四嗪

In this dissertation, the stable radical cation salts ofphenothiazine and 10 - alkylphenothiazine alky=〓(〓 hexachloroantimonate,perchlorate and iodide were prepared by one- electron oxidationwith 2,2,6,6-tetramethyl - 4 -acetyloxypiperidine oxoammoniumhexachloroantimonate, perchloric acid/hydrogen peroxide andmolecular iodine respectively, and they were characteried by UV -Vis spectroscopy and ESR spectroscopy.

本文的主要内容有：吩噻嗪和10-烃基吩噻嗪分别被碘、高氯酸／过氧化氢，2，2，6，6-四甲基-4-乙酰氧基哌啶氧铵六氯锑酸盐氧化为相应的正离子自由基碘盐、高氯酸盐、六氯锑酸盐，并用UV-Vis光谱和ESR波谱进行了鉴定和研究。

The UV-Visible absorption spectra and the fluorescence emission spectra of sixteen tetra-substituted metallo-phthalocyanine complexes {R4PcM, where R=2-［4-(2-sulfonic ethyl)piperazin-1-］ ethoxyl, 2-(piperidin-1-yl)ethoxyl; substitution position at α-position and β-position of phthalocyanine ring; M=Zn, Ni, Coand Cu} were measured.

报道了16种含哌嗪或含哌啶四取代酞菁金属配合物{R4PcM， R=2-［4-(2-磺基乙基)哌嗪-1-基］乙氧基、 2-(哌啶-1-基)乙氧基；取代位置分别在α位和β位； M=Zn， Ni， Co， Cu}的UV-Vis吸收光谱和荧光发射光谱的测定，探讨了中心金属离子、取代基种类及其取代位置、溶剂等因素对酞菁金属配合物UV-Vis吸收光谱和荧光发射光谱性质的影响。

Two triazine derivatives WDBA and WDIOA were synthesized. Four-ball machine was used to test their tribological performance in rapeseed oil.

合成了两种三巯基三嗪衍生物WDBA和WDIOA，利用四球摩擦磨损实验对该衍生物添加剂在菜籽油中的摩擦学性能进行测试。

Four new aerobic bacteria, which could degrade and mineralize atrazine and other s-triazine dericatives were isolated from the different locations impacted by herbicide spills.

本试验从不同的、曾被均三嗪类除草剂污染过的环境中分离到四株能降解CIET的细菌菌株，对它们的生理生化、分子生物学特性以及对均三嗪类除草剂的降解性作了系统研究；总结如下： 1。

In the fourth chapter, 5-phenyl-1,2,4-triazine(3) was synthesized from(5-phenyl-1,2,4-trizin-3-yl)hydrazine in the presence of sodium ethoxide firstly. Themerit of this process was simplification of operation and good yield (more than 90%),which to our knowledge has not been reported so far in literature.

第四章首先以(5-苯基-1，2，4-三嗪-3-基)肼为原料，在乙醇钠作用下经一步反应，合成了化合物5-苯基-1，2，4-三嗪(3)；该法操作简单，产率高(＞90％)，迄今未见文献报道。

Ligustrazine is a kind of the alkaloid monomer which is extracted from the rhizome of the umbelliferae Ligusticum wallichii. Chemistry structure is 2, 3, 5, 6- Tetramethylpyrazine.

川芎嗪是从伞形科植物川芎根茎中提取分离的生物碱单体，化学结构为2，3，5，6-四甲基吡嗪，目前已可人工合成。

The chemical structure of Ligustrazine is tetramethyl pyrazine, its four methyl can show different efficiency, when they are replaced by different functional units.

川芎嗪化学结构为四甲基吡嗪，其四个甲基被不同的功能基团替代后可产生不同效应，研究发现川芎嗪对心血管系统的作用有多种不同的作用途径和作用机制。

Phenothiazines were also oxidized byiodine and 2, 2, 6, 6- tetramethyl - 4 - acetyloxypiperidineoxoammonium hexachloroantimonate to radical cations in the cavityof β-cyclodextrins in aqueous solution.

以吩噻嗪衍生物为底物，2，2，6，6-四甲基-4-乙酰氧基哌啶氧铵六氯锑酸盐、碘为氧化剂，二者在水相中β-环糊精腔内发生了单电子转移反应，产生了吩噻嗪衍生物正离子自由基。

In molten ZnCl2 at high temperature, microporous organic framework based on phthalocyanine skeleton has been obtained from tetracyanopyrazine,and the dynamic trimerization reaction of 1,3,5-tricyano-benzene can lead to triazine-based material with high porosities.

在高温熔融的氯化锌存在下，四氰基吡嗪可以构建形成具有酞菁骨架的微孔材料， 1，3，5-三氰基苯可以发生三聚反应形成具有三嗪结构的微孔材料，均具有较好的多孔性能。

Methods 2-(piperazin-1-yl)-1-(pyrrolidin-1-yl)ethanone (2) was synthesized from pyrrolidine via amidation and substitution, followed by treating with chloroacetyl chloride and triphenylphosphine in a "one pot" manner to give the corresponding phosphonium chloride 3 in a stable and pure form after crystallization from isopropanol.

以四氢吡咯为原料，先与氯乙酰氯成酰胺，再与哌嗪发生取代反应制得中间体［（1-四氢吡咯基）甲基］哌嗪(2)；化合物2与氯乙酰氯和三苯基膦反应，经异丙醇重结晶得到稳定的有机鏻盐(3)；化合物3与3，4，5-三甲氧基苯甲醛发生Wittig反应，再与马来酸成盐得目标化合物马来酸桂哌齐特(1)。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。