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This paper emphasizes the mechanism of UV-cured, the mechanism of the pigment's color change, the effect of pearl pigment's mosaic gold. The conclusion is reached through the theoretical analysis of the experiment phenomena and data.

文章着重论述了紫外光固化涂料的固化机理、温变颜料的变色机理,珠光颜料的彩金效果再现,颜料对UV光油的西安理工大学硕士学位论文固化的影响以及添加合适光引发剂来调整UV光油的固化速度等问题,并通过实验现象和试验数据进行了理论分析,得出结论。

The influence of the behavior, mechanism, product structure and relation of structure with properties for co-curing reaction of epoxy resin and cyanate ester system catalyzed by transition metal acetylaceton, etc. was studied.

研究了用乙酰丙酮过渡金属络合物等促进剂催化促进环氧树脂与氰酸酯(在氰酸酯欠量,适量和过量条件下)的共固化反应行为、固化反应的机理、固化物的结构特征以及结构与性能关系。

Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明,出现在A组分中的2275~2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390~3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求,即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中;凝胶渗透色谱结果表明,成膜物质的A、B组分均为低分子量,符合预聚物的要求;涂膜表面能的测算结果表明,涂膜的表面能在33.6~47.17mN/m之间;加入碱式防污剂后涂膜的表面能略有升高;碱式防污剂的释放平稳,随着涂膜在海水中浸泡时间的增长,pH值有增加的趋势;用溶解度参数原则来评价涂料与网绳的涂装,结果表明,本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

The Solidification temperature range was defined as 110-200℃ by DSC analysis. More accelerant used can increase the casing samples dynamic performance, but more than enough accelerant can induce a severe solidified reaction that result in a smaller polymeric meshwork and reducing the sample's performance. Normally the Accelerant dosage can be 2 portions; The Epoxy resin CFRP has a obvious better performances than the Vinyl-ester Resin CFRP, i.e. had a Bend Strength of 1516MPa, LSS of 85MPa, also Tg raised to 195~C~ When used the end-carboxyl polyether to reinforce the epoxy resin, the casing sample's SS, BS and Crack Elongation all increased geminately. The CFRP performance also increased a little, that is because the performance of the CFRP mainly contributed by the CF. The reinforced resin improved the interface between the CF and resin that contribute to the little increasing.

通过DSC分析确定了该环氧树脂的固化温度范围为110~200℃,促进剂增加会提高浇注体力学性能,但过多的促进剂会使固化反应剧烈,聚合网络减小,使浇注体性能下降,一般用量为2份左右;以环氧树脂为基体的复合材料性能明显比以乙烯基酯树脂的性能提高,弯曲强度达到1516MPa,层间剪切强度达到85MPa,同时Tg也上升到195℃;用端羧基聚醚增韧环氧树脂后,其浇注体的拉伸强度、弯曲强度及断裂伸长都成倍增加,复合材料的性能也有所提高,但提高幅度不大,因为复合材料的力学性能主要由碳纤维承担,树脂增韧后改善了复合材料的界面性能。

Through research, the relationship among cured depth and concentration of photoinitiator, exposure energy, concentration of monomer, ratio of monomer to cross linker, refractive index of liquid, volume fraction of powders, mean diameter of powders are confirmed.

通过对浆料固化性能的研究,得出了固化厚度随引发剂浓度,曝光能量,单体质量分数,单体和交联剂比例,单体溶液的折射率,粉末体积分数以及粉末粒径的变化关系,并得出相应的最佳值。

The effects of curing property of coatings such as diff-erent kinds of photoinitiator,diluents and additives were discussed.

不同光引发剂、稀释剂和助剂等对UV固化环氧丙烯酸酯涂料固化性能均有影响。

All of the studies in this paper, including the study of leaching behavoirs of HLW glass under repository conditions, low oxgen and multi-barrier media; the geochemical model PHREEQC used for calculating the leachate compositions and sediment phases on the glass surface; A Monte Carlo model established and used for study of leaching behavior of HLW-glass; as well as the high-temperature self-propagating synthesis used for immobilization of Sr element in perovskite synroc, are the front research works of this field in the world, and obtained some significative results in theory and practice.

本研究所作的高放废液玻璃固化体在模拟地质处置条件下(低氧条件和多种地质介质)的浸出行为研究,采用了低氧条件和多种模拟地质介质,包括北山预选厂址的花岗岩、膨润土、水泥和Fe〓O〓作为浸出介质,模拟地下水和去离子水作为浸出剂,90℃和150℃两种浸出温度;采用了地球化学模型PHREEQC(version2.7)研究玻璃固化体浸出液中主要元素的浓度以及沉积相的生成;采用蒙特卡罗法建立玻璃固化体的计算模型,对玻璃固化体的浸出行为进行研究;采用了自蔓延高温法固化锶,这些工作都是当前国际上比较前沿的研究课题,采用了先进的分析测试技术,并且作了大量计算,得出了理论上和实践上有意义的结果。

This job studies the influence on curing performance of UV-ink by changing sorts or per centum about thermo-cross-linking agents, activity odd unit and oligomer.

实验通过改变热交联剂、活性单体、齐聚物的种类、含量,研究交联剂的相互作用对UV固化油墨中固化性质影响。

Because of advantages such as fast-curing, lower energy consumption, no solvent pollution and so on, UV-curing coatings have rapid development. It has wide range of applications in painting of wood, metal, plastic, paper. In order to fit some special applications and make cured coatings have some special performance, the development of new type of resins, diluents, functional additives used in UVCC was introduced. Some new kinds of UVCC were developed and employed.

紫外光固化涂料由于具有快速固化、低能耗、无溶剂污染等优点而得到快速的发展,在木材、金属、塑料、纸张等的涂装上有广阔的应用前景,为满足一些特殊的应用场合或使固化膜具有某些特殊的性能,一些新型树脂、稀释剂和功能助剂等得到了研究和发展,开发和应用了一些新的紫外光固化涂料品种。

To present an adhesive sheet roll for wafer processing excellent in storage stability, radiation curing property, and low contamination to wafer.

一种保存稳定性、放射线固化性以及对晶圆的低污染性优异的筒状晶圆加工用粘合片,是将由基材薄膜、放射线固化性粘合剂层、以及脱模薄膜按顺序层叠而成的层叠薄膜,多重缠绕而形成的筒状晶圆加工用粘合片,所述基材薄膜和/或脱模薄膜的与放射线固化性粘合剂层接触的面的另外面侧表面的轮廓算术平均偏差为1μm以上,且所述放射线固化性粘合剂层中所含的自由基聚合抑制剂的重量低于1000ppm。

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