固液平衡

Increasing the laser traverse speed is favourable to the TiC〓 particle engulfment leading to a more homogeneous distribution of TiC particles.

本文根据激光熔池内TiC〓受力的平衡关系推导出了液固界面淹没TiC〓的临界移动速度V〓的表达式。

Results showed that using said separation technique and calculation method to study the crystallization behavior of diesel fuels at cold filter plugging point was feasible.

实验结果表明，用该分离方法以及计算方法来研究柴油在冷滤点温度下液-固平衡态的结晶行为是可行的。

From these researches as above, this paper found a new method to analysis salty soil road engineering properties by phase equilibrium theory, which provides a new angle of analysis on salty soil properties, experiment and engineering practice in these ways as follows:(1) Analysis the disadvantage of traditional salty soil experiment;(2) Analysis the disadvantage of current salty soil definition by phase equilibrium theory, and gives the chart of distinguish salty soil by the condition of hydrography and climate change;(3) Analysis the mechanics of subgrade frost boiling based on the change rule of liquid content;(4) Based on the change rule of ingredients content and volume in salty soil, analysis the mechanics of subgrade salt heaving and the restraining method by adding sodium chloride.

通过以上研究，本文初步建立了以相平衡理论为核心的盐渍土路用工程性质分析方法，该方法对盐渍土工程性质的理论分析、试验研究以及工程实践提供了新的研究思路与方法，具体体现在：(1)分析了传统的盐渍土试验存在的缺陷；(2)分析了现行盐渍土定义的不足，并以相平衡理论为基础，结合水文、气候条件的变化给出了判别盐渍土的诺谟图；(3)分析了盐渍土盐溶液含量的变化规律，并从盐渍土含液量变化规律出发，分析了盐渍土路基较非盐渍土路基翻浆严重的机理；(4)分析了盐渍土各固相含量及其体积的相变规律，并在此基础上分析盐渍土路基的盐胀机理，以及采用添加氯化钠来抑止硫酸盐盐渍土的盐胀机理

By systemic researching and simulating experiment, the text gains such results as follows,1. On the base of sufficiency research on the oil-gas hydrocarbon systemic chemistry composing and the physical chemistry characters, we traverse the mechanism of the paraffin's deposition. Then we consider that paraffin deposition is a complex process ofphysical chemistry, which includes more than one single mechanism.2. Traversing and comparing the literature in detail on different factors that has effect on paraffin deposition, the available experimental methods on paraffin deposition, prevention of paraffin deposition, and removing of the deposited paraffin on the spot.3. Ameliorated the laser equipment of solid particle inspecting system and the corresponding test methods. Determine WCT of dead oil and live oil from KS101 well under different pressure with this system. The result implies that dead oil has opposite regulation on paraffin deposition temperature to live oil.4. A vapor-liquid-solid envelop is drawn by superposition regular vapor-liquid envelop and WCT curve thereby explained that the departure and quick raising of the curve in the low temperature zone is caused by the appearance of paraffin in solid phase.5. Estimation is made to determine the depth of paraffin deposition in the well.

通过系统的研究和实验模拟，本文取得了以下研究成果：(1)在充分调研油气烃类体系的化学组成及其物理化学特征的基础上，详细研究了石蜡沉降的机理，认为石蜡沉积是一个复杂的物理化学过程，是多种机理共同作用的结果；(2)深入调研并综合阐述了影响石蜡固相沉积的各种主要因素，对目前国内外常用的有机固相沉积实验研究方法和现场清防蜡措施也做出详尽的描述，并加以对比评价；(3)改进了油气藏开发重点实验室自行研制组装的高温高压下测定固相沉积的激光装置和测试方法，并用该套设备测定出柯深101井的井口脱气油样和凝析气平衡油样不同压力下的析蜡点，实验结果表明，脱气油和平衡油析蜡规律相反；(4)将常规气-液两相相图和析蜡曲线叠加得到了气—液—固三相相图，从而解释了气-液两相等液量线在低温区域偏离正常并快速上翘是由于体系有石蜡固相出现；(5)利用实验测试的析蜡温度预测析蜡位置，表明只有在距井口465m油管以上会有蜡析出。

It was found that sulfuric acid, 2-naphthalenesulphonic acid and sulfurous acid could be effectively separated by competitive exchange adsorption in views of action force difference of the components with the resin. The exchange adsorption dynamic diffusion parameters were calculated with diffusion equation for solids and liquid films, and the rate-determining step was determined. The model of breakthrough curve for the resin bed was suggested, and applied to simulate the breakthrough process for each component.

通过单组分、双组分和多组分平衡数据的测定，发现对于硫酸-萘磺酸-亚硫酸混合体系，可以利用不同组分与树脂作用能的不同，通过竞争交换吸附实现分离；以固相扩散方程和液膜扩散方程对交换吸附动力学参数进行了估算，确定了交换吸附过程的控制步骤；建立了床层穿透曲线模型，并对各组分穿透过程进行了模拟。

Finally, in consideration of the interfacial interaction between liquid and solid, a new model for dropwise condensation heat transfer was proposed by using the population balance concept and considering the effect of surface topography and contact angle.

最后，针对液固界面相互作用对滴状冷凝传热的影响，以液滴数平衡概念为基础，考虑表面形貌和表观接触角对冷凝传热的作用，建立了新的滴状冷凝传热模型。

The experimental products include crystal phase quartz, feldspar (alkila-feldspar, albite, K-feldspar), zinnwaldite and topaz, a melt phase and a trace vapour. The solid products were been studied by optics method, electron microprobe and X-ray analysis. The results show that liquidus temperature raises slightly and solidus temperature falls down obviously and that the upper temperature limit raises for the stability field of quartz and topaz, and falls down for the stability field of alkila-feldspar as F contents in crease.

实验淬火产物包括结晶相石英，长石(碱性长石，钠长石、钾长石)，铁锂云母和黄玉及玻璃相和微量流体，对固相淬火产物进行了系统和详细的显微观察及电子探针和x射线分析，研究了F对钠长花岗岩液、固相线温度、相关系和相组合的影响和含F钠长花岗岩的结晶序列和熔体演化、F在流体和熔体之间的分配及F对花岗质熔体结构的影响，对含黄玉矿物组合进行了一系列热力学矿物平衡计算，获得如下重要结论

The phase equilibrium data of SBO-FAME-Methanol, SBO-FAEE-Ethanol and Glycerol-FAEE-Ethanol systems were measured. The results indicated that it involved two different stages: liquid-liquid-solid reaction stage and liquid-solid reaction stage. When the molar ratio of methanol to oil is 12:1 at 65℃, the turning point is at a 55% biodiesel yield. The liquid-liquid-solid reaction model was proposed based on the double-membranes theory. It indicated that the process is reaction and mass transfer controlled together at the first stage, and the second stage is reaction controlled. The predictions of the model are matched with the experimental results.In the end, the acid was extracted using methanol and ethanol from jatropha curcas l oil.

测定了生物柴油制备过程中的SBO-FAME-Methanol、SBO-FAEE-Ethanol、Glycerol-FAEE-Ethanol三组分相平衡数据，表明固体碱催化过程分为液-液-固和液-固两个反应阶段，在醇油摩尔比为12：1、65℃的初始反应条件下，转化率达到55%时，为第一阶段向第二阶段的转折点；基于双膜理论建立了固体碱催化制备生物柴油的非均相液-液-固反应模型，表明两个反应阶段分别为传质、反应共同控制和反应控制，模型计算值与实验值吻合较好。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐