四体的

The endocyclic Sn atoms exist in a distorted triginal bipyramidal geometry with the coordination number of 5. The exocyclic Sn atoms form 6 significant bonds and exist in a distorted octahedron geometry.

化合物12的X衍射单晶测定表明，化合物是以Sn2O2四元环为中心的中心对称二聚体结构、内环锡为5配位的畸变三角双锥结构、外环锡为6配位的畸变八面体结构。

Functional ASICs are usually believed to be tetrameric assemblies of homomeric or heteromeric subunits.However,recent Gouaux and colleagues crystal structure shows that there are three subunits in ASIC1 homomeric channel.

功能性的ASICs通常被认为是由相同或不同的亚单位形成的四聚体，然而最近Gouaux等的晶体结构研究表明ASIC1同聚体由三个亚单位装配而成。

For the first time, enantiomers of C2-symmetric 1,1 -spirobiindane-7,7'-diol were resolved with crude menthyl chloroformate by phase-transfer catalysis in the presence of tetrabutylammonium bromide. The reaction was carried out at 0℃-rt. The diastereomers of SPINOL bis-menthyl carbonate can be separated by simple crystallization using alcohol. The hydrolysis of the diastereomers was carried out via aqueous NaOH/EtOH solution.

首次通过相转移催化的方法对螺双二氢茚二酚进行了有效的拆分，用L--氯甲酸薄荷醇酯做拆分剂，以四丁基溴化铵为催化剂在0℃-室温下进行酯化反应生成非对映体衍生物，以乙醇作溶剂，通过重结晶的方法分离衍生物，在水-乙醇混合溶剂条件下，用强碱NaOH或KOH分别水解，制得相应的光学纯度大于99%ee的两个异构体SPINOL，其中总收率：--SPINOL，78.2%；--SPINOL，80.6%。

The design, synthesis of crosslinked poly-salenCo complexes and their application in the HKR of terminal epoxides Di-salicylaldehydcs and tri-salicylaldchydes S-3, S-4, S-5 were synthesized from some easily prepared acids. The crosslinked polymeric ligands could be prepared by condensation of -1, 2-cyclohexanediamine stoichiometrically with a mixture of S-3 and S-4 in different proportions, polymeric catalysts were obtained by inserting the Co atoms to the ligands.

四 交联poly-salenCo络合物的设计合成及其在末端环氧化合物的HKR中的应用以几种易得的羧酸为骨架，设计合成出了相应的双水杨醛和三水杨醛S-3、S-4、S-5，将双水杨醛S-3和三水杨醛S-4按不同比例混合后再与手性环己二胺缩合制备出交联聚合物配体，该配体与Co络合后得到交联聚合物催化剂。

Moreover, the matrix effect was investigated. The results showed that samples could be completely decomposed by melting in lithium tetraborate and lithium carbonate mixed flux at about 1000℃. The introduction of lots of lithium and matrix magnesium in solution affected the determination, which could be corrected by matrix matching. Calcium, iron and aluminium with high content had no spectral interference with other elements with low content.

结果表明，样品用四硼酸锂和碳酸锂混合熔剂在1000℃左右的温度下熔融，可以完全分解试样；引进试液中大量锂和基体铁时测定有影响，用基体匹配的方法克服，含量较高的钙、铁和铝对含量低的其他元素没有光谱干扰。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1，4-丁二胺催化氧化环己烷的催化活性被测试，结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性，而单核的Fe化合物是非催化活性的。

There are many different races and ecotypes throughout its range, the more widespread being generally tetraploid with local diploid races particularly in the Mediterranean region.

在整个它的分布区有很多不同的比赛和生态型，更多的广布的特别是在地中海地区一般作为四倍体具本地二倍体比赛。

In this paper,a simulation program of hard parcels distributed in a coal seam is set up on the basis of analyses and assumptions,and four distributions of these parcels in a geven coal seam are analysed,which lay the theoretical foudation and necessory conditions of studying cutter random loads and designing dynamically working mechanism and entire machine.

文章通过分析假设，建立了硬质包裹体在煤层中分布的模拟程序，并模拟分析了硬质包裹体在煤层中的四种分布状况，为研究截割刀具的随机载荷、以及工作机构和整机的动态设计奠定了基础。

Campo Vieje has four types of wine: the white wine is fermented in the oak barrel for 4 to 6 months. The wine fluid is refined and fresh, with a fruit and vanilla fragrance. The structure is well balanced and suitable for smoked fish and white meat. Crianze is full of the aroma of ripe fruits, together with the fragrance of licorice. It tastes tender, elegant, and as smooth as velvet and will taste better with half-baked beef steak or mutton chop. Reserva is a very rich and mellow wine, perfect for meat.

帝国田园共出品四款酒：帝国田园白酒，在橡木桶发酵4-6个月，酒体典雅爽快，带野果和香草香味，酒体结构平衡，适合配烟熏鱼和白肉；帝国田园陈酿Crianza富有成熟果实的浓香，加上甘草的香味，饮之如天鹅绒般地柔软优雅，配上半熟的牛排、羊排口感更佳；帝国田园珍藏Reserva是一款非常浓郁、醇厚的葡萄酒，最宜搭配肉类食物。

Based on the crystal field theory, perturbation formulas of the spin Hamiltonian parameters g-factors (fourth-order) and the hyperfine structure constants (third-order) of 3d9 ions under tetragonal symmetry are established for the cases of small spin-orbit coupling coefficients and large spin-orbit coupling coefficients of the ligands.

本文基于晶体场理论，在较统一的理论模型和计算方法基础上运用微扰法分别对配体旋轨耦合系数较小和配体旋轨耦合系数较大的情况建立了3d9离子的自旋哈密顿参量g因子的四阶微扰公式和A因子的三阶微扰公式。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。