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More levels of nano-SiO〓 lead to larger particle size. An increase in polymerization reaction temperature causes the decrease in coagulum and increase in viscosity and particle size, and the nano-SiO〓 has same effects at certain temperature. When the levels of hydrophilic monomer acrylic acid and hydroxylethyl methacrylate in core composite are increased, the particle size of emulsifier-free emulsion decreases, in spite of the presence of nano-SiO〓.

无皂乳液具有单分散性好、表面洁净、成本低廉、不影响产品性能的特点,首次研究了含或不含纳米粒子的含羟基和羧基的丙烯酸无皂乳液聚合,发现含或不含纳米粒子的无皂乳液聚合后的粒子粒径较大,具有单分散性;较多的纳米粒子导致较大的乳液粒径;反应温度升高,凝聚物含量下降,而乳液粘度和乳胶粒粒径增加,在相同的反应温度下,纳米粒子降低了聚合过程中的凝聚物含量,增加了乳液聚合物的粘度和粒径;不论纳米粒子是否存在,当无皂乳液核组成中亲水单体AA和HEMA用量增加时,乳胶粒粒径均减少。

When the sodium lauryl sulfate and p-octyl polyethylene glycol phenyl ether is used and its level in 3% and 6: 4 ratio, the polymerization process has the lowest coagulum and the highest monomer conversion. Higher reaction temperature and more level hydroxyl value lead to more coagulum, the latter also lead to larger particle size. The acid value has larger influence on viscosity and coagulum, there exist a best range. The emulsion particle size is larger for its hydrophilicity, most of its particles are connected together.

在含较高亲水单体的乳液聚合体系中,难以制得稳定的预乳化液,不能采用工业生产中常用的预乳化工艺,而只能采用混合单体直接滴加的方法;由于单体混合物的亲水亲油值较高,用阴离子型乳化剂十二烷基硫酸钠和非离子型乳化剂聚乙二醇辛基苯基醚混合,用量为单体总量的3%,且比例在6:4时,乳液聚合时具有最低的凝聚物含量和最高的单体转化率;乳液聚合反应温度升高,可以提高单体转化率,增加反应速度,但凝聚率相应提高;随着羟基单体含量的增加,聚合过程中凝聚率增加,聚合物乳胶粒平均直径增加;羧基单体有一个最佳的用量(2.6%),过高或过低凝聚率均提高;羧基含量对乳液的粘度有较大的影响,当羧基含量较低时,羧基含量增加,乳液粘度增加明显;含羟基乳液粒子由于含亲水基团较多,使得乳胶粒径增大,乳胶粒子大多数互相凝聚在一起,处于凝聚态。

The fabrication of fibers was attempted. The copolymers, the copolymers containing MOCT and the copolymer films containing MOCT were characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Differential Scanning Calorimetry, Thermogravimetric Analyzer and X-ray Diffraction etc. The conclusions were summarized as following,1. The AN/MMA copolymers were testified that copolymerization of most AN and MMA occurred and the ratio of AN and MMA in copolymer was less than the ratio of monomers. With the increase of the contents of MMA, the viscosity of copolymer solution, molecular weight and decomposition temperature of copolymers increase.

通过傅立叶变换红外光谱、扫描电子显微镜、差示扫描量热分析、热重分析、X-射线衍射分析等测试方法对得到的AN/MMA共聚物、含有正十八烷微胶囊的共聚物以及共聚物膜等进行了测试和分析,得到如下的研究结论: 1、丙烯腈—甲基丙烯酸甲酯之间发生了聚合反应,共聚物的组成比略小于投料比;共聚物的粘度和分子量随着第二单体MMA加入量的增加有增大的趋势;第二单体加入量的增大使得共聚物的分解温度升高,通过热重分析证实当AN/MMA摩尔比为85/15时,共聚物的耐热稳定性较高。

The mass loss patterns of four type litters fitted exponential model, and the decomposition rate could be well predicted by their lignin/N ratio.

结果表明:与对照相比,降水量减少条件下,蒙古栎叶凋落物的初始N、P、K浓度显著升高,初始木质素浓度显著降低,凋落物分解速率大,N、P、K矿化率高,N和P固持时间缩短;降水量增加情况下,其凋落物初始N浓度显著降低、木质素浓度显著升高,N、P、K矿化率低,N和P固持时间延长。4种类型叶片凋落物的质量损失过程均符合指数降解模型,分解速率可以由凋落物木质素/N来预测。

In addition, the pCO2 in the hypolimnion near the sediment is the highest and has an increasing tendency, which indicates that the degradation of organic matter in the sediments has an important effect on the pCO2 in the hypolimnion.

静水层沉积物附近pCO2最高并且还有持续增加的趋势,说明沉积物中有机质降解是静水层中CO2增加的主要原因,夏季湖底水温较高加快了沉积物中有机质的降解。

The different climbing plants have different branching behaviour. Humulus scandens increases the chance of encountering the external support through increasing the number of branches on unit stem length, but Ampelopsis delavayana and Parthenocissus tricuspidata increase the chance of encountering the external support through increasing branch length.

不同攀援方式植株以及植物的不同生长形式均表现出了有差异的分枝行为,葎草通过增加单位茎长度的上分枝数以达到增加遇到外界支持物的机会,而三裂叶蛇葡萄和爬山虎则通过增加分枝长度的方法来增加遇到外界支持物的机会。

The effect of hydrophobe content on the intrinsic viscosity and Huggins constant kH of the water - soluble hydropho-bically associating terpolymers were discussed in this paper. Further...

结果表明,随疏水基团含量增加,特性粘数减小、Huggins常数增大;共聚物亚浓溶液的表观粘度随疏水基团含量的增加而增加,随温度、剪切速率的增加而降低,共聚物在NaCl、CaCl2盐水溶液中出现盐增粘现象。

The aim of this study was to develop a novel amphiphilic functional block poly(ε-caprolactone) bearing ketone groups MPEG-b-P(OPD-co-CL. 2-oxepane-1, 5-dione was copolymerized with ε-caprolatone in which methoxy poly (MPEG, Mn=5 000) and stannous octoate were used as initiator and catalyst, respectively. The syntheses were conducted by bulk and solution polymerization. 1H NMR results showed that peak position and splitting of the polymers synthesized through solution polymerization were consistent with theoretical data, demonstrating the products were designed block copolymers. While in the bulk polymerization, polymer peak position was changed due to their high reaction temperature, suggesting their structural variation.

将带有羰基官能团的4-羰基己内酯和ε-己内酯分别在甲氧基聚乙二醇(MPEG,Mn=5 000)为引发剂,异辛酸亚锡为催化剂溶液和本体体系中开环聚合,合成了两亲性侧基带有羰基官能团的聚己内酯嵌段共聚物MPEG-b-P(OPD-co-CL.1H NMR结果表明采用溶液聚合法合成的聚合物各峰的峰位置和分裂情况与理论一致,证明了产物是实验所设计的嵌段共聚物,而采用本体聚合法合成的聚合物由于温度的影响,聚合物各峰的峰位置发生了变化,说明其结构发生了变化;差示扫描量热法分析结果表明随着OPD单体含量的增加,聚合物的熔点,玻璃化转变温度和熔融焓增加;热失重测试结果表明OPD单体的引入增加了聚合物的热敏感性。

Results: With zinc polycarboxylic cement molecular weights and sintering temperature of powder in creasing.

结果:水门汀压缩强度和对牙釉质的剪切粘接强度随共聚物分子量增加而增加,但当共聚物分子量增加到5.2×10^4了以后,水门汀就不能使用。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下(pH=1.0~14.0)的乙二醇/水(V/V=1:1)溶液低温ESR谱,发现不同pH下,溶液中具有不同组成的配合物,根据不同pH下ESR谱的变化,利用Johnson的加合规则并结合红外光谱,推测了它们在溶液中的可能结构;利用波谱参数计算了配合物键参数;利用电子光谱数据计算了配合物的晶体场参数,讨沦了它们的成配特性,结果表明:VO配合物属离子型配合物,随取代水分子的配体(Ser、Phen或Bipy)数目增加,键参数减小,配合物共价性增强,同时得出这些体系中,生物配体竞争配位规律:Phen和Bipy与VO的配位能力比Ser强。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。