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增感剂

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Macrokinetics of mesitylenic acid synthesis by oxidation of mesitylene

菁染料也常被称为光谱增感剂或增感染料。

The results indicated that the interaction mechanism of methionine reacted with different chemical sensitizers is not identical.

发现蛋氨酸与不同的化学增感剂的反应机理是不尽相同的。

By adding various dyes to the silver bromide , it can be made additionally sensitive to green light

溴化银加入各种化学增感剂后,可使其对绿色光尤其敏感。

By adding various dyes to the silver bromide it can be made additionally sensitive to green light.

溴化银加入各种化学增感剂后,又可使其感受染色光。

PbS nanoparticales as a sensitizer is added to the 0.8 μm cubic silver bromide emulsion for the chemical sensitization.

采用纳米硫化铅作为增感剂对边长为0.8μm的溴化银立方体颗粒进行了化学增感。

In this dissertation, sensitization and its mechanism by some well-known stabilizers, especially 5-methyl-7-hydroxyl-tetraazaindene in silver chloride emulsion have been systematically studied It is found that sensitization by stabilizer is obvious in whatever unsensitized or sulfur-sensitized silver chloride emulsion, as well as fog-inhibition.

本论文研究了一些常用的有机稳定剂特别是四氮杂茚在氯化银乳剂中的增感作用及系统地研究其增感作用机理。

Moreover, supersensitization as well as its mechanism by stabilizers is studied in spectral-sensitized AgCl emulsion Results indicate that the adding order of stabilizer and sensitizing dye has great influence on the sensitivity of emulsion and only stabilizer added after sensitizing dye can supersensitization be obtained Apart from supersensitization and fog-inhibition by stabilizers, it is also significant to spread the amount of addition of dye, which can lead the further improvement of sensitivity of emulsion.

本文还研究了稳定剂在氯化银乳剂中的超增感作用并应用多种手段研究了其超增感作用机理。结果说明,稳定剂与增感染料的添加次序对乳剂感光度有非常重要的影响,只有在增感染料之后加才可能产生增感作用。在一定的稳定剂添加范围内,它不仅可以提高氯化银乳剂的感光度、降低灰雾,而且还能加大增感染料的用量,进一步提高乳剂的感光度。这对乳剂的光谱增感来说具有重要意义。

On the bases of absorption spectra measurements, it is shown that stabilizer is beneficial to the stability of J-aggregate of sensitizing dye Results of reflection spectra and spectral-exposure experiments demonstrate that spectra absorbance are greatly affected by the adding order of stabilizer and sensitizing dye and only stabilizer added after dye can advantage for J-aggregate of sensitizing dye neatly forming on the surface of silver chloride grain and its absorbance be available ESR experiments show that the addition of stabilizers can decrease the number of dye positive hole and accelerate the decay of it Then desensitization aroused by the recombination of dye positive hole with photoelectron and/or latent image center, was reduced at the presence of the stabilizers

通过溶液光谱实验说明稳定剂有利于染料J聚集体的稳定性;反射光谱实验和光谱曝光实验证明稳定剂与染料的添加次序对乳剂的光吸收有很大的影响,只有稳定剂在染料之后加才有利于染料在AgCl颗粒上排列整齐形成J聚集态及其光吸收;ESR实验结果说明稳定剂的加入可以降低染料正空穴的浓度及其衰减速率,使乳剂中染料正空穴减少,从而抑制了染料正空穴引起的减感作用。因此可以认为稳定剂的超增感作用:一是有利于染料形成J聚集态及乳剂的光吸收;二是降低染料正空穴的浓度,从而抑制染料的减感。同时还提出了染料与稳定剂的增感吸附模型。

Fluorescence emission spectra and UV absorb spectra analysis have been undertaken to test the influence of solvent polarity on the lowest excited singlet state of the tertiary amines. The absorption maxima were red-shafted slightly, and the emission maxima were red-shafted strongly, which showed all of the three compounds were found to be essentiallyππ* in character, which makes for the formation of triplet-exciplex state and the subsequent reactions,?known as photo-reduction and hydrogen-abstraction.

本文借助光谱检测的手段测试了新合成的增感剂的光物理化学性能,利用荧光发射光谱和紫外吸收光谱测试了溶剂极性对叔胺的最低激发单重态的影响,实验结果表明叔胺的紫外最大吸收波长随溶剂极性的增强产生轻微的红移,荧光最大发射波长随溶剂极性的增强产生明显的红移,表明三种叔胺的最低激发单重态具有ππ*跃迁的特性,这对于激态复合物的生成以及其后的光致还原反应和提氢反应的发生都非常有利。

Silver carboxylates,silver halide, toner s,antifoggants,stabilizers,sensitizers,binders and other ingredients of PTG materials are introduced,and the imaging theories for PTG materials are reviewed.

重点介绍了羧酸银、卤化银、调色剂、防灰雾剂与稳定剂、光谱增感剂以及粘合剂等PTG材料的主要组分,并对PTG材料成像机理的研究情况进行了评述

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