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The mechanism of the reaction was studiedin detail,in which excited state avaliable to carryout the excited state intramolecular proton transferreaction was recognized.The INDO/S-CI semiempiricalMO method was used to calculate transition energiesand oscillator strength,and assign spectra theore-tically,the calculated spectra values were basicallyconsistent with the experimental values.Themolecular orbital properties for the adjacent HOMO-LUMO of various kinds of conformersand anion species,thetransition properties and symmetry for thetransition from ground state to lower excited stateswere analysed,especially,no much study on theanion species all of the world.

位能曲线的求法满足反应坐标是反应过程中能量最小途径的定义,较详细地研究了各类反应的质子转移历程,认定在哪个激发态有利于发生激发态分子内质子转移反应,用INDO/S-CI半经验MO方法进行跃迁能和振子强度计算及光谱的理论指认,计算的光谱值和实验值基本吻合,并分析了各种异构体和阴离子的HOMO-LUMO附近的轨道性质,各跃迁态的跃迁性质和对称性,尤其是对阴离子的研究国内外尚不多见。

The four sets of stator bars including those retired from three large generators and the standby bar subjected to Dynamic Mechanical Analysis, Scanning Electron Microscopic and optical microscope observation. It was revealed from DMA that the peak value tan d m of mechanical loss thermogram tan d ~ T shift toward a higher temperature and a lower amplitude, indicating that the amount of movement monomers diminished greatly in the insulation aging process, the tan d 195, increased very slightly with the service time of insulation, showing the degrading of bonding properties at interface, and the presence of more defects in insulation. The observation of SEM and optical microscope showed that more and more voids appears in insulation, and delamination was formed due to development of voids in aging process.

对不同运行年数的线棒进行了 DMA 、 SEM 、光学显微镜等微观分析试验,动态力学分析发现(参见 Hao et al, CEIDP, 2002:404),力学损耗温度谱 tan d ~ T 的峰值 tan d m 随老化时间向高温、低值方向移动,表明促成环氧发生玻璃化转变的活性侧基或发生局部运动的活性链段减少,分子链的刚性增强;195℃的力学损耗 tan d 195随老化时间有缓慢增大的趋势,表明有更多的能量耗散在界面处,界面的粘合性变差,甚至由于界面粘结不良出现微观缺陷; SEM 和光学显微分析发现(参见 Hao et al-2, IEEE DEI, 2003),老化后的绝缘气隙增多,随着老化时间气隙不断扩展或相互连通,绝缘逐渐分层。

Two mode of plastid inheritance, uniparental maternal and biparental inheritance, were discovered in angiosperms at the beginning of this contury, and our knowledge of the mode and cytological basis of cytoplasmic inheritance, esp. plastid, has been improved in many respects following the new cytological and molecular techniques, eg. electron microscopy, DNA fluorescence and RFLP.

近几年由于电镜、DNA的荧光检测及RFLP等新的细胞学和分子生物学技术的发展,使对植物细胞质遗传形式及其细胞学基础有了一定的了解,但多是单一的方法或对雌、雄配子发生、发育个别发育时期研究的结果,对大部分植物种的质体遗传方式或细胞学基础仍不清楚,在有些植物种间应用不同的研究方法得出的结论也不一致。

A two-component carbon tetrachloride system and a two-component aqueous system have been treated with the proposed strategy where only 21 calibration samples are needed, and the result showed that the predictive ability was not obviously impaired for the former system while being clearly strengthened for the latter one in comparison with a conventional way that required a calibration set of 100 samples.5 An unlooked-for experimental observation that in near-infrared spectroscopy the second overtone of aniline adsorbed by 13X molecular sieve nearly disappeared led us investigate a fundamental problem: the behavior of NIR when the outside space surrounding a molecule is too small to allow the molecule to vibrate freely.

同时,最小相关样本设计能进一步减少所需的校正样本数,且能提供更多合适变量以建立多元校正模型。这两方面的改进使模型的预测能力得以提高,其预测精度即使在水体系中也有明显的改善。五、近红外漫反射光谱在线非接触监测气-固吸附过程中出现了一个意外现象,即在近红外光谱上,被13X分子筛吸附的苯胺的二级倍频几乎完全消失了。这促使笔者深入探讨了近红外光谱的空间效应(当一分子被一足够小的刚性空间限制时,其振动的受限导致一级倍频和二级倍频强度均减少,并且后者减少的程度比前者更大)。

A novel method for the measurement of insulin-link growth factor I with capillary zone electrophoresis was developed. The molecular interaction between IGF-I and its polyclonal antibody was primarily studied with immunocapillary electrophoresis and the binding constant was determined. The work shows the possibility of applying CE to immuno-analysis, which could be a new clinical analytical method for diagnosis, treatment and monitoring for the endocritic and metabolic diseases.

以分子间相互作用理论为依托,以胰岛素样生长因子-Ⅰ及其抗体为研究体系,建立了用毛细管区带电泳测定IGF-I的方法,并首次用免疫毛细管电泳方法研究了IGF-I与它的多克隆抗体的相互作用,测定了它们的结合常数,进一步证实了在毛细管电泳中实施免疫分析的可能性,为内分泌及代谢性疾病等威胁人类健康的常见病的临床诊断及治疗观察提供了新的检测方法。

The main results and conclusions are as followings.1, The histone deacetylase inhibitors were used to feed the larve of the fly, and then the polytene chromosomes were observed under the microscope.

得到的主要结果和结论如下: 1,通过用去乙酰化酶抑制剂处理果蝇幼虫,观察果蝇多线染色体在热休克基因处的形态变化,发现去乙酰化酶抑制剂介导的乙酰化水平的升高可引起染色体结构的显著变化,推测乙酰化修饰不仅影响分子间的相互作用而且还可以影响染色体的高级结构。

Recombinatino polypeptide or chemically synthesized polypeptide antigen is used to immunize the mammal to obtain polyclonal antibody and the nonconservative amion acid sequence of the antiboby to N-terminal with recognition site qBrn-2 of development regulatory protein qBrn-2. The antibody does not recognize other POU structure domain protein, and recognizes specifically qunique protein in Western imprinting experiment. The qBrn-2 expression mode obtained immunohistochemistry process is identical with the resulted height of in-situ molecular hydridization.

以重组多肽或化学合成多肽为抗原免疫哺乳动物获得的多克隆抗体,这一抗体对发育调控蛋白qBrn-2的识别位点为qBrn-2的N-末端的非保守性的氨基酸序列,该抗体不识别其它POU结构域蛋白;在Western印记实验中,该抗体特异地识别单一的蛋白;利用免疫组织化学接示的qBrn-2表达模式与分子原位杂交的结果高度一致。

The CORNELL/COPERSUCAR/USPA project for the application of RELP technology in sugarcane encompasses three objectives: aEstablishing measures of genetic distance among and within species of the Saccharum complex and hybrids. bDevelopment of a genetic linkage map applicable to the saccharum genera.

CORNELL/COPERSUCAR/USPA 合作的多倍体的核酸内切酶内切限制断段变化技术应用于甘蔗,包括三个目的:a建立甘蔗属的合成物和杂种种内和种间的基因距离的测定。b发展应用于甘蔗属的基因链锁图。c努力建立分子标记和农学特性之间的链锁。

The instrument may be used in measuring sheat wave resonant absorption spectrum of liquid film in 1x10 to the power -5 -500 Hz frequency range and in providing measurement data for the research of the interaction range between clusters, long chains and multibands of liquid film, the group behavior of molecules and clusters, the long chain in polymer solution, the second, the third and the fourth group behavior in left liquid and other group behavior in chemical solution and complex.

本发明的谱仪可在10 -5 ―500Hz频率范围内,测量液体膜的切变波共振吸收谱,为研究溶液中的团簇间、长链间和多键间的交互作用范围,分子和团簇的集团行为,高分子溶液中的长链,生命液体中的二、三、四级或其他化学溶液和络合物中的基团的行为提供可靠的测量。

In order to provide more information for the further taxonomic studies on Sterculiaceae, three problems are carefully analyzed here, which are (1) the taxonomic position and systematic relations of the family,(2) the taxonomic position and relationships of some genera in this family, and (3) the application of some new taxonomic characteristics to the classification of the family.

本文从梧桐科的分类地位和系统关系﹑属的分类地位和亲缘关系以及分类学新特征在梧桐科分类中的应用三个方面入手,分析了梧桐科分类学研究的历史﹑现状和存在的问题,特别是把来自分子资料的研究结果与传统分类进行了比较分析,试图为梧桐科的分类学研究提供更多的帮助。

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Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

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Chapter Three: Type classification of DE structure in Sino-Tibetan languages.

第三章汉藏语&的&字结构的类型划分。