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Herein, we report the enantioselective total syntheses of slagenins A-C and their antipodes. Starting from readily available ethyl -4-chloro-3-hydroxy-butanonate, elongation of the carbon chain with diazomethane, followed by oxidation of the given α-diazoketone using distilled DMD, afforded a key intermediate α-ketoaldehyde .

本文从方便易得的-4-氯-3-羟基-丁酸乙酯出发,经重氮甲烷延伸碳连、DMD氧化相应的α-重氮酮,制得α-酮醛;该化合物与尿素在氢氟酸作用下,以协同方式非对映选择性的直接构建了cis-四氢呋喃并[2,3-d]咪唑啉-2-酮双环结构,进而合成了天然产物slagenins A、B、和C的对映体。

Chapter two: Using 5-(4-aminophenyl)-10,15,20-triphenylporphyrin as thestarting compound, the classical diazotization of aniline and the resulting reaction ofdiazo salts were applied to porphyrin for the first time, and a series of asymmetriclysubstituted meso-tetraarylporphyrins including 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin, 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin, 5-(4-cyanophenyl)-10,15,20-triphenylporphyrin, 5-(4-bisphenyl)-10,15,20-triphenylporphyrin and 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin were synthesized.

第二章:在已合成的5-(4-氨基苯基)-10,15,20-三苯基卟啉基础上,首次将芳胺的重氮化及重氮盐反应应用于卟啉,合成了5-(4-氯苯基)-10,15,20-三苯基卟啉、5-(4-碘基苯基)-10,15,20-三苯基卟啉、5-(4-氰基苯基)-10,15,20-三苯基卟啉、5-(4-联苯基)-10,15,20-三苯基卟啉和5-(4-羟基苯基)-10,15,20-三苯基卟啉等一系列不对称取代的meso-四芳基卟啉。

Study on comparative morphology of dissimilitude in winged bean breed,compare with kinship of dissimilitude breed.

以四棱豆豆荚长、宽、高、豆夹宽高比、豆粒百粒重、每个豆荚豆粒数及豆荚特异性形状等指标为依据,对不同的四棱豆品种进行形态学研究,比较不同品种之间的亲缘关系。

In Chapter 4we make more study about the properties of the multifractal Hausdorff mea-sure.The existence of finite measure subsets and the Frostman theorem areproved in this chapter.

第四章我们进一步讨论重分形Hausdorff测度的性质,证明了关于重分形Hausdorff测度的有限测度子集的存在性及Frostman定理。

Low temperature inspissation reflux's withdrawing a machine set is to synthesize a reflux, the 渗漉 withdraws, the against the current withdraws and takes out with hot reflux and lifts and condenses 4 kinds and withdraws principle, withdraw, condensing Chinese herbal medicine two work prefaces carry on in the meantime, a completion Chinese herbal medicine withdraws, concentrated new craft, and change and withdraw the work in the bottle and often press of heat decoction craft, make use of vacuum negative press and carry on low temperature and withdraw low temperature concentrated, make and withdraw work temperature in the bottle a control in 60 ℃~70 ℃, concentrated temperature control in 50 ℃~60 ℃, promised the medicine material valid composition to be steamed not and run off.

请各位英语高手帮忙,拜托,急用,有重谢!!请各位英语高手帮忙翻译以下内容,不要机械翻译,感觉不错定当加分重谢!!拜托,急用!!低温浓缩回流提取机组是综合了回流,渗漉提取,逆流提取与热回流抽提浓缩四种提取原理,将中药的提取、浓缩两道工序同时进行,一次完成中药提取、浓缩新工艺,并改变提取罐内的工作与常压的高温煎煮工艺,利用真空负压进行低温提取低温浓缩,使提取罐内的工作温度控制在60℃~70℃,浓缩温度控制在50℃~60℃,保证了药材有效成分不被蒸了流失。

It seeds area and total yield are big in our country.This study combined Hubei province item of the project of country important food foisori science and technology. It considered the difference of climate character、 cultivate system and plant habit in the southeast of Hubei、 in the middle of Hubei、 in the northwest of Hubei and in the Jianghan plain four rice plant areas. It had formed " double season rice three ripe high yield in the southeast of Hubei mode "、" sparse、 manipulative、 weight middle season rice high yield in the middle of Hubei mode"、" zero till light-duty high yield plant in the Jinghan plain mode" and " cover with ground film wet in all process in the northwest of Hubei plant mode" four adaptive plant modes base on present plant modes.

本研究结合粮食丰产科技工程国家重大科技专项湖北项目的部分研究内容,针对湖北省鄂东南、鄂中、江汉平原及鄂西北四大稻作区不同生态气候特点、耕作制度和种植习惯,在现有栽培技术的基础上组装集成"鄂东南双季稻三熟高产模式"、"鄂中稀、控、重中稻高产模式"、"江汉平原免耕轻型丰产栽培模式"及"鄂西北全程地膜覆盖湿润栽培模式"四种配套栽培技术模式,分别在武穴、随州、沙洋、房县等四地进行大田试验示范。

We firstly succeeded in the separation of the new cationic complexes of tetrakis (4-methoxyphenyl) porphyrin with yttrium, erbium, thulium and ytterbium (RE-TMOPP-Cl) by reserved-phase high performance liquid chromatography.

我们首次用高效液相色谱分离了性质极其相似的钇、铒、铥和镱四个重稀土的阳离子型四(4-甲氧基苯基)卟啉配合物。

In the forth chapter, the convergence problem of three Ishikawa and modified three Ishikawa iterative sequences under uniformly continuousΦ-strongly pseudo-contractive mapping and approximating pseudo-contractive mapping is

第四章主要讨论了三重迭代序列以及修改了的三重迭代序列在一致连续的Φ-强伪压缩映射、渐近伪压缩映象下的收敛问题,给出了其判别准则和结论描述。

Pseudocumene, mesitylene, 1,2,3-trimethylbenzene and durene among theheavy aromatic hydrocarbon from catalytic reformation in oil refinery areimportant fine chemical materials, they have not only high additional value butalso particularly useful property, therefore, the exploiting and utilizing the sourceof the heavy aromatic hydrocarbon are of large commercial benefit and promisingapplication future.

炼油厂催化重整装置重芳烃中偏三甲苯、均三甲苯、连三甲苯、均四甲苯等都是精细化工的重要原料,不仅附加价值高,而且具有独特的优良性能。因此开发利用重芳烃资源具有较大的经济价值和广泛的应用前景。

Using classical diazotisation of anilines, 5-(4-aminophenyl)-10,15,20-triphenyl-porphyrin was converted to a series of meso-tetraarylporphyrins with different substituents, including 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin (80%), 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin (74%), 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin (76%), 5-(4-hydrazinephenyl)-10,15,20-triphenylporphyrin (67%) and 5-(4-bisphenyl)-10,15,20-triphenylporphyrin (32%). Therefore an efficient way of synthesizing unsymmetrically substituted TAPs was developed.

利用芳胺的重氮化及重氮盐反应,研究了5-(4-氨基苯基)-10,15,20-三苯基卟啉上氨基官能团的转化反应,以较高产率合成了5-(4-羟基苯基)-10,15,20-三苯基卟啉(80%)、5-(4-氯苯基)-10,15,20-三苯基卟啉(74%)、5-(4-碘基苯基)-10,15,20-三苯基卟啉(76%)、5-(4-肼基苯基)-10,15,20-三苯基卟啉(67%)和5-(4-联苯基)-10,15,20-三苯基卟啉(32%)等一系列含单个para-取代基的meso-四芳基卟啉,为合成不对称取代的芳基卟啉提供一条有效途径。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。