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The good catalytic performances were obtained on those catalysts supported by SiO_2. With the increasing calcination temperature from 300℃to 700℃, Co_3O_4 particles augmented and sintered on the samples surface which contained 10 wt.% cobalt, the crystallite size of Co_3O_4 was aggrandized from 7.2 nm to 20.3 nm by inchmeal. On the other hand, the activation energy for the combustion reaction was increased linearly with the augment of average crystallite size of Co_3O_4, the TOF value on prepared catalyst was decreased with it. Thus, the catalytic combustion was a typical structure-sensitive reaction.

在钴含量为10 wt%的样品上,随着焙烧温度由300℃提高到700℃,钴物种出现迁移团聚甚至烧结,在XRD中测定的Co_3O_4晶粒尺寸由7.2 nm逐步增加至20.3 nm;另一方面,催化剂的燃烧活化能随样品上Co_3O_4晶粒的平均尺寸增加而呈现线形增加趋势,而单位时间内单位活性物种上的甲烷转换频数随着粒径增加而逐渐降低,这一现象证实了该反应属于典型的结构敏感反应。

Along with seawater stress strength upward, the ratio of root to shoot, Na+, Cl- and soluble sugar contents were increased significantly. Under the 10% and 20% seawater treatments, chlorophyll contents have no obvious difference compared with the control, but significantly decreased when the seawater stress further increased. Under the 10% seawater treatments, K+ contents in the shoot and root of Lactuca indica seedlings have no distinct difference compared with the control, but along with seawater stress strength upward, K+ content were markedly decreased by degrees. However, soluble protein content first increased then decreased with seawater concentration augment.

结果表明:苦荬菜幼苗地上部受海水胁迫较为显著,而根在30%海水以内与对照相比没有显著差异;根冠比随着海水比例的增加而提高;10%和20%海水处理下,叶绿素含量与对照相比差异不显著,但随着海水浓度的进一步增加,叶绿素含量显著下降;10%海水处理下,苦荬菜地上部分及根K+含量与对照差异不显著,高于10%海水处理,K+含量随海水比例的增加地上部和根部均逐渐显著降低;海水处理下,体内Na+和Cl-含量逐渐显著增加;地上部可溶性糖逐渐显著增加,而可溶性蛋白呈先升后降。

The results showed that elevated CO2 increased the R/S ratio and the dry mass of both coarse and fine roots, indicating that the seedlings under elevated CO2 allocated more biomass to their belowground part. Compared with control, elevated CO2 increased the contents of reducing sugar, sucrose, and total soluble sugar in coarse roots significantly, but had less effect on those in fine roots. Elevated CO2 increased the contents of starch and total non-structural carbohydrate both in coarse roots and in fine roots. Under elevated CO2, the carbon content in coarse and fine roots had an unsignificant increasing trend, while the nitrogen content decreased significantly, which resulted in an increase of C/N ratio.

结果表明:CO2浓度升高使红桦幼苗粗根和细根的干质量增加,同时根/冠值显著升高,表明CO2浓度升高使红桦幼苗生物量向根系的分配增加;与对照相比,粗根的还原糖、蔗糖和总可溶性糖含量显著增加,而在细根中没有显著变化;粗根、细根的淀粉和总的非结构性碳水化合物含量显著增加;CO2浓度升高下粗根和细根的碳含量有升高的趋势但未达到显著水平,同时氮含量降低,碳/氮值升高;氮的吸收量在粗根和细根中均无显著变化。

The results showed that elevated CO2 increased the R/S ratio and the dry mass of both coarse and fine roots, indicating that the seedlings under elevated CO2 allocated more biomass to their below- ground part. Compared with control, elevated CO2 increased the contents of reducing sugar, sucrose, and total soluble sugar in coarse roots significantly, but had less effect on those in fine roots. Elevated CO2 increased the contents of starch and total non-structural carbohydrate both in coarse roots and in fine roots. Under elevated CO2, the carbon content in coarse and fine roots had an unsignificant increasing trend, while the nitrogen content decreased signifi- cantly, which resulted in an increase of C/N ratio.

结果表明:CO2浓度升高使红桦幼苗粗根和细根的干质量增加,同时根/冠值显著升高,表明CO2浓度升高使红桦幼苗生物量向根系的分配增加;与对照相比,粗根的还原糖、蔗糖和总可溶性糖含量显著增加,而在细根中没有显著变化;粗根、细根的淀粉和总的非结构性碳水化合物含量显著增加;CO2浓度升高下粗根和细根的碳含量有升高的趋势但未达到显著水平,同时氮含量降低,碳/氮值升高;氮的吸收量在粗根和细根中均无显著变化。

The results indicates, with the same level of other parameters, the TN removal can reach 80.0% and 70.9% with the control of dissolved oxygen under the levels of 0.3-0.6mg/l and 0.6-0.9mg/l, respectively; the TN removal upgrades from 80%, 83% to 84.1% with the decrease of sludge load in the system from 0.1, 0.07, to 0.05gCOD/gMLSS·d; the nitrogen removal only reaches 58% when C/N is 4, but can reach more than 80% when C/N is at or over 7, which indicates that the TN removal increases when higher C/N ratio; when HRT increases from 12h, 18h to 24h, the TN removal also increases from 78.6%, 82.0% to 83.0%; the TN removal average in the system increases from 75.6%, 78.5% to 83.0% with the increase of sludge age from 18d, 20d to 24d; the low oxygen conditions in the modified Orbal oxidation ditch model do not decrease the effect of COD removal, and the dissolved oxygen gradient with the distribution of 0-2-1mg/l in the system ensures the COD removal reaching the range of 80%-86%; and the phosphate removal, however, is not good enough, which varies from 40% to 50%, even lower than 35% in occasional situations, and the phosphate concentration in the outflow varies in the range of 1.28-2.38mg/l, which dissatisfies the discharge standard with the level of 1.0mg/l.

试验结果表明,在其它参数相同的情况下,将外沟道的溶解氧分别控制在0.3~0.6mg/l 和0.6~0.9mg/l 两个水平,外沟道中TN 去除率分别为80.0%和70.9%;系统中污泥负荷分别为0.1gCOD/gMLSS·d、0.07 gCOD/gMLSS·d、0.05 gCOD/gMLSS·d时,随着污泥负荷的降低,TN 的去除率却是上升的,分别为80%、83%、84.1%;本试验中,当C/N 为4时,仅能获得58%的脱氮率,当C/N 为7 或更高时脱氮率能达到80%以上,进水C/N 比值越高,总氮的去除率越高;在本试验中采取的水力停留分别为12h、18h、24h 时,外沟道中的总氮去除率随水力停留时间的增加而增加,分别为78.6%、82.0%和83.0%;当系统泥龄分别为18d、20d、24d 时,系统平均TN 去除率分别为75.6%、78.5%、83.0%,随着泥龄的增大TN 的去除率增加;改良型奥贝尔模型的低氧条件并没有降低COD 的去除效果,系统0-2-1mg/l的溶解氧梯度分布使得COD 去除率一般都在80%~86%之间;本试验中磷的去除效果不好,去除率基本在40%~50%之间,有的甚至低于35%,出水磷的浓度在1.28~2.38mg/l 之间,低于1.0mg/l 的出水排放标准。

The results showed:Under the same fertilizer consumption,covered with straw and covered with film can increase the chlorophyll content and total leer area duration of the maize,can improve leaf nitrate reeducates activity,Photosynthesis and roots vigor,and the nitrate reeducates activity,the chlorophyll content and the roots vigor present positive correlation with yield. Meanwhile,average dry matter accumulation of straw-covered increased 7.1% than this of no-ploughed,yield increased 15.3%.The average dry matter accumulation of film-covered increased 20.1% than which of no-ploughed and 12.1% than which of plough and covered with straws.And yield increased 26.8% and 10.1%,notable differences.

结果表明:在相同的肥料用量条件下,秸秆覆盖和薄膜覆膜对玉米生长发育具有良好的促进作用,能显著增加玉米叶片叶绿素含量和光合势,增强叶片硝酸还原酶活性和根系活力,同时玉米叶片硝酸还原酶活性、叶绿素含量、根系活力等与最终籽粒产量呈正相关;秸秆覆盖比免耕全生育期平均单株干物质积累量增加7.1%,籽粒产量增加15.3%,薄膜覆膜分别比免耕和翻耕残茬覆盖全生育期平均单株干物质积累量增加20.1%和12.1%,最终籽粒产量增加26.8%和10.1%,差异显著。

The study indicates that the content of soil carbon is on the low side because human behavior has a negative effect on sloping cropland. However, the content of every group soil carbon increased drastically by planting Robinia . With the increasing of the time of conservation, the relationship is very remarkable. After 50 years of restoration, the content of TOC, LOC, NLOC and AI in the study plot increased by 271%,174%, 467%, and 271%, respectively, compared with sloping cropland. The increasing speed of NLOC was faster than LOC. It is assumed that the increased carbon by restoration is stored in an inactive form to produce active matter which is necessary for biont. And the soil carbon must keep active to fulfill the balance of carbon dynamic transformation. At initial stages, soil carbon management index increased remarkably.

营造刺槐林可以显著增加土壤碳库各组分含量,并随恢复年限呈显著线性关系,50a时TOC、LOC、NLOC和碳库指数分别较坡耕地增加271%、174%、467%和271%,其中NLOC增加速率略高于LOC,表明植被恢复增加的土壤碳素绝大多数以非活性形态贮存起来,而为了满足生物生长所必须的活性物质来源,土壤碳库必须维持一定的活度状态来满足碳素的动态转化平衡,碳库管理指数在营造刺槐林初期显著降低,随后先增加后降低,与刺槐林生长特性密切相关;但与天然林相比差距仍然较大,恢复50a时TOC、LOC和NLOC仅为侧柏林的49%、34%和61%。

The influences of environmental factors on the abiotic methylation were studied. The biggest production of methylmercury was found after 2 days of incubation in presence of FA. The rate of production of methylmercury depends upon temperature. In presence of FA from sediment, the biggest production of methylmercury was found under 40℃. In presence of FA from soil, production rate increases with temperature. The biggest production of methylmercury was found when solution pH was 2 and 4 in presence of FA from sediment and soil, respectively. Increase in concentrations of inorganic mercury and FA solution causes an increase in the production of methylmercury. Under irradiation with ultraviolet ray, blacklight lamp as well as natural light, methylation is stimulated, especial for irradiation of ultraviolet light.

环境条件对汞甲基化作用的影响研究得出,在底泥和土壤FA体系中甲基汞产量均在反应2天后达到最大值;在底泥FA体系中汞的甲基化在反应温度为40℃时产量最大,而在土壤FA体系中,甲基汞产量在10~60℃之间随反应温度升高而增加;底泥和土壤FA体系中汞的甲基化分别在pH值为2和4时最大;甲基汞产量均随无机汞浓度和腐殖质浓度的增加而增加;紫外线、黑光灯和自然光照射都可促进甲基汞的生成,紫外线的作用尤其明显。

And also the device was simulating. The results of cold - flow model test indicate that pressure drop rises with increasing air quantity and solids quantity respectively, however, much more air quantity will make pressure drop minish in the same height position;The average concentration of granule minishes with increasing air quantity, and rises with increasing solids quantity in the same height position;The inhomogeneity of distribution of the average granule concentration minishes with increasing air quantity, and rises with increasing the granule quantity.

冷态实验结果表明:流化床内同一高度截面与基准面之间的压差是随风量的增加而增加的,但是风量过于增大反而使同一高度截面与基准面之间的压差减小了,同时,压差是随初始物料量的增加而逐渐增加的;在同一高度截面上,颗粒平均浓度随风量的增大而逐渐减小的,随物料量的逐渐增大而增大的;颗粒浓度分布的不均匀性随风量的增大而逐渐减小,而随物料量的增加而不断增大的。

Yunnan Tobacco Research Institute, Yuxi 653100Abstract : In order to investigate the effect of medium and trace elements, organic fertilizer on appearance and internal qualities of sun-cured tobacco, search after some efficient ways to improve the qualities, by adding organic fertilizer in basal dressing and spraying trace elements on leaf surface, the results showed that both organic and medium or trace fertilizer having the effect of increasing output value and yield. Among the experimental treatments, magnesium fertilizer and manure plus rape cake showed the most.

为研究中微肥和有机肥对红土晒烟外观和内在品质的影响,探索提高和改善红土晒烟品质的有效途径,试验在基肥中加入有机肥,和大田生长期在叶面喷施中微量元素肥料,结果表明:施用有机肥的处理与对照相比,产量增加7.3%~20.9%,产值增加8.8%~25.3%,以厩肥+菜籽饼处理的效果最好;四个喷施微肥的处理其产量和产值均超过了喷清水的对照,其中产量增加6.7%~15.6%,产值增加6.8%~20.5%,以喷施镁肥的增幅最大。

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