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By the present of DMF, attractions arising from hydroxyl groups increased, and it is more favored to forming hydrogen bonds between amino acids; repusings arising from apolar alkyl groups side-chaines have little change ,but they increase with increasing alkyl groups, llydroxyl groups assist in the formation of hydrogen bonds in interior protein molecules, alkyl groups assist in the highly extension of peptide chaines, these make protein structure stabilized.

而L-缬氨酸非极性侧基的排斥作用在15%乙醇中最大,随乙醇含量的进一步增加,排斥作用的影响逐渐减小,吸引作用的影响逐渐占据主导,且越来越大。

With increasing DMFcontent in mixed solvents, the dipolar attracting interactions betweenglycine molecules increase; the attracting interactions arising fromhydroxyl groups between L-serine molecules increase rapidly; the repulsing interactions involving apolar side-chains between L-valine moleculeshave little fluctuate. By the present of ethanol, attractions arising fromhydroxyl groups increase obviously, repulsions arising from apolarside-chains decrease.

随溶液中DMF含量的增大,甘氨酸和L-丝氨酸两分子间的偶极吸引作用逐渐增大。L-丝氨酸羟基的吸引作用影响更加明显,因此增加速度较快。L-缬氨酸非极性侧基的排斥作用变化略有波动。

Leaves sessile; blade broadly oblong or oblong-ovate to narrowly oblong or oblong-lanceolate, 2-6.5(-8)× 1-3.2 cm, thickly papery, abaxially rather paler but not glaucous; laminar glands dense, unequal dots or short streaks; intramarginal glands dense; main lateral veins 4-6-paired, with densely reticulate tertiary venation not or scarcely prominent abaxially; base cordate-amplexicaul, apex rounded to shallowly retuse.

叶无柄 叶片宽长圆形或长圆状卵形到狭长圆形或长圆状披针形, 2-6.5(-8)* 1-3.2 厘米,厚纸质,背面相当浅但不是苍白;片状腺体浓,不相等的小圆点或者短的条纹;近边缘内腺体浓; 4-6配对的主要侧脉,突出的具密网状第三脉不或几乎不;抱茎基部心形,先端圆形对浅微凹。

Leaves with petiole 0.5-2 mm; blade narrowly triangular-lanceolate, 2.5-5.8 × 0.7-2.3 cm, thickly papery, abaxially ± densely glaucous; laminar glands long to short streaks; abaxial glands rather sparse; main lateral veins 2- or 3-paired, all branches clearly visible and forming undulating intramarginal vein, tertiary reticulation nearly invisible; base cuneate, apex acute to subacute.

叶具叶柄0.5-2毫米;叶片狭三角形披针形, 2.5-5.8 * 0.7-2.3 厘米,厚纸质,背面多少密被白霜;片状的腺长到短条纹;背面的腺体相当稀;主要侧脉2-或3对,全部的分枝明显可见的并且形成波状近边缘内脉,近看不见的第三级网脉;基部楔形,先端锐尖到近尖。

Leaves 5, not fully expanded at anthesis; petiole 5.5--15 cm, with thick long pilose hairs; leaf blade nearly kidney-shaped, rounded-ovate, or 5-angled, 2.5--7 × 4.5--11 cm,± equally 3-foliolate, abaxially with white hairs, adaxially glabrous, base broadly cordate; lateral leaflets subsessile, unevenly 2-lobed; central leaflet subsessile or with a 1--4 mm petiolule, deeply 3-lobed, lobes entire or dissected, ultimate lobes triangular to narrowly linear and 2--3.5 mm wide.

叶5,不完全膨大的在花期;叶柄5.5-15厘米,具厚具长柔毛毛;叶片差不多肾形,圆形卵形,或具5个角, 2.5-7 * 4.5-11厘米,多少具3小叶,背面具白色的毛,正面无毛,基部宽心形;侧生小叶近无柄,不均匀2裂;中心的小叶近无柄或具一1-4毫米小叶柄,3深裂,裂片全缘的或多裂,末级的裂片三角形到狭线形和2-3.5毫米宽。

In chapter 4, by analyzing the interchange of seepage water between overburden layer of weak permeability and sandy gravel bed, a short computer program for adopting weighting soil layer on the landside of dike is put forward, the optimal design schemes about combination weighting soil layer with inverted drainage works are studied.

第四章 通过分析堤基弱透水覆盖层与下卧砂砾层之间的渗流关系,创建了堤防背水侧盖重压渗的快捷计算模型并研制了相应的计算软件,提出了盖重压渗与反滤导渗相结合的优化设计方案。

A similar initiator, Et_2Zn/-Sparteine, yielded polys with threo-diisotactic -rich structure in the main chain, indicative of strongly asymmetric inducation in this system. In this case, no polymeric complexes in-site formed because of the intensive coordination between sparteine and Zn ions.The binary initiating system composed of Et_2Zn and n-BuLi combined the advantages of both metal alkyls, which gave the polymers with higher molecular weights and moderate optical activity ~(25_D =-97.1°~+24.3°.

Et_2Zn/n-BuLi二元引发体系综合了两种金属烷基化物的优点,得到了分子量相对较高(M_n=1.4x10~3~4.9×10~3)且含有手性超分子结构的光学活性聚合物;聚合物中锌含量的微小变化可引起聚合物光学活性明显改变,超分子手性与聚合物侧基的绝对构型存在关联。

Ovary: ovules numerous, on 3 parietal placentas; style simple, geniculate at base, conspicuously clavate, with an anterior opening stigmatic cavity.

子房 胚珠多数,在3侧膜胎座上;花柱单,膝曲的在基部,显著棍棒状,具一个前面的开阔的的柱头的洞。

Petiole 5-7 mm, pubescent; leaf blade dark or purple-green, glossy adaxially, light green abaxially, orbicular or elliptic to oblong, sometimes obovate, 5-9 × 2.8-6 cm, leathery, both surfaces glabrous, but sometimes puberulous along margin, base broadly cuneate, apex acuminate or acute, apiculate; lateral veins 15-20 pairs, more conspicuous abaxially, veins and veinlets slender, subparallel, obscure.

叶柄5-7毫米,具短柔毛;叶片深色的或紫色绿色,正面有光泽,淡绿背面,圆形的或椭圆形到长圆形,有时倒卵形, 5-9 * 2.8-6 厘米,革质,两面无毛,但是有时被微柔毛的沿边缘,基部宽楔形,先端渐尖或锐尖的,具细尖;侧脉15-20 对,更多的背面明显,脉和细脉纤细,近平行,不明显。

The analysis of 1H NMR showed that the succinyl group was successfully conjugated to the amino group of chitosan molecule, and the degree of substitution of Suc-Chi values increased with increasing succinic anhydride/amino mole ratio or reducing the molecular weight of chitosan.

利用壳聚糖和琥珀酰酐反应合成了N-琥珀酰壳聚糖,1H NMR分析表明通过反应可在壳聚糖的侧氨基引入亲水性的羧基,增加琥珀酰酐/氨基的摩尔投料比或者选择分子质量较小的壳聚糖,有利于提高N-琥珀酰壳聚糖的琥珀酰化度。

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