多分子的

One has noted that small conjugated molecules, single- and multiple-wall carbon nanotubes and macromolecules such as DNA possess many useful device characteristics, for instance, molecular switch, molecular memory, negative differential resistance and single-molecule transistors.

人们发现小的共轭分子、单层或多层碳纳米管、大的有机分子具有功能器件的特性，例如：分子开关、分子存储器、负微分电导、分子场效应管等特性，并且对此进行了论证报道。

Polyatomic molecules Compared with diatomic and triatomic molecules and large clusters, the interaction of polyatomic molecules with intense femtosecond laser field need to be paid more attention.

多原子分子相对于简单的小分子和团簇分子而言，多原子分子与强激光的相互作用还缺少深入的研究。

The saltier the water, the higher the pressure it takes (and hence the more energy you need) to push water through a membrane in order to leave behind the salt.

为了将水分子推向薄膜的另一端从而留下盐分子，水的盐分越多，要加载的压力就越多（因而所需要的能量就越多）。

Tricholoma may be a paraphyletic genus two. The collections identified as T. caligatum is a mixture. Some parts of them from France are members of T. matsutake, the other parts from North America are closed to T. bakamatsutake and T. fulvocastaneum. Tricholoma robustum and T. focale form a clade which is obviously a sister group of the stirp Subannulate. The stirp Caligata was defined as a group mainly on the basis of the predominant veil. But from the result of molecular systematic analysis, the presence of veil is not a stable character in the matsutake group. Species having symbiosis with conifers and broad leaf tree are all transformed from those whose host specificity is not strict. The phylogenetic tree based on ITS sequences resembled the tree of NJ algorithm based on cladistic coding. In the phylogenetic tree based on morphylogical characters, T. zangii and T. bakamatsutake form a clade, but it is the result of convergent evolution as suggested by molecular analyses. The distribution area of the matsutake group can be divided into six regions: middle and northern Europe region, Mediterranean region, Hengduan Mount.— Southeastern Tibet region, Northeastern China—Japan—Far-east Russia region, the Atlantic—North America region and the Rocky Mountain region. The abundance center of the matsutake group are Hengduan Mount.—Southeastern Tibet region and the Rocky Mountain region. Hengduan Mount.

松口蘑群的分子系统学研究得出的结果有：由于粗壮口蘑和羽衣口蘑明显和亚环族(Tricholoma，section subannulate)的种类是来自同一个谱系，和其它松口蘑群的种不具有最近共同祖先，因此松口蘑群是一个多系群；松口蘑群和口蘑属其他种类的亲缘关系比和蜜环菌属更接近；梭柄松苞菇和松口蘑群的差距明显小于油黄口蘑(T.flavovirens)和棕灰口蘑；口蘑属是一个多系群；鉴定为欧洲口蘑的标本明显不是一个单系群，其中一部分是松口蘑，另一部分和黄褐口蘑及傻松口蘑(T.bakamatsutake)比较接近；划分松口蘑群的标准是菌环的存在，但从分子系统学的结果来看，菌环的存在与否并非是一个很稳定的性状；和针叶树专性共生及和阔叶树专性共生均由寄主专化性不强的种类转化而来；在形态学系统发育树上青冈口蘑和傻松口蘑被聚为一个分枝，分子系统学的研究结果表明，这是趋同进化的结果；用支序方法编码作出的NJ树的结果更接近ITS序列的结果。

The tracheary elements in secondary xylems of Actaea asiatica root and rhizomes were observered with a scanning electron microscope and found to contain abundant types, which mainly included tracheids, tracheid-like vessels, fibriform vessels, and typical vessels. Of these types, the tracheids, tracheid-like vessels, fibriform vessels were first found. Scalariform perforation plates, reticulate perforation plates, mixed perforation plates and simple perforation plates were observed in the typical vessels and the reticulate perforation plates ,mixed perforation plates were first founded the lateral-wall perforation plates, multiple end walls and pit membrane vestige were also observed in the tracheary elements.

利用扫描电子显微镜对毛茛科类叶升麻根和根状茎次生木质部中的管状分子进行观察，发现其管状分子类型丰富，主要有：管胞、管胞状导管、纤维导管和典型的导管分子，其中管胞、管胞状导管和纤维导管为在该类群中首次报道；在导管分子中，存在着梯状穿孔板、网状穿孔板、混合型穿孔板和单穿孔板，其中网状穿孔板和混合型穿孔板为在该类群中的首次报道；对其导管分子上的侧壁穿孔板、多穿孔板和纹孔膜残余也进行了描述。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

POMs and deys are still maintained integrallty.AFM exhibits the films is even.The thickness of each layer is about 1.25nm. The AFM images reflect that there are some protuberances on the outer surface layer of the film, which due to the aggregates of spherical structure PMo12. Cyclic Voltammograms reflects the redox potentials of dye in multilayer shifts towards more positive values than pure dye multiplayer which may be explained by charge transfer from dye to POM. Fluorescence spectra show that polyoxometalates caused the fluorescence decay of dyes, which maybe used as fluorescence sensors.

UV-VIS说明复合膜均匀生长； IR 光谱、XPS能谱研究结果表明，紫外光照前后，膜中多酸/染料分子间没有发生显著的光化学反应，各组分的结构仍然保持；原子力显微镜显示，膜的外表面是均匀的，每一个双层厚度大约是1.25nm，膜表面的隆起，可能是多酸阴离子簇堆积所引起；循环伏安测定结果表明，由于多酸阴离子的影响，有机染料的氧化还电位发生了正的偏移，反映出复合膜中染料分子与多酸阴离子间发生了荷移相互作用，导致染料分子失去部分电子而使氧化性略强；荧光光谱研究结果表明，多酸阴离子可以有效地引发荧光染料的荧光淬灭，这为多酸在荧光传感器方面的应用提供了有价值的信息。

Through the analysis of De, an alternative mechanism interpreting of the"overshoot"phenomena can be obtained: when the diffusing time of small molecular penetrants is shorter than relaxation time of the involved polymer, small molecular substance penetrates into the polymer quickly and its concentration reached a maximum, then the swelling of the polymer by the small molecules makes the chain structure of the polymer relaxed, thus the free volume in polymer matrix, which is occupied by small molecule, decreased, and will squeeze part of the small molecular substance out of the polymer, and therefore overshoot behavior can be observed.

通过对De的分析，可以得出产生&超调&现象的机理的另一种解释：小分子渗透物质的扩散时间相对于聚合物的松弛时间要短（相当于有个更快的扩散速度），所以小分子迅速扩散进聚合物中达到一个极值，由于小分子物质对聚合物的溶胀，使得聚合物链结构产生松弛，由于聚合物链结构的变化，小分子物质占有的自由体积会减小，这样会挤出小分子物质，使得小分子物质在聚合物中的浓度减小，如果高聚物粘弹性明显，甚至可能出现多个浓度的衰减振荡并达到平衡值。

objective to evaluate the clinical effect of high myopia treated with lasik by a small optical zones flying spot scanner machine.methods 364 cases (721 eyes) of high myopia were treated with lasik by the schwind esiris laser machine with small optical flying spot scanner.the ablation zone was single zone or multi zone.the ablation depth was range of 78～187μm.all cases were followed up for 3～12 months.the changes of their visual acuities,subjective manifest refraction and complications were observed.results postoperatively,at one day and 3 month the visual acuities were 1.0 or better in 72.0%（519/721） and 81.7%（589/721）.the diopter within ±1.00 was 89.7%（647/721） and 90.7%（654/721）respectively.the complications include:decentral ablation 3 eyes (0.42%),decentral flap 5 eyes (0.69%),epithelial ingrowth 5 eyes(0.69%),glare 15 eyes(2.08%).conclusion the clinical effect of high myopia treated with lasik by a small optical zones flying-spot scanner machine was safety and efficacy,although it needs more corneal tissues.

目的 评价小光斑飞点扫描式准分子激光lasik治疗高度近视的效果。方法采用德国schwind esiris准分子激光机对364例（721眼）高度近视进行了lasik治疗。切削模式采用单区或多区切削，切削总量为78～187μm。随访3～12个月，观察术后视力、屈光度和并发症等情况。结果术后裸眼视力≥1.0者，术后1天、3个月时分别为72.0%（519/721）、81.7%（589/721）；术后屈光度在±1.00d以内者，术后1天、3个月时分别为：89.7%（647/721）、90.7%（654/721）。主要的并发症有：偏中心切削3眼(0.42%)、瓣位置偏离5眼(0.69%)、角膜上皮植入5眼(0.69%)、眩光15眼(2.08%)。结论小光斑飞点扫描式准分子激光lasik治疗高度近视的临床效果安全有效，但是需要切削较多的角膜组织。

Series of crosslinked polymers containing POSS were synthesized in this thesis. The main contents include three parts as follows:(1) The preparation of different POSS molecules containing multiple functionalgroups and the development of crosslinked polymers containing POSS were reviewed in detail.

2合成了一种多功能团的POSS分子(T_8H_8)及四种不同长度的双烯功能团有机小分子，这些有机小分子可以通过硅氢化反应与POSS形成交联聚合物，在聚合物中作为连接链将POSS分子连接起来。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。