基尔

The factors affect on the degree of substitution of product, yield and apparent viscosity, such as the mol rates of EPTAC with -NH2, reaction temperature, reaction time and the content of water in system have been discussed in detail. FTIR spectrometer and UV spectrometer are used to characterize the structure of the derivative and it is proved that substitution reaction mainly occurs on the -N element .The particle size and morphology of chitosan and quantemary ammonium salt of chitosan are analysised by comparing photos of their scanning electron microscope. The degree of substitution of HACC is determined by acid -base conductometric titration. An error in current formula of DS has pointed out and a correct formula has presented.On the base of experience of above experiment, the reaction conditions of HACC were systematically investigated through orthogonal design, and then the best conditions are found. Water-solubility and dependence of pH are studied.

壳聚糖和环氧丙基三甲基氯化铵在异相条件下发生反应，通过单因素实验，制备了一系列不同性能的壳聚糖季铵盐，本文首次详细讨论了反应条件(反应摩尔比、反应时间、反应温度、水含量)对产率及产物性能的影响；用红外光谱和核磁共振对结构进行表征分析时，发现季铵盐阳离子基以N位上取代为主；通过电镜图片对壳聚糖和季铵盐衍生物外观形貌进行对比，采用酸碱电导滴定法测定产物的取代度，并对常用取代度公式做了修正。

Synthesis of Antidote of N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane BI Hong-mei, ZHANG Jin-yan, LIANG Ying, SHEN Yong (College of Arts and Sciences Heilongjiang August First Reclamation University, Daqing 163319, Heilongjiang, China) Abstract: N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was synthesized by one pot method with isopropanolamine, cyclopentanone and dichloroacetyl chloride. The optimum reaction conditions obtained are as follows:the proportion in moles of the above materials is 1∶1∶1.2, reaction solvent is toluene, reaction temperature is -15 to -10 ℃,reaction time is 3 h, under the optimum condition, the yield of the compound is 50.0%.

除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷的合成毕洪梅，张金艳，梁英，沈勇(黑龙江八一农垦大学文理学院，黑龙江大庆 163319)摘要：以33%的氢氧化钠水溶液为缚酸剂，异丙醇胺、环戊酮和二氯乙酰氯为原料，采用&一锅法&合成了N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷，采用正交实验法得到最佳反应条件：反应原料摩尔比为1∶1∶1.2，苯作溶剂，反应的温度为-15 ℃~-10 ℃，搅拌时间为3 h，产率达到50.0%。

Trifluoromethyl-3-heptadfluoroisopropyl-2-perfluoropentene-4-(N',N'-dimethylamino propyl) imino was prepared by the reaction of hexafluoropropene timer with N,N-dimethyl propanediamine in the molar ratio 1:1.0 at room temperature for 8h, and the structures of VIII were identified by IR and NMR spectra.

以六氟丙烯三聚体与N，N-二甲基丙二胺为原料合成叔胺2-三氟甲基-3-七氟异丙基-2-全氟戊烯-4-(N'，N'-二甲胺丙基)亚胺，利用红外光谱和核磁共振确定其结构，并通过对合成条件的考察得其最佳合成条件：乙醚为溶剂，碳酸钠为缚酸剂，摩尔投料比为1：1.0，在室温下反应8小时。

Gortat was hoping to play alongside Jason Kidd and Dirk Nowitzki and, most of all, compete with Erick Dampier for the starting job.

哥塔特希望能在贾森-基德和德克-诺维斯基身边打球，更重要的是他有机会跟丹皮尔竞争首发位置。

The analysis shows that, the larger the mol value of ethylic sequence in high molecule chains, the higher the low-temperature viscosity, the worse the low-temperature starting performance and pumpability.

通过分析得出：随着高分子链中丙基序列所占摩尔分数的增大，低温粘度变大，低温启动和泵送性能变差；而随着乙烯基含量的增加，低温粘度下降，低温性能变好。

In 1955, Keeling devised an instrument that could measure concentrations of carbon dioxide in all kinds of environments, from sooty city rooftops to pristine wilderness forests.

作出这个曲线图的是一位坚持不懈、孤身作战的科学家：查尔斯基林（2）。1955年，基林设计了一台可以用来测量在任何环境中的二氧化碳含量的机器，不管是黑烟笼罩的城市屋顶，还是亙古蛮荒的森林。

In 1955, Keeling devised an instrument that could measure concentrations of carbon dioxide in all kinds of environments, from sooty city rooftops to pristine wilderness forests.

作出这个曲线图的是一位坚持不懈、孤身作战的科学家——查尔斯基林（2）。1955年，基林设计了一台可以用来测量任何环境中的二氧化碳含量的机器，不管是煤烟熏黑的城市屋顶，还是原始蛮荒的森林。

I'd imagine Kenyon Martin, Kittles, Van Horn and a slew of other NBA players would say the same for Jason Kidd.

我可以想像肯扬-马丁、基特尔斯、范霍恩和其他许多 NBA 球员都会在谈到贾森-基德时表现出同样的赞赏。

Focusing on the PGE enrichment mechanism in the basic-ultrabasic intrusions in the Panxi rift, firstly, through the interpretation of TM photograph, data processing of regional geochemical exploration and geophysical prospecting results of gravity, magnetic force and seism, we analyzed the controlling effect of structure and magmatic movement on the PGE mineralization; Secondly, through the study of volcanic apparatus, petrography, measurement of comprehensive geochemical section, isotope tracing and dating of typical PGE-rich melanocratic rock series, we discussed the sources of the PGE-bearing mafic-ultramafic intrusions and basalts, their timing, evolvement sequences, the geochemical processes of magma crystallization and fractionation, and the relationship between magma evolution and structural development; Finally, through the analysis of PGE and chalcophile elements concentrations in the melanocratic rock series and the contrastive study with the Noril''sk magmatic Ni-Cu-PGE sulfide deposit, its related continental flood basalts and Siberia Traps, we discussed PGE mineralization characteristics and its enrichment mechanisms in the melanocratic rock series in the Panxi rift.

本项目首先围绕川西地区主要的PGE矿床及伴生矿的地质环境和有关的地质构造背景，通过TM卫片解译、区域化探和重、磁及地震物探资料分析，总体把握构造及岩浆活动对PGE成矿的控制作用；然后通过对典型富PGE暗色岩套的火山机构地质构造、岩石岩相学、地球化学、同位素定年和示踪等方面的工作，分析本区基性－超基性含矿岩体与喷出岩之间的成岩物质来源、侵入时代及演化序列，研究该区同一岩浆房分异结晶的地球化学过程及其随构造发展的耦合关系；最后通过对暗色岩套PGE地球化学剖面分析以及与俄罗斯诺里尔斯克陆内裂谷溢流型玄武岩中PGE矿化的岩石－构造环境对比研究，探讨该区暗色岩套中的矿化特点和富集部位及其PGE富集机制。

The yields were 67～89% and 61～90% respectively, and the ees were 66～99. 9% and 68～99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中，将配体8和10分别用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.015/1时，化学产率分别为67～91％和61～90％，ee值分别为66～99.9％和68～99.9％（反式-5-癸烯和萘基烯丙基醚除外）。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐