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Cement and silver sand are used as the basis materials for solidifying galvanized sludge containing heavy metals such as Ni,Cr and Cu,the lixivium test to solidified matter shows that the effect of solidifying galvanized sludge with cement is good.

采用水泥和细砂作固化基材处理含Ni、Cr、Cu等重金属的电镀污泥,对固化块的浸出试验表明:水泥固化该电镀污泥效果良好,固化过程中加入适当的螯合剂KS-3,可以提高固化效果,并对固化块在不同pH浸取剂下的重金属浸出浓度进行了研究。

The changes of molecular weight and viscosity of the UV-curing coatings during storage were determined by GPC and viscometry .

用凝胶渗透色谱和粘度法跟踪测定光固化涂料贮存期间的分子量参数和粘度,探讨了影响光固化涂料贮存稳定性的各种因素,对2种光固化树脂在加入不同光引发剂、不同活性稀释剂后的贮存稳定性作了评价。

Three components of peroxide in the activator amongwhich have the different decomposed temperatures made the Vinyl-ester resinsolidified heat discharge increased that gained a bigger solidified degree. Theactivator-adopted quantity can dramatically affect the casting samples performance:eg. When use 1.0-1.4 portions of activator, the casing sample can reach its maximumTensile strength and Bend strength; when use more activator, the polymeric meshworkcontracted which embrittle the casing sample and reduce the dynamic performance; Inthe Pultrusion processing, when CF composed of about 60vo1%, more demould agentcan bring the better processing but degrade the CFRP, normally use around 1.2 portion.

采用具有不同分解温度的三组分有机过氧化物引发剂,乙烯基酯树脂的固化反应放热量增加,固化程度提高;引发剂用量对浇注体的性能影响很大,在用量为 1.0~1.4 份时,浇注体拉伸强度剂弯曲强度达到最高,过多的引发剂使聚合网络减小,浇注体变脆,力学性能降低;在拉挤成型工艺中,碳纤维的体积含量一般为 60%左右,脱模剂增加使加工性能好转但会使复合材料性能下降,一般用量为 1.2 份。

The experiment results indicated that the cross-linking mechanism of hydrogenated terpinene maleic anhydride with bisphenol A epoxy resin was similar to anhydride curing with epoxy resin in the presence of accelerants. The curing degree was increasing as the curing temperature was arisen and the curing time was delayed, and the gelation time was shortened obviously as the curing temperature was arisen and the dosage of accelerants was increased.

实验结果表明:HTMA与环氧树脂的固化反应过程与促进剂作用下的酸酐固化环氧树脂的交联反应机理一致;固化度随温度升高、时间延长而提高,而凝胶时间随温度升高、促进剂用量的增加明显缩短。

The results show that Irgacure1000 is preferable in the system and the rate is highest when the amount of Irgacure1000 is 3%;the drying condition has a considerable impact on the rate ; it decreases with the increase in neutralization degree;when NaOH is used as neuralization agent,the rate at the later period is higher than that when triethyl amine used; the structure of polymer has a certain effect on the rate and it accelerates with the increase in the ratio of PBA/DMPA and HEAD/DMPA.

结果表明,本体系优选光引发剂Irgacure1000的质量分数为3%时固化速度最快;干燥条件对光固化速度有很大的影响;随着中和度的提高,固化速度下降;用NaOH作为中和剂时,后期固化速度快于用三乙胺;聚合物结构对固化速度有一定的影响,随着PBA/DMPA和HEA/DMPA比例的提高,固化速度加快。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15~4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1~2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓~IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯,甲基丙烯酸-β-羟乙酯,丙烯酸及苯乙烯合成厂丙烯酸共聚树脂,并与含-NCO端基的聚氨酯丙烯酸酯接枝反应,经水性化后,得到两个系列(Acr-g-TPU-PETA和Acr-g-PPU-PETA)各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系,粘度与水相近,为牛顿流体,固含量30%左右。光固化前干燥涂膜的玻璃化转变温度在-15℃~4℃之间,有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料,接枝样dTG峰明显宽化,表明接枝样中链段之间的相互作刚有多重性,丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50%~30%者相对较好,且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1~2级,冲击强度为50kg·cm,柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团,碳—碳双键密度太低,光固化膜交联点太少,硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中,不出现色斑,光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜,光泽度及耐丁酮溶剂性能均有所提高,不会诱导铁基生锈,钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色,对光固化涂层的颜色干扰较小,为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出,且对所附着的铁基有诱导锈蚀作用。

Add red paint or carbon black to based varnish of high quality to study the influence on curing performance of UV-ink by changing sorts or per centum. The result is that the job can acquire thermo-cross-linking UV-ink by adding thermo-cross-linking agents.

优化光油配方,选择品质较好的光油,加入红色颜料、炭黑后配制出不同的热交联-UV固化油墨,研究交联剂的相互作用对油墨固化性质的影响,结果表明,加入交联剂后可以得到性能优良的热交联-UV固化油墨。

Foshan City HS surplus resin plant, is a professional engaged in the production of epoxy resin curing agent of the manufacturers and sales.

佛山市协盈树脂厂,是一家专业从事环氧树脂固化剂生产和销售的厂家。

Clients can be based on product specifications, characteristics and application of the selection of a suitable curing agent and fluorocarbon resin.

客户可根据产品的规格、特征及应用等来选用适合的固化剂以及氟碳树脂。

The modified acrylic resin could be a macromolecule curing agent of adhesive, and it can improve the strength and transparency.

该改性后的丙烯酸树脂可作为胶粘剂的大分子固化剂,能提高粘接强度和透明性。

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