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四氯苯醌

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In part four, a new method of protein assay based on charge-transfer reaction of protein with chloranil has been established.

第四部分,作者首次建立了以四氯苯醌荷移反应测定蛋白质的新方法,并测定了蛋白质结合四氯苯醌的最大结合数和反应平衡常数。

The yield of TAMD was only 20% without participation of acetic acid, and it was almost 0% without chloranil.

没有冰乙酸,醇色体的收率仅为20%;没有四氯苯醌,醇色体的收率几乎为零。

The photo reactions of β-diketones compounds with chloranil in C6D6 were through free radical intermediates.

β二酮类化合物与四氯苯醌在C6D6溶液中的光化学反应过程具有自由基反应的特点。

The different substitutes had an effect on the main form of β-diketones, making the hydrogen donors to chloranil different correspondingly.

二酮类化合物中的不同取代基会影响其主要存在形式,因而使得四氯苯醌夺取氢的对象也有所不同。

The effect of acetic acid and its consumption, chloranil and its consumption on the preparation of TAMD by means of dioxygen liquid-phase oxidation of TMAL was probed into, and the results showed that both of them had great influence on the yield of TAMD.

探讨了冰乙酸及其用量、四氯苯醌及其用量对氧气液相催化氧化孔雀绿隐色体制取孔雀绿醇色体的影响,发现二者对醇色体的收率和纯度均有很大影响。

1 At a reaction temperature of 100 ℃ and a reaction time of 30 min to give 2,which was then subjected to condensation reaction with p-propoxy mandelic acid in the presence of phosphoric acid at a molar ratio of m(2)∶m( p-propoxy mandelic acid )∶m=1∶1∶1 at a reaction temperature of 60 ℃ for 3 h to yield 3,which was further oxidized by chloranil to give t.

对现有分散红356合成工艺进行了优化,以n∶n=1.2∶1投料,100℃反应30 min得缩合物2,再在等质量磷酸催化下与分批加入的等质量对丙氧基扁桃酸60℃缩合3 h得缩合物3,经温和氧化剂四氯苯醌氧化得标题化合物,总收率55%。

In the process, chloranil firstly was excited to singlet state and then a labile hydrogen abstraction interaction between singlet chloranil andβ-diketones was involved to form singlet stable neutral radical pairs.

光照作用下,四氯苯醌首先跃迁至单线态,然后夺取β二酮类化合物分子中的活泼氢,形成单线态中性自由基对。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能,通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应,合成了聚噻吩对二甲氨基偶氮苯甲烷,再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

The main products are fatty acid methyl ester with an annual output of 6,000 tons, with an annual output of 1,000 tons Phytosterols, natural vitamin E oil, food and feed-grade class of natural vitamin E powder with an annual output of 1,200 tons, four with an annual output of 2,000 tons chlorobenzene quinone, crystalline acid Sodium, anhydrous sodium acetate with an annual output of 3,000 tons, and plasticizers to octyl phthalate, and other products, 30,000 tons more than the total output.

主要产品有脂肪酸甲酯年产6000吨,植物甾醇年产1000吨,天然维生素E油、食品级和饲料级天然维生素E粉年产1200吨,四氯苯醌年产2000吨,结晶乙酸钠,无水乙酸钠年产3000吨,以及增塑剂对苯二甲酸二辛酯,等系列产品,总产量30000吨以上。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品:对氯苯酚,邻氯苯酚,2,4二氯苯酚,2,6二氯苯酚,2,4,5三氯苯酚,2,4,6三氯苯酚,4氯2苄基苯酚,对溴苯酚,2,4,6三溴苯酚,对氯苯基叔丁基醚,间溴苯甲醚,间溴氟苯,α溴甲基四氢呋喃,α溴代4氯苯乙酮,α溴4甲氧基苯乙酮,4氯二苯甲酮,4氯2甲基苯胺,N(2羟乙基)乙二胺, 2,3二溴丙酰氯,对溴苯磺酰氯,对苯二甲酰氯,间苯二甲酰氯,N氯代丁二酰亚胺,N溴代丁二酰亚胺,四氯苯醌,5氯靛红。

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