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四氧化锇

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To solve this problem, several methods have been introduced for the recovery and reuse of the ligands and osmium tetroxide.

为了解决这一问题,科学家探索了多种回收手性配体和四氧化锇的方法。

But, the powdery osmium, gradually will be oxidized under the normal temperature, and production perosmic anhydride.

可是,粉末状的锇,在常温下就会逐渐被氧化,并且生成四氧化锇

The copolymers are oxidized with hydrogen peroxide in the presence of osmium tetroxide. It is confirmed by superscript 1H-NMR and FTIR that the double bonds in the molecule chains of the copolymers are fully oxidized, while the segments of polystyrene in the copolymers are kept intact.

采用双氧水在四氧化锇催化下对聚合物分子链进行氧化降解,1H-NMR和FT-IR分析表明共聚物中的双键被全部氧化并发生断裂,而共聚物中聚苯乙烯的链节并未被破坏。

Briefly, coronal brain sections (100 mm)were cut with a vibratome, postfixed with 4% glutaraldehydein 0.1 mmol/L cacodylate buffer (pH 7.4) for 1 h, andthen with 1% osmium tetroxide in 0.1 mmol/L cacodylatebuffer for 2 h. After rinsing with distilled water, the brainsections were treated with 1% aqueous uranyl acetateovernight, dehydrated in an ascending series of ethanolsto 100%, followed by dry acetone, and then embedded inDurcupan ACM. Ultrathin sections (0.1 mm) were cut andstained with 3% lead citrate and subsequently examinedwith a Zeiss transmission electron microscope (Zeiss Inc.,Thornwood, NY, USA).

简单的说,先用切刀制成100um的冠状脑切片,然后用含有4%戊二醛在0.1 mmol/L的二甲砷酸缓冲液(PH7.4)中固定1小时后,放在含有1%四氧化锇的0.1 mmol/L的二甲砷酸缓冲液中2小时,接着用蒸馏水冲洗后,放在1%的aqueous uranyl acetate中过夜,接下来用梯度酒精(至100%)脱水,然后用丙酮干燥,再用Durcupan ACM包埋,切成0.1um的超薄切片后用3%的lead citrate染色,随后用透射电子显微镜观察。

Perosmic anhydride when 48 degrees Celsius will melt, to 130 degrees Celsius when will seethe with excitement.

四氧化锇在48摄氏度时会熔化,到 130摄氏度时就会沸腾。

The chlorin e6 7 and chiorin 11 were oxidized further with osmium oxide in the same oxidization condition to yield bateriochlorin 8 and 12, respectively.

卟吩醛2在碱性条件下转化为卟吩e6三甲酯7,2与烷基溴化镁的格氏反应给出脱镁叶绿酸醇9,选择高钌酸四丙基铵和N-甲基吗啉N-氧化物将3-位羟基氧化成羰基,所生成的卟吩二酮10在酸性条件下脱去甲酸甲酯生成焦脱镁叶绿酸衍生物11,用四氧化锇对7和11实施氧化,则分别转化为细菌卟吩衍生物8和12。

The methyl pheophorbide-a (5) was oxidized with osmium oxide and sodium periodate to give chlorin 8 which was converted into aldehyde purpure-18 (9) and purpure-7 trimethyl ester (10) by air-oxidation in butanol in the presence of sodium.

选用四氧化锇和高碘酸钠将5氧化成卟吩醛(8),在丁醇中以丁醇钠作催化剂, 8的氧化和重排反应给出3-甲酰基紫红素-18酯(9)和紫红素-7三甲酯衍生物10。

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Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。