was more closely than with others and give molecular biology support for the resolution of position and classification of lesser panda.

利用IGF-Ⅰ基因构建的进化树上,大熊猫和小熊猫此基因的同源性达到95%,并且显示小熊猫与大熊猫的亲缘关系与其它哺乳动物相比要近的多,为大熊猫及小熊猫的分类学提供了分子生物学的依据,但这样的结果也许与IGF-Ⅰ在物种间的高度保守性有关,我们认为,对于大小熊猫是否同属一科还需要进一步的研究。

The structures were studied by IR and NMR. The absorption frequencies of the carbonyl group markedly depended on the coordination no. of the tin atom. The chem. shifts of 119Sn and 13C and the 1J(119Sn-13Sn) coupling constants of the compounds were determine Small structural changes around the tin atom were reflected in the 119Sn chem. shifts. For tributyltin arylcarboxylates, a relationship between 119Sn chem. shifts and Hammett constants of the para-substituents was found. The biol. activities of same compounds have been studied. They may be used as fungicides for fruit.

通过对它们的红外光谱、核磁共振谱(^1^3C, ^1^1^9Sn)的研究,表明羰基红外吸收频率与锡原子的配位数有密切关系,同样分子上的微小变化明显地表现在δ119Sn上,对位取代基苯甲酸酯的δ119Sn与苯环上取代基的Hammett常数之间存在良好的线性关系:δ119Sn=19.11σ+110.612 n=7,γ=0.9955着重研究了部分化合物在经济作物上的抗病原菌能力,结果表明,这是一类具有广谱性的有机锡化合物,抗菌活性优于对比药剂朴海因,接近或相当于多菌灵,它们同时具有较强的除草活性。

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Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

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Chapter Three: Type classification of DE structure in Sino-Tibetan languages.

第三章汉藏语&的&字结构的类型划分。