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Keywords: solid phase organic synthesis; stereoselective reaction; heterogeneous photosensitization

中文关键词:固相有机合成;立体选择性反应;非均相光敏异构化

The activity and stability of the catalyst showed better than those of cobalt phthalocyanine sulfonate.

催化剂的活性组分在使用过程中不流失,其活性和稳定性均优于磺化酞菁钴催化剂。

Results Compared high kV X-ray chest film with spiral CT,to simplex silicosis,X-ray films coincided with CT scans;to mixed silicosis,the effect of CT scans were better than X-ray's;to large nodule,coalesced progressive massive fibrosis,the detected ratio of CT scans were higher than X-ray chest films;to silicosis complication,for example,emphysema,pleural thickening,phthisic,mediastinal impairment lympy node etc,CT scans were more reliable than X-ray films,especially HRCT can earlier find silicotic nodule and fine structure of focus.Selective application of CT scan,had great diagnostic value in complicated silicosis and silco-tuberculosis and lung cancer complicated with silicosis etc.

结果 高千伏X线胸片与螺旋CT作对比,结果对单纯矽肺并发肺癌,CT片与X线胸片基本一致;对于复杂矽肺并发肺癌CT优于X线胸片;对于大结节、肺内进行性大块纤维化(progressive massive fibrosis,PMF)融合、空洞及钙化CT检出率明显高出胸片;对矽肺并发肺癌的合并其他如肺气肿、胸膜肥厚、结核、纵隔淋巴受累等CT均较胸片可靠;特别是HRCT能早期发现矽肺肿块样病灶中细微结构,选择性应用CT,对复杂矽肺并发肺癌合并结核等鉴别诊断有很大价值。

Fault rocks, microstructures and homogeneous temperature (concentrated around 160℃) of fluid inclusions in the quartz veins shows that the fault belt mainly underwent shallow brittle deformation and the highest-grade dynamic metamorphic rock is mylonitized sericite phyllite.

显微构造、断层岩与石英脉流体包裹体均一温度(集中在160℃附近)均显示,断裂带以浅层脆性变形为主,最深动力变质岩仅为糜棱岩化绢云母千枚岩。

Protease treatment of the plasma membranes could abolish the binding but NaIO_4 and glycosidase could not, indicating that nsLTP144 bound to plasma membranes protein without carbohydrate moiety. Using the homobifunctional cross-linking regent bissuberate (BS~3) and rice plasma membranes incubated with ~(125)I-Trx-nsLTP144, we identified, after SDS-polyacrylamide gel electrophoresis and autoradiography, a putative protein receptor on the rice plasma membranes with the molecular mass around 60 kDa. NsLTP144 can not trigger extracelluar alkalization in arabidopsis, but can abolish the extracellular alkalization effect of phytopathogen elicitor cryptogein, suggesting that cryptogein and nsLTP144 may bind to the same membrane protein. In vitro pull-down assay showed that nsLTP144 interacted with OsCaM1, a possible extracellular calmodulin, implying that nsLTP144 and OsCaM1 could function in the same signal transduction pathway. These results shed light on revealing the roles of nsLTP in vivo and make it promising to finally characterize the plasma membranes receptor of nsLTP.

发现~(125)I-Trx-nsLTP144、~(125)I-Trx-nsLTP110与水稻细胞质膜均具有特异性结合,而且结合是饱和性的、可被竞争的,符合配体-受体结合的典型特征,同时用于对照实验的蛋白质~(125)I-Thioredoxin没有此特性,表明水稻细胞质膜上存在nsLTP的受体;利用可氧化糖基的NaIO_4和水解糖基的N\'-糖苷酶F处理水稻细胞质膜,再进行结合实验,结合活性几乎不受影响;而利用胰蛋白酶处理细胞膜则使得结合能力几乎完全丧失,表明其受体为没有经过糖基化修饰的蛋白质;利用交联剂BS~3交联配体一受体后,再进行SDS-PAGE分离和放射自显影,结果显示水稻细胞质膜上的nsLTP受体中有一个60kDa的蛋白质可以与nsLTP144发生特异性的结合,可能是其受体;细胞外碱化实验表明,nsLTP144不能促使拟南芥原生质体细胞培养液的细胞外碱化反应,却能猝灭来自植物病原菌的激发子Cryptogein刺激拟南芥原生质体产生的细胞外碱化反应,表明nsLTP和Cryptogein结合细胞膜上相同的位点,保护了植物细胞免受Cryptogein导致的细胞程序性死亡,并诱导系统获得性抗性的产生;体外Pull-down实验表明,nsLTP144和水稻的OsCaM1具有相互作用,暗示了nsLTP144和OsCaM1可能同在一个信号通路上起作用。

In order to study the method and its capability of the borax ceramsite concrete as the layer of accumulation of heat of floor radiant heating,the borax ceramsite concrete was used to substitute for pisolite concrete as the layer of accumulation of heat in the floor radiant heating system during the construction of Lakeside Garden Buildings in Liaohua District.

目的研究硼泥陶粒混凝土作为低温热水地板辐射供暖系统蓄热层的作法及其性能。方法辽化湖畔花园小区住宅楼工程中,用硼泥陶粒混凝土代替豆石混凝土作低温热水地板辐射供暖系统蓄热层,取暖期内对试验工程进行温度监测实验。结果试验工程混凝土试块强度平均值为27.5 MPa,合格率为100%,厚度均在允许偏差内,合格率100%;外观鉴定混凝土表面无裂缝,并根据温度监测结果画出了取暖期内每天温度随时间变化的曲线图。结论用硼泥陶粒混凝土作低温热水地板辐射供暖系统的蓄热层,与用豆石混凝土相比,减轻了建筑物自重、减缓了传热速度、增强了房间的热稳定性

In this paper, theory of homogenization was introduced into the calculation of plasterboard filled with concrete and Representative Volume Element model of plasterboard filled with concrete was established.

本文将均质化理论引入灌芯混凝土石膏板的计算,建立了灌芯混凝土石膏板的代表性体积单元模型,应用有限元分析程序ANSYS对此RVE模型进行模拟,获得其等效弹性常数,为结构的有限元计算提供了有效途经。

The results of GPC show that there are two different reaction mechanisms,linear condensation and cyclic reaction in the synthesis process,and the molecular weightreaches 1.17×105 and P d is 1.33.The DSC curves show that supercritical carbon dioxide can plasticize PC so that the T g of PC decreased.

凝胶渗透色谱测试表明,合成过程中存在线形缩聚和成环两种不同的反应机理,产物的重均分子量高达117740,分子量分布指数 P d=1.33;差示扫描量热法测试表明,超临界CO2能增塑PC致使其玻璃化转变温度降低。

In addition, the effect of toluene solvent was assessed by the polarizable continuum model.

结果表明,气相和溶液中途径2均是较优途径,并且甲苯对该反应的溶剂化效应不明显。

In the normal rats (n=5、6), CGRP-LI were mainly present in small and some medium-sized neurons and the primary afferent fibers and ter- minals in laminae Ⅰ,Ⅱ,Ⅴ,Ⅹ and Lissauer's tract of the spinal cord; GAL- and SP-LI were mainly present in small neurons and the superficial layers of the dorsal horn. After the adjuvant injection both CGRP-and SP-LI were in- creased corresponding to the development of arthritis. On day 2, CGRP-and SP-LI were moderately increased in laminae Ⅰ,Ⅱ and the posterior commis- sure of the spinal cord and small neurons in DRG, while SP was obviously in- creased in the superficial layers and DRG. On day 14, CGRP-LI were marked- ly enhanced in the above regions with the development of polyarthritis. Some- times many strongly stained long fibers could be seen in the posteriot commis- sure.

在DRG中,CGRP主要分布于小和中等神经元之中,SP和GAL主要分布于小神经元之中;2、注入弗氏完全佐剂(含冻干结核菌0.5mg)后第2天动物(各5~6例)产生具有明显红、肿、热、痛和痛敏的急性关节炎,免疫组化实验观察到注射侧脊髓背角和DRG中CGRP-和SP-LI明显增加;在佐剂后第14天,动物患肢肿胀、痛敏和自发痛均进一步加重,部分动物健肢也出现红肿,产生多发性关节炎时,脊髓背角浅层和DRG中CGRP-和SP-LI增加更为明显,并且在灰质后联合中可见许多深染的CGRP-LI长纤维;在佐剂后第21和28天,随着佐剂性关节炎的逐渐恢复,脊髓背角和DRG中CGRP-和SP-LI也接近正常。

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延期开工的Kolmogorov宣布要衡量所有套职能有限许多坐标限制在于衡量子寅。换句话说,如果是/否的问题回答f可看的价值观念在许多最有限坐标,然后它有一个概率的答案。

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